Light-emitting device and method of manufacturing the same

Patent metadata

Field	Value
Publication number	US-12459949-B2
Application number	US-202217660722-A
Country	US
Kind code	B2
Filing date	Apr 26, 2022
Priority date	May 3, 2021
Publication date	Nov 4, 2025
Grant date	Nov 4, 2025

Abstract

Disclosed are a light-emitting device and a method of manufacturing the same. The light-emitting device includes: a first electrode; a second electrode facing the first electrode; an emission layer between the first electrode and the second electrode and including a quantum dot including a first ligand bonded to a surface thereof; and a charge transport layer including an inorganic nanoparticle including a second ligand bonded to a surface thereof, wherein an interface between the emission layer and the charge transport layer includes a cross-link in which the first ligand on the surface of the quantum dot and the second ligand on the surface of the inorganic nanoparticle are linked by a cross-linking agent.

First claim

What is claimed is:

1 . A light-emitting device comprising:
a first electrode; a second electrode facing the first electrode; an emission layer between the first electrode and the second electrode and comprising a quantum dot comprising a first ligand bonded to a surface thereof; and a charge transport layer between the first electrode and the emission layer and comprising an inorganic nanoparticle and a second ligand coordinate-bonded to a surface of the inorganic nanoparticle, wherein an interface between the emission layer and the charge transport layer comprises a cross-link in which the first ligand on the surface of the quantum dot and the second ligand on the surface of the inorganic nanoparticle are linked by a cross-linking agent.

2 . The light-emitting device of claim 1 , wherein
the cross-linking agent comprises two or more functional groups, and the two or more functional groups are each independently an azide group, an alkoxy group, a vinyl group, a thiol group, an amine group, an epoxy group, an oxirane group, a carboxyl group, or any combination thereof.

3 . The light-emitting device of claim 1 , wherein
the cross-linking agent comprises two or more functional groups, and the two or more functional groups are each an azide group.

4 . The light-emitting device of claim 1 , wherein the cross-linking agent is at least one selected from following compounds:

wherein, n is an integer from 1 to 5.

5 . The light-emitting device of claim 1 , wherein the first ligand bonded to the surface of the quantum dot is oleic acid, oleyl amine, 1-dodecanethiol, trioctylphosphine oxide, 2-ethylhexane-1-thiol, caproic acid, propionic acid, benzoic acid, cinnamic acid, thiophenol, adamantyl acid, or any combination thereof.

6 . The light-emitting device of claim 1 , wherein
the first electrode is an anode, the second electrode is a cathode, and the charge transport layer is a hole transport layer.

7 . The light-emitting device of claim 6 , wherein the inorganic nanoparticle in the hole transport layer comprises WO 2 , WO 3 , NiO, MoO 3 , Cr 2 O 3 , Bi 2 O 3 , CuO, Cu 2 O, Cul, CuSCN, Nb 2 O 5 , BaSnO 3 , Zn 2 SnO 4 , SrTiO 3 , Zn 2 TiO 8 , or any combination thereof.

8 . The light-emitting device of claim 6 , wherein the second ligand bonded to the surface of the inorganic nanoparticle in the hole transport layer is oleic acid, oleyl amine, 1-dodecanethiol, trioctylphosphine oxide, 2-ethylhexane-1-thiol, caproic acid, propionic acid, benzoic acid, cinnamic acid, thiophenol, adamantyl acid, alkyl trimethoxy silane, mercaptopropionic acid, tert-butoxyamino acid, carbazole-substituted alkyl carboxylic acid, pyrene-substituted alkyl carboxylic acid, or any combination thereof.

9 . The light-emitting device of claim 1 , wherein
the first electrode is a cathode, the second electrode is an anode, and the charge transport layer is an electron transport layer.

10 . The light-emitting device of claim 9 , wherein the inorganic nanoparticle in the electron transport layer comprises ZnO, TiO 2 , SnO 2 , In 2 O 3 , WO 3 , Nb 2 O 3 , CeO x , Al-doped ZnO, Mg-doped ZnO, Li-doped ZnO, Y-doped ZnO, Al-doped TiO 2 , Mg-doped TiO 2 , Li-doped TiO 2 , Y-doped TiO 2 , or any combination thereof.

