Polymer composition with improved stress whitening resistance

Patent metadata

Field	Value
Publication number	US-11525050-B2
Application number	US-201616062416-A
Country	US
Kind code	B2
Filing date	Dec 15, 2016
Priority date	Dec 18, 2015
Publication date	Dec 13, 2022
Grant date	Dec 13, 2022

Abstract

A polymer composition is provided with improved stress whitening resistance, having at least one thermoplastic polymer material and a dielectric liquid. A process for preparing the polymer composition, a cable having at least one electrically insulating layer obtained from the polymer composition, and a process for preparing the cable are also provided.

First claim

The invention claimed is:

1. A polymer composition comprising at least one polypropylene-based thermoplastic polymer material and a dielectric liquid, wherein the dielectric liquid comprises at least one compound corresponding to formula (I) below:
R 1 - A -R 2   (I)

in which R 1 and R 2 , identical or different, are unsubstituted aryl groups and the element A represents a single bond or an alkylene group,
wherein the polypropylene-based thermoplastic polymer material comprises at least one homopolymer or one copolymer of propylene P 1 , and at least one homopolymer or one copolymer of α-olefin P 2 .

2. The polymer composition according to claim 1 , wherein the aryl group comprises from 5 to 20 carbon atoms.

3. The polymer composition according to claim 1 , wherein the element A is an alkylene group containing from 1 to 10 carbon atoms.

4. The polymer composition according to claim 3 , wherein the alkylene group is a group —(CH 2 ) n — with 1≤n≤10; a group —(CHR) n — with 1≤n≤5 and R being an alkyl group; a statistical group —(CHR) p —(CH 2 ) m —, with 1≤p+m≤9, and R being an alkyl group; or a statistical group —(CHR) p1 —(CH 2 )m′—(CHR′) p2 —, with 1≤p 1 +m′+p 2 ≤8, and R and R′ being different alkyl groups.

5. The polymer composition according to claim 1 , wherein at least one of said groups R 1 or R 2 of the compound of formula (I) is a phenyl group.

6. The polymer composition according to claim 1 , wherein the compound of formula (I) is diphenylethane, diphenylmethane or 1,2,3,4-tetrahydro(1-phenylethyl)naphthalene.

7. The polymer composition according to claim 1 , wherein the dielectric liquid comprises at least 50% by mass of at least one compound of formula (I), relative to the total mass of the dielectric liquid.

8. The polymer composition according to claim 1 , wherein the ratio of the number of aromatic carbon atoms to the total number of carbon atoms in the dielectric liquid is greater than or equal to 0.6.

9. The polymer composition according to claim 1 , wherein the dielectric liquid represents from 1% to 20% by mass relative to the total mass of the polymer composition.

10. The polymer composition according to claim 1 , wherein the propylene copolymer P 1 is a copolymer of propylene and ethylene.

11. The polymer composition according to claim 10 , wherein the propylene homopolymer or copolymer P 1 represents from 40% to 70% by mass of the polypropylene-based thermoplastic polymer material.

12. The polymer composition according to claim 10 , wherein the α-olefin homopolymer or copolymer P 2 is a heterophasic copolymer comprising a thermoplastic phase of propylene type and a thermoplastic elastomer phase of the type copolymer of ethylene and of an α-olefin, a polyethylene or a mixture thereof.

13. The polymer composition according to claim 10 , wherein the α-olefin homopolymer or copolymer P 2 represents from 30% to 60% by mass of the thermoplastic polymer material.

14. A process for preparing the polymer composition as defined in claim 1 , comprising at least one step i) of mixing a polypropylene-based thermoplastic polymer material with said dielectric liquid.

15. A cable comprising at least one elongated electrically conducting element, and at least one electrically insulating layer obtained from a polymer composition as defined in claim 1 .

16. The cable according to claim 15 , wherein the electrically insulating layer is a non-crosslinked layer.

17. A process for manufacturing an electric cable as defined in claim 15 said process comprising at least one step 1) of extruding the polymer composition around an elongated electrically conducting element, to obtain an electrically insulating layer surrounding said elongated electrically conducting element.

Assignees

• Nexans

Inventors

• Perego Gabriele
• Mazel Christelle
• Meyer Matthias
• Charrier Dimitri
• Festaz Xavier

Classifications

• C08L2201/08

  Stabilised against heat, light or radiation or oxydation · CPC title

• C08K5/01

  Hydrocarbons {(C08K5/0091 takes precedence)} · CPC title

• C08L2666/30

  Hydrocarbons · CPC title

• C08L23/10 Primary

  Homopolymers or copolymers of propene · CPC title

• H01B9/027

  composed of semi-conducting layers · CPC title