Method for producing resin particle dispersion, method for producing toner for electrostatic image development, and toner for electrostatic image development

Patent metadata

Field	Value
Publication number	US-12435187-B2
Application number	US-202117411663-A
Country	US
Kind code	B2
Filing date	Aug 25, 2021
Priority date	Mar 26, 2021
Publication date	Oct 7, 2025
Grant date	Oct 7, 2025

Abstract

A method for producing a resin particle dispersion includes: obtaining a phase-inverted emulsion by adding a neutralizer to a resin solution prepared by dissolving a resin having an acid value in an organic solvent to thereby neutralize the resin and then adding an aqueous medium to the resulting resin solution to subject the resin to phase inversion emulsification; and removing the organic solvent from the phase-inverted emulsion. In the course of obtaining the phase-inverted emulsion, a maximum agitation power per unit mass (kg) of the resin when the resin solution containing the aqueous medium added thereto is agitated to perform the phase inversion emulsification is from 0.4 W to 20 W inclusive.

First claim

What is claimed is:

1. A method for producing a resin particle dispersion, the method comprising:
obtaining a phase-inverted emulsion by adding a neutralizer to a resin solution prepared by dissolving a resin having an acid value in an organic solvent to thereby neutralize the resin and then adding an aqueous medium to the resulting resin solution to subject the resin to phase inversion emulsification; and
removing the organic solvent from the phase-inverted emulsion,
wherein, in the course of obtaining the phase-inverted emulsion, a maximum agitation power per unit mass (kg) of the resin when the resin solution containing the aqueous medium added thereto is agitated to perform the phase inversion emulsification is from 0.4 W to 20 W inclusive.

2. The method for producing a resin particle dispersion according to claim 1 , wherein the resin has an acid value of from 8 mg KOH/g to 20 mg KOH/g inclusive.

3. The method for producing a resin particle dispersion according to claim 1 , wherein the resin is a polyester resin.

4. The method for producing a resin particle dispersion according to claim 2 , wherein the resin is a polyester resin.

5. The method for producing a resin particle dispersion according to claim 1 , wherein the organic solvent contains at least one selected from ketones and at least one selected from alcohols,
wherein the amount of the at least one selected from ketones relative to 10 parts by mass of the resin is from 4 parts by mass to 15 parts by mass inclusive, and
wherein the amount of the at least one selected from alcohols relative to 10 parts by mass of the resin is from 1 part by mass to 5 parts by mass inclusive.

6. The method for producing a resin particle dispersion according to claim 2 , wherein the organic solvent contains at least one selected from ketones and at least one selected from alcohols,
wherein the amount of the at least one selected from ketones relative to 10 parts by mass of the resin is from 4 parts by mass to 15 parts by mass inclusive, and
wherein the amount of the at least one selected from alcohols relative to 10 parts by mass of the resin is from 1 part by mass to 5 parts by mass inclusive.

7. The method for producing a resin particle dispersion according to claim 3 , wherein the organic solvent contains at least one selected from ketones and at least one selected from alcohols,
wherein the amount of the at least one selected from ketones relative to 10 parts by mass of the resin is from 4 parts by mass to 15 parts by mass inclusive, and
wherein the amount of the at least one selected from alcohols relative to 10 parts by mass of the resin is from 1 part by mass to 5 parts by mass inclusive.

8. The method for producing a resin particle dispersion according to claim 4 , wherein the organic solvent contains at least one selected from ketones and at least one selected from alcohols,
wherein the amount of the at least one selected from ketones relative to 10 parts by mass of the resin is from 4 parts by mass to 15 parts by mass inclusive, and
wherein the amount of the at least one selected from alcohols relative to 10 parts by mass of the resin is from 1 part by mass to 5 parts by mass inclusive.

9. The method for producing a resin particle dispersion according to claim 5 , wherein the at least one selected from ketones is methyl ethyl ketone, and the at least one selected from alcohols is isopropanol.

10. The method for producing a resin particle dispersion according to claim 6 , wherein the at least one selected from ketones is methyl ethyl ketone, and the at least one selected from alcohols is isopropanol.

11. The method for producing a resin particle dispersion according to claim 7 , wherein the at least one selected from ketones is methyl ethyl ketone, and the at least one selected from alcohols is isopropanol.

12. The method for producing a resin particle dispersion according to claim 8 , wherein the at least one selected from ketones is methyl ethyl ketone, and the at least one selected from alcohols is isopropanol.

13. The method for producing a resin particle dispersion according to claim 1 , wherein the neutralizer is ammonia, and
wherein the total amount of the neutralizer added relative to 10 parts by mass of the resin is from 0.02 parts by mass to 0.06 parts by mass inclusive.

14. The method for producing a resin particle dispersion according to claim 2 , wherein the neutralizer is ammonia, and
wherein the total amount of the neutralizer added relative to 10 parts by mass of the resin is from 0.02 parts by mass to 0.06 parts by mass inclusive.

15. The method for producing a resin particle dispersion according to claim 1 , wherein the temperature of the resin solution containing the aqueous medium added thereto during the phase inversion emulsification is from 20° C. to 80° C. inclusive.

16. The method for producing a resin particle dispersion according to claim 1 , wherein the aqueous medium is continuously added to the resin solution, and
wherein the rate of addition of the aqueous medium to 10 parts by mass of the resin is from 0.03 parts by mass/min to 0.80 parts by mass/min inclusive.

17. The method for producing a resin particle dispersion according to claim 1 , wherein the phase inversion emulsification of the resin is performed using an emulsification tank equipped with an anchor mixing impeller,
wherein the ratio Di/Dt of an impeller diameter Di of the anchor mixing impeller to a tank diameter Dt of the emulsification tank is from 0.90 to 0.99 inclusive, and
wherein the number of rotations of the anchor mixing impeller is from 10 rpm to 100 rpm inclusive.

18. The method for producing a resin particle dispersion according to claim 1 , wherein a resin particle dispersion for a toner is produced.

19. A method for producing a toner for electrostatic image development, the method comprising:
forming aggregated particles by aggregating, in a dispersion containing resin particles in a resin particle dispersion obtained by the resin particle dispersion production method according to claim 1 , at least the resin particles; and
fusing and coalescing the aggregated particles by heating an aggregated particle dispersion containing the aggregated particles dispersed therein to thereby form toner particles.

20. A toner for electrostatic image development comprising toner particles obtained by the method for producing a toner for electrostatic image development according to claim 19 .

Assignees

• Fujifilm Business Innovation Corp

Inventors

• Inukai Takashi
• Yamamoto Keita

Classifications

• B01F23/4146

  Emulsions including solid particles, e.g. as solution or dispersion, i.e. molten material or material dissolved in a solvent or dispersed in a liquid · CPC title

• B01F23/4142

  Inversed-type emulsions · CPC title

• B01F23/48

  characterised by the nature of the liquids (B01F23/47 takes precedence) · CPC title

• B01F23/49

  Mixing systems, i.e. flow charts or diagrams · CPC title

• B01F23/43

  using driven stirrers · CPC title