11 . The light-emitting device of claim 9 , wherein the second ligand bonded to the surface of the inorganic nanoparticle in the electron transport layer is oleic acid, oleyl amine, 1-dodecanethiol, trioctylphosphine oxide, 2-ethylhexane-1-thiol, caproic acid, propionic acid, benzoic acid, cinnamic acid, thiophenol, adamantyl acid, alkyl trimethoxy silane, mercaptopropionic acid, tert-butoxyamino acid, carbazole-substituted alkyl carboxylic acid, pyrene-substituted alkyl carboxylic acid, or any combination thereof.

12 . The light-emitting device of claim 1 , wherein the quantum dot comprises a first quantum dot and a second quantum dot, and the emission layer comprises a cross-link in which a first ligand on a surface of the first quantum dot and a first ligand on a surface of the second quantum dot are linked by the cross-linking agent.

13 . The light-emitting device of claim 1 , further comprising a second charge transport layer between the emission layer and the second electrode and comprising an inorganic nanoparticle comprising a third ligand bonded to a surface thereof,
wherein an interface between the emission layer and the second charge transport layer comprises a cross-link in which the first ligand on the surface of the quantum dot and the third ligand on the surface of the inorganic nanoparticle in the second charge transport layer are linked by the cross-linking agent.

14 . The light-emitting device of claim 1 , wherein
the emission layer comprises a first emission layer and a second emission layer, the first emission layer being between the first electrode and the second emission layer, the quantum dot comprises a first quantum dot and a second quantum dot, a first ligand bonded to a surface of the first quantum dot in the first emission layer is a hole-transporting ligand, and a first ligand bonded to a surface of the second quantum dot in the second emission layer is an electron-transporting ligand.

15 . A method of manufacturing a light-emitting device, the method comprising:
preparing a first electrode; forming a charge transport layer by providing, on the first electrode, an inorganic nanoparticle composition comprising an inorganic nanoparticle and a solvent, the inorganic nanoparticle comprising a second ligand bonded to a surface thereof; forming a preliminary emission layer by providing, on the charge transport layer, a quantum dot composition comprising a quantum dot, a cross-linking agent, and a solvent, the quantum dot comprising a first ligand bonded to a surface thereof; forming an emission layer by performing at least one selected from among a heat treatment and a UV irradiation on the preliminary emission layer; and forming a second electrode on the emission layer.

16 . The method of claim 15 , wherein the forming of the emission layer further comprises cross-linking the first ligand and the second ligand by performing the at least one selected from among the heat treatment and the UV irradiation on the preliminary emission layer.

17 . The method of claim 15 , wherein the forming of the emission layer further comprises cross-linking a first ligand on a surface of a first quantum dot included in the quantum dot and a first ligand on a surface of a second quantum dot included in the quantum dot by performing the at least one selected from among the heat treatment and the UV irradiation on the preliminary emission layer.

18 . The method of claim 15 , further comprising forming a second charge transport layer by providing a second inorganic nanoparticle composition on the emission layer,
wherein the second inorganic nanoparticle composition comprises a solvent and an inorganic nanoparticle comprising a third ligand bonded to a surface thereof.

19 . The method of claim 18 , wherein the forming of the second charge transport layer further comprises cross-linking the first ligand and the third ligand by performing at least one selected from among a heat treatment and a UV irradiation on the second inorganic nanoparticle composition.

20 . The method of claim 15 , wherein the quantum dot composition has a viscosity of about 1 cP to about 10 cP and a surf

Assignees

• Samsung Display Co Ltd

Inventors

• Jung Yunku
• Lee Changhee
• Choi Hyekyoung
• Ha Jaekook

Classifications

• H10K71/441

  in the presence of solvent vapors, e.g. solvent vapour annealing · CPC title

• H10K2102/331

  Nanoparticles used in non-emissive layers, e.g. in packaging layer · CPC title

• H10K2102/103

  comprising indium oxides, e.g. ITO · CPC title

• H10K2102/102

  comprising tin oxides, e.g. fluorine-doped SnO2 · CPC title

• H10K85/6574

  comprising only oxygen in the heteroaromatic polycondensed ring system, e.g. cumarine dyes · CPC title