Process and system for producing a product hydrocarbon

Patent metadata

Field	Value
Publication number	US-12454500-B2
Application number	US-202218549580-A
Country	US
Kind code	B2
Filing date	Mar 14, 2022
Priority date	Mar 15, 2021
Publication date	Oct 28, 2025
Grant date	Oct 28, 2025

Abstract

Producing a product hydrocarbon includes subjecting a feed mixture containing a feed hydrocarbon and oxygen to selective oxidation to obtain a product mixture containing product hydrocarbon and water. A subsequent mixture is formed from a portion of the product mixture by separating a portion of the water. Oxygen in the feed mixture is partially converted during the selective oxidation, so that the product mixture has a first residual oxygen content and the subsequent mixture has a second residual oxygen content. Detection of the first and/or the second residual oxygen content is performed using a first measuring device. A second measuring device at the end of the catalyst bed detects temperature. Using a process control and/or evaluation unit, measurement data of the first and/or second measuring device(s) are detected and are evaluated and/or processed while obtaining follow-up data. Process control is carried out on the basis of the follow-up data.

First claim

The invention claimed is:

1. A method for producing a product hydrocarbon, comprising:
subjecting a feed hydrocarbon in a feed mixture containing the feed hydrocarbon and oxygen to selective oxidation in a reactor having a catalyst bed to obtain a product mixture containing the product hydrocarbon and water, wherein the feed hydrocarbon is ethane and the product hydrocarbon is ethylene and the selective oxidation is carried out in the form of oxidative dehydrogenation of ethane; and
forming a subsequent mixture from at least part of the product mixture by separating at least part of the water;
wherein:
the method is carried out in such a way that the oxygen contained in the feed mixture is partially converted during the selective oxidation, so that the product mixture has a first residual oxygen content and the subsequent mixture has a second residual oxygen content;
a detection of the first and/or of the second residual oxygen content is carried out using at least one first measuring device;
at least one second measuring device is provided at an outlet end of the catalyst bed, which second measuring device is set up to detect a variable characterizing an operating stability, the variable characterizing the operating stability being a temperature at the outlet end of the catalyst bed;
using a process control and/or evaluation unit, measurement data of the at least one first measuring device and/or the at least one second measuring device are detected over a detection period and are evaluated and/or processed to obtain follow-up data;
process control is carried out on the basis of the follow-up data, wherein the process control comprises adjusting at least one operating parameter;
the reactor used for the selective oxidation is cooled using at least one coolant; and
the at least one operating parameter represents or comprises a coolant temperature of the at least one coolant or an oxygen content of the feed mixture.

2. The method of claim 1 , wherein the first residual oxygen content is at least 0.41 mole percent and the second residual oxygen content is at least 0.62 mole percent.

3. The method of claim 2 , wherein the first residual oxygen content is at least 0.41 mole percent and the second residual oxygen content is at least 0.62 mole percent, and wherein the second residual oxygen content is at most 2 mole percent.

4. The method of claim 3 , wherein the at least one first measuring device is set up for gas chromatographic and/or paramagnetic oxygen measurement and/or is set up for oxygen measurement using a quantum cascade laser.

5. The method of claim 2 , wherein the first residual oxygen content is at least 0.41 mole percent and the second residual oxygen content is at least 0.62 mole percent, or wherein the second residual oxygen content is at most 2 mole percent.

6. The method according to claim 5 , wherein the at least one first measuring device is set up for gas chromatographic and/or paramagnetic oxygen measurement and/or is set up for oxygen measurement using a quantum cascade laser.

7. The method of claim 1 , in which an oxygen content of the feed mixture is predetermined using a control system, the oxygen content of the feed mixture being detected using at least a third measuring device and/or being derived from process parameters.

8. The method of claim 1 , wherein the follow-up data comprises a value of the first and/or the second residual oxygen content determined over the detection period and/or a range of variation thereof and/or a value of the operating stability characterizing variable determined over the detection period and/or a range of variation thereof.

9. The method according to claim 1 , wherein the at least one operating parameter represents or comprises a coolant temperature of the at least one coolant and an oxygen content of the feed mixture.

10. The method according to claim 1 , wherein the coolant is passed through the reactor in co-current or counter-current flow to the feed mixture.

11. The method according to claim 1 , wherein the reactor used for the selective oxidation comprises a plurality of reaction tubes, wherein the at least one first measuring device and/or the at least one second measuring device is associated with one or a part of the reaction tubes.

12. The method according to claim 1 , wherein the oxidative dehydrogenation of ethane is carried out using a catalyst containing at least the elements molybdenum, vanadium, and niobium.

13. The method according to claim 12 , wherein the catalyst further contains tellurium.

14. The method of claim 1 , wherein the first residual oxygen content is at least 0.41 mole percent and the second residual oxygen content is at least 0.62 mole percent, or wherein the second residual oxygen content is at most 2 mole percent.

15. The method according to claim 14 , wherein the at least one first measuring device is set up for gas chromatographic and/or paramagnetic oxygen measurement and/or is set up for oxygen measurement using a quantum cascade laser.

16. A plant for producing a product hydrocarbon in the process according to claim 1 , the plant comprising:
a feed source comprising a feed hydrocarbon;
a reactor configured to receive the feed hydrocarbon from the feed source and subject a feed mixture containing the feed hydrocarbon and oxygen to selective oxidation to obtain a product mixture containing the product hydrocarbon and water, wherein the feed hydrocarbon is ethane and the product hydrocarbon is ethylene and the selective oxidation is carried out in the form of oxidative dehydrogenation of ethane;
a separator configured to form, by separating at least part of the water, a subsequent mixture from at least part of the product mixture;
wherein the plant is arranged to carry out the process in such a way that the oxygen contained in the feed mixture is partially reacted during the selective oxidation, so that the product mixture has a first residual oxygen content and the subsequent mixture has a second residual oxygen content;

at least one first measuring device configured to detect the first and/or the second residual oxygen content;
at least one second measuring device provided at the outlet end of the catalyst bed, wherein the at least one second measuring device is configured to detect a variable characterizing an operating stability, the variable characterizing the operating stability being a temperature at an outlet end of the catalyst bed; and
a process control and/or evaluation unit configured to detect measurement data of the at least one first measuring device and/or the at least one second measuring device over a detection period and to evaluate and/or process the measurement data while obtaining follow-up data;
wherein the plant is configured to carry out a process control on the basis of the follow-up data, wherein the process control comprises adjusting an operating parameter;
wherein the reactor is configured to be cooled using at least one coolant; and
wherein the at least one operating parameter represents or comprises a coolant temperature of the at least one coolant and/or an oxygen content of the feed mixture.

Assignees

• Linde Gmbh

Inventors

• Zellhuber Mathieu
• Schubert Martin
• Meiswinkel Andreas
• Wohl Anina

Classifications

• C07C2527/057

  Selenium or tellurium; Compounds thereof · CPC title

• C07C2523/28

  Molybdenum · CPC title

• C07C2523/22

  Vanadium · CPC title

• C07C2523/20

  Vanadium, niobium or tantalum · CPC title

• C07C2523/652

  Chromium, molybdenum or tungsten · CPC title