Treatment method for cotton textile

Patent metadata

Field	Value
Publication number	US-11306430-B2
Application number	US-202117308161-A
Country	US
Kind code	B2
Filing date	May 5, 2021
Priority date	Oct 16, 2018
Publication date	Apr 19, 2022
Grant date	Apr 19, 2022

Abstract

A method of making an antimicrobial textile comprising TiO2 nanoparticles is described. The TiO2 nanoparticles are immobilized by first treating a textile with a base, and then contacting with TiO2 nanoparticles in a solution of an alcohol and acid. The textile may be subsequently irradiated with UV light prior to use. The antimicrobial textile shows high effectiveness against the growth and proliferation of microorganisms transmitted within indoor environments.

First claim

The invention claimed is:

1. Treatment method for a cotton textile, the method comprising:
contacting the cotton textile with an inorganic base to produce a treated cotton textile;
rinsing the treated cotton textile to produce a rinsed cotton textile;
depositing a TiO 2 coating composition onto the rinsed cotton textile, wherein the TiO 2 coating composition contains TiO 2 nanoparticles, methanol, and an organic acid, and the depositing forms a coated textile, wherein the TiO 2 coating composition fully coats the cotton textile during the depositing; and
irradiating the coated textile with a UV light to form an antimicrobial textile, wherein the irradiating forms hydrogen bonds between the TiO 2 nanoparticles and surfaces of individual fibrils of the cotton textile,
wherein the TiO 2 coating composition contains the TiO 2 nanoparticles at a concentration of 10-100 ppm by weight, and the TiO 2 nanoparticles are anatase TiO 2 nanoparticles having an average particle diameter of less than 21 nm.

2. The method of claim 1 , wherein the TiO 2 coating composition contains 60-90 wt % of the organic acid and 10-40 wt % of the methanol relative to a total weight of the TiO 2 coating composition.

3. The method of claim 1 , wherein the cotton textile and the TiO 2 nanoparticles are not contacted with a binding agent, and the TiO 2 coating composition does not comprise a binding agent.

4. The method of claim 1 , wherein the antimicrobial textile contains the TiO 2 nanoparticles at a weight percentage of 0.01-2.00 wt % relative to a total weight of the antimicrobial textile.

5. The method of claim 1 , wherein the cotton textile consists essentially of cotton fiber.

6. The method of claim 1 , wherein the antimicrobial textile comprises fibers having a surface area in which 15-40% of the surface area is covered by TiO 2 nanoparticles.

7. The method of claim 1 , wherein the antimicrobial textile has an antimicrobial activity at least 100 times greater than a second textile that was treated with an essentially identical method that did not have TiO 2 nanoparticles, when the antimicrobial textile and the second textile are contacted with similar bacteria and/or fungal cells and a growth medium.

8. The method of claim 7 , wherein the antimicrobial textile and the second textile are contacted with similar bacteria, which are gram-positive cocci.

9. The method of claim 7 , wherein the antimicrobial textile and the second textile are contacted with similar fungal cells, which are yeast cells.

10. The method of claim 1 , wherein the antimicrobial textile is a component of a bandage, a cast, a gown, a lab coat, a mask, a shoe covering, a face covering, a curtain, a bedcovering, a carpeting, and/or a head covering.

11. The method of claim 1 , wherein the irradiating forms hydrogen bonds directly between hydroxyl groups of cellulose molecules of the cotton textile and surfaces of the TiO 2 nanoparticles.

12. The method of claim 1 , further comprising
neutralizing to a pH of 6.5-7.5 by treating with an inorganic acid.

13. The method of claim 12 , wherein the organic acid is acetic acid and the inorganic acid is nitric acid.

14. The method of claim 12 , wherein the cotton textile consists of cotton fibers.

15. The method of claim 12 , further comprising after the depositing and before the irradiating:
heating and drying the coated textile at a temperature of 27-50° C.

Assignees

• Univ Imam Abdulrahman Bin Faisal

Inventors

• Salama Khaled
• Al Jindan Reem Y

Classifications

• D06M2101/06

  cellulosic · CPC title

• D06M10/06

  Inorganic compounds or elements · CPC title

• D06M10/08

  Organic compounds · CPC title

• D06M16/00 Primary

  Biochemical treatment of fibres, threads, yarns, fabrics, or fibrous goods made from such materials, e.g. enzymatic · CPC title

• D06M11/46 Primary

  Oxides or hydroxides of elements of Groups 4 or 14 of the Periodic Table; Titanates; Zirconates; Stannates; Plumbates · CPC title