Electrode and rechargeable lithium battery including the same

Patent metadata

Field	Value
Publication number	US-12500243-B2
Application number	US-202318159048-A
Country	US
Kind code	B2
Filing date	Jan 24, 2023
Priority date	Jan 28, 2022
Publication date	Dec 16, 2025
Grant date	Dec 16, 2025

Abstract

An electrode including a current collector; an electrode active material layer on a surface of the current collector and including internal pores; an inner coating layer filled in the internal pores of the electrode active material layer and including an adhesive material; and an outer coating layer disposed on a surface of the electrode active material layer and including an adhesive material. A total weight of the inner coating layer and the outer coating layer per area of one surface of the current collector is about 0.1 g/m 2 to about 0.7 g/m 2 . In addition, the electrode active material layer has a porosity of about 13% to about 16% in a cross section having a depth of about 20 μm from the surface of the electrode active material layer to the current collector.

First claim

What is claimed is:

1 . An electrode, comprising
a current collector; an electrode active material layer on a surface of the current collector and comprising internal pores; an inner coating layer filled in the internal pores of the electrode active material layer and comprising an adhesive material; and an outer coating layer on a surface of the electrode active material layer and comprising the adhesive material, wherein a total weight of the inner coating layer and the outer coating layer per area of one surface of the current collector is about 0.1 g/m 2 to about 0.7 g/m 2 , and the electrode active material layer has a porosity of about 13% to about 16% in a cross section having a depth of about 20 μm from the surface of the electrode active material layer to the current collector, wherein the porosity increases as the total weight of the inner coating layer and the outer coating layer per area of one surface of the current collector increases.

2 . The electrode of claim 1 , wherein
the porosity increases as the depth increases from the surface of the electrode active material layer to the cross section having the depth of about 20 μm to the current collector.

3 . The electrode of claim 1 , wherein
the electrode active material layer has a porosity of about 10% to about 12% in a cross section having a depth of about 10 μm from the surface of the electrode active material layer to the current collector.

4 . The electrode of claim 1 , wherein
the electrode active material layer has a porosity of about 13% to about 16% in a lower portion of the cross section having the depth of about 20 μm from the surface of the electrode active material layer to the current collector.

5 . The electrode of claim 1 , wherein
the electrode active material layer has a porosity of about 13% to about 16% porosity in a cross section having a depth of about 30 μm from the surface of the electrode active material layer to the current collector.

6 . The electrode of claim 1 , wherein
the porosity of the cross section having the depth of about 20 μm from the surface of the electrode active material layer to the current collector is about 15% to about 16% when the total weight of the inner coating layer and the outer coating layer per area of one surface of the current collector is about 0.5 to about 0.7 g/m 2 , is about 14% to about 15% when the total weight of the inner coating layer and the outer coating layer per area of one surface of the current collector is about 0.3 to about 0.5 g/m 2 , and is about 13 to about 14% when the total weight of the inner coating layer and the outer coating layer per area of one surface of the current collector is about 0.1 to about 0.3 g/m 2 .

7 . The electrode of claim 1 , wherein
a thickness of the outer coating layer is about 0.5 μm to about 2 μm.

8 . The electrode of claim 1 , wherein
the inner coating layer and the outer coating layer is formed by electrospinning.

9 . The electrode of claim 8 , wherein
the electrospinning is performed by electrospinning of an aqueous solution comprising the adhesive material under conditions of a flow rate of about 1.0 ml/min to about 5.0 ml/min, a progress rate of about 400 cm/min to about 1000 cm/min, and a voltage of about 30 kV to about 50 kV.

10 . The electrode of claim 1 , wherein
the adhesive material comprises an acryl-based polymer.

11 . The electrode of claim 1 , wherein
the adhesive material is in particle form, and a D50 particle diameter of the adhesive material is about 350 nm to about 650 nm.

12 . The electrode of claim 1 , wherein
the inner coating layer and the outer coating layer each further comprises a filler.

13 . The electrode of claim 12 , wherein
the filler comprises a fluorine-based polymer.

14 . The electrode of claim 12 , wherein
the filler is in particle form, and a D50 particle diameter of the filler is about 100 nm to about 400 nm.

15 . The electrode of claim 1 , wherein
the electrode active material layer further comprises a conductive material, a binder, or a combination thereof.

16 . The electrode of claim 1 , wherein
the electrode satisfies Equation 1:
100%*([ T B ]−[T A ])/[ T A ]≤20%  Equation 1

wherein, in Equation 1, [T A ] is an initial thickness of the electrode; and [T B ] is a thickness of the electrode after a state of charge (SOC) of a rechargeable lithium battery comprising the electrode reaches 100%.

17 . The electrode of claim 1 , wherein
the electrode is a negative electrode.

18 . A rechargeable lithium battery, comprising
a positive electrode; a negative electrode; and an electrolyte, wherein at least one of the positive electrode or the negative electrode is the electrode of claim 1 .

Assignees

• Samsung Sdi Co Ltd

Inventors

• Lee Jinhee
• Song Hyo-Jung
• Kim Minjae
• Yang Mihwa
• Koo Kyoseon
• Moon Jeunggi
• You Duckjae

Classifications

• H01M4/623

  fluorinated polymers · CPC title

• Y02E60/10

  Energy storage using batteries · CPC title

• H01M2300/0097

  with adhesive layers · CPC title

• H01M10/052

  Li-accumulators · CPC title

• H01M4/624

  Electric conductive fillers · CPC title