Three-dimensional printing with reciprocal feeding of polymerizable liquid

Patent metadata

Field	Value
Publication number	US-12454095-B2
Application number	US-202318239317-A
Country	US
Kind code	B2
Filing date	Aug 29, 2023
Priority date	Jun 20, 2014
Publication date	Oct 28, 2025
Grant date	Oct 28, 2025

Abstract

Described herein are methods, systems and apparatus (including associated control methods, systems and apparatus), for the production of a three-dimensional object by “bottom up” additive manufacturing, in which a carrier is vertically reciprocated with respect to a build surface, to enhance or speed the refilling of the build region with a solidifiable liquid. In preferred (but not necessarily limiting) embodiments, the three-dimensional object is produced from a liquid interface by continuous liquid interface production (i.e., “CLIP”).

First claim

That which is claimed is:

1. A method of forming a three-dimensional object, comprising:
providing a carrier and an optically transparent semipermeable member having a build surface, said carrier and said build surface defining a build region therebetween, with said build surface in fluid communication by way of said semipermeable member with a source of polymerization inhibitor;
filling said build region with a polymerizable liquid;
continuously or intermittently irradiating said build region through said optically transparent semipermeable member to form a solid polymer in said build region, while forming or maintaining a liquid film release layer comprised of said polymerizable liquid between said solid polymer and said build surface, wherein polymerization of said liquid film release layer is inhibited by said polymerization inhibitor;
continuously or intermittently advancing said carrier away from said build surface to form said three-dimensional object from said solid polymer;
said filling step further comprising vertically reciprocating said carrier with respect to said build surface to enhance or speed the refilling of said build region with said polymerizable liquid,
wherein a gradient of polymerizable liquid is formed or maintained as an interphase between said liquid film release layer and said solid polymer and in contact with each thereof, said gradient of polymerizable liquid comprising said polymerizable liquid in partially cured form, and
wherein said liquid release layer is continuously maintained by feeding an inhibitor of polymerization through said optically transparent member.

2. The method of claim 1 , wherein said optically transparent semipermeable member is comprised of a fluoropolymer.

3. The method of claim 1 , wherein said vertically reciprocating step is carried by motion of said carrier alone.

4. The method of claim 1 , wherein said vertically reciprocating step is carried out by combined motion of said carrier and said build surface.

5. The method of claim 1 , wherein said irradiating is intermittent irradiating, and said intermittent irradiating is synchronized with said vertically reciprocating.

6. The method of claim 1 , wherein said irradiating is intermittent irradiating, and said intermittent irradiating is not synchronized with said vertically reciprocating.

7. The method of claim 1 , wherein said vertically reciprocating step comprises an upstroke and a downstroke, with the distance of said upstroke greater than the distance of said downstroke, to thereby concurrently carry out said advancing step in part or in whole.

8. The method of claim 1 , wherein said vertically reciprocating step comprises an upstroke, and wherein the speed of said upstroke accelerates over a period of time during said upstroke.

9. The method of claim 1 , wherein said vertically reciprocating step comprises a downstroke, and wherein the speed of said downstroke decelerates over a period of time during said downstroke.

10. The method of claim 1 , wherein said vertically reciprocating step is carried out over a total time of from 0.01 to 10 seconds, and/or over an upstroke distance of travel of from 0.02 millimeters to 10 millimeters.

11. The method of claim 1 , wherein said advancing step is carried out intermittently at a rate of 1 individual advances per minute up to 1000 individual advances per minute, each followed by a pause during which an irradiation is carried out.

12. The method of claim 11 , wherein each of said individual advances is carried out over an average distance of travel for each advance of from 10 microns to 200 microns.

13. The method of claim 1 , wherein the gradient of polymerizable liquid is maintained for at least 15 seconds.

14. The method of claim 13 , wherein the gradient of polymerizable liquid is maintained for five minutes or more.

15. The method of claim 14 , wherein the gradient of polymerizable liquid is maintained until the three-dimensional object is completed.

16. The method of claim 1 , further comprising heating said polymerizable liquid.

17. The method of claim 1 , wherein filling said build region with polymerizable liquid comprises forcing said polymerizable liquid into said build region under pressure.

18. The method of claim 1 , further comprising monitoring at least one process parameter and/or providing at least one known or predetermined process parameter; and then altering at least one process condition in response to said monitored process parameter or known or predetermined process parameter.

Assignees

• Carbon Inc

Inventors

• Ermoshkin Alexander
• Shirvanyants David
• Phelps Nordstrom Kirk
• Ermoshkin Nikita
• Samulski Edward T
• Desimone Joseph M

Classifications

• B29K2105/0058

  Liquid or visquous · CPC title

• B33Y50/02 Primary

  for controlling or regulating additive manufacturing processes · CPC title

• B29C64/264

  Arrangements for irradiation · CPC title

• B29C64/255

  Enclosures for the building material, e.g. powder containers · CPC title

• B29C64/232

  for motion along the axis orthogonal to the plane of a layer · CPC title