Cerium citrate, method of making and corrosion inhibitor comprising cerium citrate
US-2017350019-A1 · Dec 7, 2017 · US
US12467148B2 · US · B2
| Field | Value |
|---|---|
| Publication number | US-12467148-B2 |
| Application number | US-202218060824-A |
| Country | US |
| Kind code | B2 |
| Filing date | Dec 1, 2022 |
| Priority date | Dec 2, 2021 |
| Publication date | Nov 11, 2025 |
| Grant date | Nov 11, 2025 |
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A marine ICCP system includes an electrical circuit comprising a primary and a secondary circuit. The primary circuit comprises a first electrode connected to a positive terminal of a power source to act as an active anode; and a second electrode connected to a negative terminal of the power source. The secondary circuit comprises a passive electrode normally disconnected from the electrical circuit and arranged to act as back-up protection, wherein the second electrode connectable to the passive electrode. The passive electrode is arranged to be connected to the power source if a detected output voltage in the primary circuit reaches a maximum value and if a determined polarization potential for the cathode is insufficient. The control unit is operable to control the output voltage supplied to the primary and secondary circuits separately in order to supply an individual output voltage to each circuit.
Opening claim text (preview).
The invention claimed is: 1 . A marine impressed current cathodic protection system having an electrical circuit comprising a control unit for controlling the impressed current cathodic protection system, voltage sensors detecting an output voltage impressed on the circuit and measuring polarized potential of the protected structure, current sensor detecting a current supplied to the circuit and a source of electrical power from at least one direct current power source; wherein the electrical circuit comprises a primary circuit and a secondary circuit; the primary circuit comprising: at least one first electrode connected to a positive terminal of the at least one power source to act as an active anode; and at least one second electrode connected to a negative terminal of the at least one power source to act as a cathode, wherein at least one metallic component to be protected forms said cathode; and the secondary circuit comprising: at least one passive electrode normally disconnected from the electrical circuit and arranged to act as back-up protection, the at least one passive electrode being a sacrificial anode; the at least one second electrode connectable to the at least one passive electrode; wherein the at least one passive electrode is connectable to the positive terminal of the at least one power source by a controllable switch in the secondary circuit; the control unit is operable to control the marine impressed current cathodic protection system such that the at least one passive electrode is connected to the at least one power source if a detected output voltage in the primary circuit reaches a maximum value and if a determined polarization potential for the cathode is insufficient; wherein the control unit is operable to control the output voltage supplied to the primary and secondary circuits separately; in order to supply an individual output voltage to each circuit. 2 . The system according to claim 1 , wherein the control unit is operable to monitor the output voltage and current supplied to the at least one first electrode, and to determine a value for polarization potential for the cathode in the primary circuit. 3 . The system according to claim 2 , wherein the control unit is operable to compare the polarization potential of the cathode to a desired protection potential and to control the output voltage and current to minimize the potential difference. 4 . The system according to claim 1 , wherein the maximum value for the output voltage in the primary circuit corresponds to the breakdown potential of the first electrode. 5 . The system according to claim 1 , wherein the output voltage supplied to the primary circuit is limited by the maximum value for the output voltage in the primary circuit. 6 . The system according to claim 1 , wherein the output voltage supplied to the secondary circuit is limited by the voltage of the at least one direct current power source. 7 . A method for controlling a marine impressed current cathodic protection system having an electrical circuit comprising a control unit for controlling the impressed current cathodic protection system, voltage sensors detecting an output voltage impressed on the circuit and measuring polarized potential of the protected structure, current sensor detecting a current supplied to the circuit and at least one source of electrical power from at least one direct current power source; where the electrical circuit further comprises a primary circuit comprising: at least one first electrode connected to a positive terminal of the power source to act as an active anode; at least one second electrode connected to a negative terminal of the power source to act as a cathode, wherein at least one metallic component to be protected forms said cathode; and a secondary circuit comprising: at least one passive electrode normally disconnected from the electrical circuit and arranged to act as back-up protection, the at least one passive electrode being a sacrificial anode; the at least one second electrode connectable to the at least one passive electrode; wherein the method comprises the steps of: monitoring the output voltage and current supplied to the at least one first electrode, and determining a value for polarization potential for the primary circuit; comparing the polarization potential to a desired protection potential and controlling the output voltage and current to minimize the potential difference; and if the monitored output voltage reaches a maximum value; connecting the at least one passive electrode to the electrical circuit; connecting the at least one passive electrode to a source of electrical power; and controlling the output voltage supplied to the primary and secondary circuits separately and supplying an individual output voltage to each circuit. 8 . The method according to claim 7 , wherein the maximum value for the output voltage in the primary circuit corresponds to the breakdown potential of the first electrode. 9 . The method according to claim 7 , wherein the output voltage supplied to the primary circuit is limited by the maximum value for the output voltage in the primary circuit. 10 . The method according to claim 7 , wherein the output voltage supplied to the secondary circuit is limited by the voltage of the at least one direct current power source or breakdown potential of the contacting material. 11 . The method according to claim 7 , wherein the method involves the option step of determining a value for polarization potential for the primary circuit and comparing the polarization potential to a desired protection potential prior to connecting the at least one passive electrode to a source of electrical power. 12 . A vessel provided with a marine impressed current cathodic protection system according to claim 1 .
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