Nanostructured iron/carbon for scavenging oxygen

Patent metadata

Field	Value
Publication number	US-12453357-B2
Application number	US-202117386417-A
Country	US
Kind code	B2
Filing date	Jul 27, 2021
Priority date	May 22, 2015
Publication date	Oct 28, 2025
Grant date	Oct 28, 2025

Abstract

The invention is directed to a nanostructured composite material comprising a mixture of at least one metal particle such as iron and a carbon material from biomass such as D-glucose, D-glucosamine hydrochloride or α-cyclodextrin. The invention is also directed to a composition comprising the composite material comprising the composite material and an inorganic salt, and a method for synthesizing the composite material comprising immersing the carbon material into a solution of metal ions, drying the impregnated carbon particle and subjecting the impregnated carbon particle to a carbothermal reduction process. The nanostructured composite material is useful as an oxygen scavenging layer in a multi-layer film which comprises the oxygen scavenging layer and an oxygen barrier layer that retards the permeation of oxygen from an external environment.

First claim

What is claimed is:

1. A composite material comprising at least one metal particle and a carbon material, wherein said carbon material is derived from a biomass material that comprises a saccharide, wherein the saccharide is selected from a monosaccharide, disaccharide, oligosaccharide or a polysaccharide; wherein the monosaccharide is selected from the group consisting of glucose, fructose and galactose; wherein the oligosaccharide is selected from the group consisting of a sugar or an amino sugar; or wherein the polysaccharide is selected from the group consisting of a cyclodextrin, a cellulose, a glycogen, a chitin and a hemicellulose, wherein said carbon material is a carbon particle or a sheet-like material having a porous structure with size of pores only in the range of 10 to 700 nm, wherein said metal particle is a zero-valent transition metal particle, and wherein said at least one metal particle is uniformly distributed on or within said carbon material.

2. The composite material according to claim 1 , wherein the saccharide is selected from the group consisting of a-cyclodextrin, 13-cyclodextrin, Y-cyclodextrin, D-glucosamine hydrochloride, L-glucosamine hydrochloride, a-D-glucose, 13-D-glucose, a-L-glucose and 13-L-glucose.

3. The composite material according to claim 1 , wherein said carbon material has a surface area in the range of 50 m 2 /g to 1000 m 2 /g.

4. The composite material according to claim 1 , wherein said carbon material acts as a support for said metal particle.

5. The composite material according to claim 4 , wherein the transition metal of said zero-valent transition metal particle is selected from the group consisting of iron particles, ruthenium particles, osmium particles, cobalt particles, rhodium particles, iridium particles, manganese particles and combinations thereof.

6. The composite material according to claim 1 , wherein said metal particle has a particle size of less than 500 nm.

7. The composite material according to claim 1 , wherein the concentration of said metal particle in the composite material is in the range of 1 to 80 wt %, based on the dry weight % of said carbon material.

8. A composition comprising
i. a composite material comprising at least one metal particle and a carbon material;
ii. an inorganic salt; and
iii. optionally an aqueous medium;
wherein said carbon material is derived from a biomass material that comprises a saccharide, wherein the saccharide is selected from a monosaccharide, disaccharide, oligosaccharide or a polysaccharide; wherein the monosaccharide is selected from the group consisting of glucose, fructose and galactose; wherein the oligosaccharide is selected from the group consisting of a sugar or an amino sugar; or wherein the polysaccharide is selected from the group consisting of a cyclodextrin, a cellulose, a glycogen, a chitin and a hemicellulose, wherein said carbon material is a carbon particle or a sheet-like material having a porous structure with size of pores only in the range of 10 to 700 nm, wherein said metal particle is a zero-valent transition metal particle, and wherein said at least one metal particle is uniformly distributed on or within said carbon material.

9. The composition according to claim 8 , wherein the inorganic salt is an electrolyte or an acidifying agent.

10. The composition according to claim 9 , wherein the electrolyte is a halide compound selected from the group consisting of an alkali metal halide, an alkaline earth metal halide and a metal halide.

11. The composition according to claim 8 , wherein the concentration of said inorganic salt is in the range of 0.1 to 20 wt %, based on the dry weight of said composite material.

12. The composition according to claim 9 , wherein said acidifying agent is a polyacid selected from the group consisting of polyacrylic acid, polymethacrylic acid, polyethylacrylic acid and polymaleic acid.

Assignees

• Agency Science Tech & Res
• Nat Univ Singapore
• Agency For Science Tech Research

Inventors

• Li Xu
• Chieng Yu Yuan
• Wong Siew Yee
• Wang Suxi
• Huang Jen-Yi
• Zhou Weibiao

Classifications

• B65D81/266

  for absorbing gases, e.g. oxygen absorbers or desiccants (B65D51/244, B65D51/30 take precedence) · CPC title

• B01J20/3236

  containing metal, other than zeolites, e.g. oxides, hydroxides, sulphides or salts · CPC title

• B01J20/3204

  Inorganic carriers, supports or substrates · CPC title

• B01J20/3085

  Chemical treatments not covered by groups B01J20/3007 - B01J20/3078 · CPC title

• B01J20/28085

  being more than 50 nm, i.e. macropores · CPC title