Polymer composition with improved stress whitening resistance

Patent metadata

Field	Value
Publication number	US-12486388-B2
Application number	US-202217859312-A
Country	US
Kind code	B2
Filing date	Jul 7, 2022
Priority date	Jun 14, 2018
Publication date	Dec 2, 2025
Grant date	Dec 2, 2025

Abstract

A polymer composition is provided with improved stress whitening resistance, having at least one thermoplastic polymer material and a dielectric liquid. A process for preparing the polymer composition, a cable having at least one electrically insulating layer obtained from the polymer composition, and a process for preparing the cable are also provided.

First claim

The invention claimed is:

1 . An electric cable comprising:
at least one elongated electrically conducting element; and at least one electrically insulating layer obtained from a polymer composition having at least one polypropylene-based thermoplastic polymer material and a dielectric liquid, wherein the dielectric liquid comprises at least one compound corresponding to formula (I) below:
R 1 -A-R 2   (I)

in which R 1 and R 2 , identical or different, are unsubstituted aryl groups and the element A represents a single bond or an alkylene group; and

wherein the element A is an alkylene group of the formula —(CH 2 )n- with 1≤n≤10; a group —(CHR)n′- with 1≤n≤5 and R being an alkyl group; a statistical group —(CHR)p-(CH 2 )m-, with 1≤p+m≤9, and R being an alkyl group; or a statistical group —(CHR)p1-(CH 2 )m′—(CHR′)p2-, with 1≤p1+m′+p2≤8, and R and R′ being different alkyl groups.

2 . The electric cable according to claim 1 , wherein the aryl groups each comprises from 5 to 20 carbon atoms.

3 . The electric cable according to claim 1 , wherein at least one of said groups R 1 or R 2 of the compound of formula (I) is a phenyl group.

4 . The electric cable according to claim 1 , wherein the compound of formula (I) is diphenylethane, diphenylmethane or 1,2,3,4-tetrahydro(1-phenylethyl)naphthalene.

5 . The electric cable according to claim 1 , wherein the dielectric liquid comprises at least 50% by mass of at least one compound of formula (I), relative to the total mass of the dielectric liquid.

6 . The electric cable according to claim 1 , wherein the ratio of the number of aromatic carbon atoms to the total number of carbon atoms in the dielectric liquid is greater than or equal to 0.6.

7 . The electric cable according to claim 1 , wherein the dielectric liquid represents from 1% to 20% by mass relative to the total mass of the polymer composition.

8 . The electric cable according to claim 1 , wherein the polypropylene-based thermoplastic polymer material comprises at least one homopolymer or one copolymer of propylene P1, and at least one homopolymer or one copolymer of α-olefin P2.

9 . The electric cable according to claim 8 , wherein the propylene copolymer P1 is a copolymer of propylene and ethylene.

10 . The electric cable according to claim 8 , wherein the propylene homopolymer or copolymer P1 represents from 40% to 70% by mass of the polypropylene-based thermoplastic polymer material.

11 . The electric cable according to claim 8 , wherein the α-olefin homopolymer or copolymer P2 is a heterophasic copolymer comprising a thermoplastic phase of propylene type and a thermoplastic elastomer phase of the type copolymer of ethylene and of an α-olefin, a polyethylene or a mixture thereof.

12 . The electric cable according to claim 8 , wherein the α-olefin homopolymer or copolymer P2 represents from 30% to 60% by mass of the thermoplastic polymer material.

13 . The electric cable according to claim 1 , wherein the electrically insulating layer is a non-crosslinked layer.

14 . A process for preparing a polymer composition of at least one electrically insulating layer of an electric cable the electric cable having
at least one elongated electrically conducting element; and at least one electrically insulating layer obtained from a polymer composition having at least one polypropylene-based thermoplastic polymer material and a dielectric liquid, wherein the dielectric liquid comprises at least one compound corresponding to formula I) below:
R 1 -A-R 2   (I)

in which R 1 and R 2 , identical or different, are unsubstituted aryl groups and the element A represents a single bond or an alkylene group; and

wherein the element A is an alkylene group of the formula —(CH 2 )n- with 1≤n≤10; a group —(CHR)n′- with 1≤n≤5 and R being an alkyl group; a statistical group —(CHR)p-(CH 2 )m-, with 1≤p+m≤9, and R being an alkyl group; or a statistical group —(CHR)p1-(CH 2 )m′—(CHR′)p2-, with 1≤p1+m′+p2≤8, and R and R′ being different alkyl groups,
said process comprising at least one step i) of mixing a polypropylene-based thermoplastic polymer material with said dielectric liquid.

15 . The process for manufacturing an electric cable as defined in claim 14 said process further comprising at least one step of extruding the polymer composition around said elongated electrically conducting element, to obtain said electrically insulating layer surrounding said elongated electrically conducting element.

Assignees

• Nexans

Inventors

• Perego Gabriele
• Mazel Christelle
• Meyer Matthias
• Charrier Dimitri
• Festaz Xavier

Classifications

• C08L2666/30

  Hydrocarbons · CPC title

• C08K5/01

  Hydrocarbons {(C08K5/0091 takes precedence)} · CPC title

• H01B9/027

  composed of semi-conducting layers · CPC title

• H01B3/441 Primary

  from alkenes · CPC title

• C08L2207/066

  LDPE (radical process) · CPC title