Optical film, polarizing plate, and image display device

Patent metadata

Field	Value
Publication number	US-10459290-B2
Application number	US-201514802438-A
Country	US
Kind code	B2
Filing date	Jul 17, 2015
Priority date	Jan 18, 2013
Publication date	Oct 29, 2019
Grant date	Oct 29, 2019

Abstract

A film of 15 to 45 μm thick containing a cellulose acylate and an aromatic ester oligomer having a repeating unit derived from a dicarboxylic acid and a repeating unit derived from a diol, in which the repeating unit derived from a dicarboxylic acid has a ratio m/n of from 0/10 to 3/7, m and n represent a molar proportion of a repeating unit derived from an aliphatic dicarboxylic acid and an aromatic dicarboxylic acid, respectively, and the film satisfies |Rth(590)|≤50 nm; has a good appearance and is free of deterioration in display performance when the film with a thin thickness is produced in the form of a roll, achieves a high pencil hardness by imparting a high Knoop hardness to the film, even with a hard coat layer provided, and is free of display unevenness on installing the film in a liquid crystal display device.

First claim

What is claimed is:

1. An optical film containing a cellulose acylate film wherein:
the cellulose acylate film contains a cellulose acylate and an aromatic ester oligomer having a repeating unit derived from a dicarboxylic acid and a repeating unit derived from a diol,
the cellulose acylate film has a thickness of from 15 to 35 μm,
the repeating unit derived from a dicarboxylic acid has a ratio m/n of from 0/10 to 3/7,
wherein m represents a molar proportion of a repeating unit derived from an aliphatic dicarboxylic acid, and n represents a molar proportion of a repeating unit derived from an aromatic dicarboxylic acid, and

the cellulose acylate film satisfies the following expression (1):
| Rth (590)|≤50 nm  (1)

wherein Rth(590) represents a retardation in a thickness direction at a wavelength of 590 nm,

wherein a proportion of a repeating unit derived from ortho-phthalic acid in the repeating unit derived from the dicarboxylic acid contained in the aromatic ester oligomer is 70% by mol or more, and
wherein the Knoop hardness of the optical film is 240 or more N/mm 2 .

2. The optical film according to claim 1 , wherein the aromatic ester oligomer has a hydroxyl value of 10 mgKOH/g or less.

3. The optical film according to claim 1 , wherein the aromatic ester oligomer has both ends that each are terminated with a monocarboxylic acid residual group.

4. The optical film according to claim 3 , wherein the monocarboxylic acid residual group is an aliphatic monocarboxylic acid residual group having from 2 to 3 carbon atoms.

5. The optical film according to claim 1 , wherein the aromatic ester oligomer has a number average molecular weight Mn of from 600 to 2,000.

6. The optical film according to claim 5 , which contains the aromatic ester oligomer in an amount of from 5 to 25% by mass based on the cellulose acylate.

7. The optical film according to claim 1 , which further contains a compound having a ratio of (molecular weight)/(number of aromatic groups) of 300 or less and represented by the following general formula (2):

wherein R 11 , R 13 and R 15 each independently represent a hydrogen atom, an alkyl group having from 1 to 20 carbon atoms, a cycloalkyl group having from 3 to 20 carbon atoms, an alkenyl group having from 2 to 20 carbon atoms, or an aromatic group having from 6 to 20 carbon atoms.

8. The optical film according to claim 1 , which contains the aromatic ester oligomer in an amount of from 5 to 25% by mass based on the cellulose acylate.

9. The optical film according to claim 7 , which further contains a compound having a ratio of (molecular weight)/(number of aromatic groups) of 300 or less and represented by the general formula (2) in an amount of from 0.5 to 20% by mass based on the cellulose acylate.

10. The optical film according to claim 1 , which further contains an ultraviolet ray absorbent.

11. The optical film according to claim 1 , which further contains at least one layer of an antiglare layer, a hard coat layer, or a patterned retardation layer, on the cellulose acylate film.

12. The optical film according to claim 11 , wherein the patterned retardation layer contains a first region and a second region, the first region has an Re(550) value of from 30 to 250 nm, the second region has an Re(550) value of from 30 to 250 nm, and
wherein Re(550) represents a retardation in an in-plane retardation at a wavelength of 550 nm.

13. A polarizing plate containing an optical film containing a cellulose acylate film wherein:
the cellulose acylate film contains a cellulose acylate and an aromatic ester oligomer having a repeating unit derived from a dicarboxylic acid and a repeating unit derived from a diol,
the cellulose acylate film has a thickness of from 15 to 35 μm,
the repeating unit derived from a dicarboxylic acid has a ratio m/n of from 0/10 to 3/7,
wherein m represents a molar proportion of a repeating unit derived from an aliphatic dicarboxylic acid, and n represents a molar proportion of a repeating unit derived from an aromatic dicarboxylic acid,

the cellulose acylate film satisfies the following expression (1):
| Rth (590)|≤50 nm  (1)

wherein Rth(590) represents a retardation in a thickness direction at a wavelength of 590 nm,

wherein a proportion of a repeating unit derived from ortho-phthalic acid in the repeating unit derived from the dicarboxylic acid contained in the aromatic ester oligomer is 70% by mol or more, and
wherein the Knoop hardness of the optical film is 240 or more N/mm 2 .

14. A liquid crystal display device containing an optical film containing a cellulose acylate film wherein:
the cellulose acylate film contains a cellulose acylate and an aromatic ester oligomer having a repeating unit derived from a dicarboxylic acid and a repeating unit derived from a diol,
the cellulose acylate film has a thickness of from 15 to 35 μm,
the repeating unit derived from a dicarboxylic acid has a ratio m/n of from 0/10 to 3/7,
wherein m represents a molar proportion of a repeating unit derived from an aliphatic dicarboxylic acid, and n represents a molar proportion of a repeating unit derived from an aromatic dicarboxylic acid,

the cellulose acylate film satisfies the following expression (1):
| Rth (590)|≤50 nm  (1)

wherein Rth(590) represents a retardation in a thickness direction at a wavelength of 590 nm,

wherein a proportion of a repeating unit derived from ortho-phthalic acid in the repeating unit derived from the dicarboxylic acid contained in the aromatic ester oligomer is 70% by mol or more, and
wherein the Knoop hardness of the optical film is 240 or more N/mm 2 .

Assignees

• Fujifilm Corp

Inventors

• Hisakado Yoshiaki
• Nagura Masato
• Naito Yu
• Inoue Rikio
• Adegawa Yutaka

Classifications

• C08J5/18

  Manufacture of films or sheets · CPC title

• G02B5/3033 Primary

  in the form of a thin sheet or foil, e.g. Polaroid · CPC title

• C08J2301/10

  Esters of organic acids · CPC title

• G02B5/3083

  Birefringent or phase retarding elements (G02B5/3008, G02B5/3016 take precedence; systems for polarisation control G02B27/286; manufacturing phase modulating patterns by lithographic processes G03F7/001) · CPC title

• C08L67/03

  the dicarboxylic acids and dihydroxy compounds having the carboxyl- and the hydroxy groups directly linked to aromatic rings · CPC title