Resin composition, prepreg, film with resin, metal foil with resin, metal-clad laminated board, and wiring board

Patent metadata

Field	Value
Publication number	US-12428534-B2
Application number	US-202017763328-A
Country	US
Kind code	B2
Filing date	Sep 18, 2020
Priority date	Sep 27, 2019
Publication date	Sep 30, 2025
Grant date	Sep 30, 2025

Abstract

An aspect of the present invention relates to a resin composition, which contains a modified polyphenylene ether compound of which a terminal is modified with a substituent having a carbon-carbon unsaturated double bond and a free radical compound, in which the free radical compound has at least one free radical group selected from the group consisting of structures represented by Formulas (1), (2), (3) and (4) in a molecule.

First claim

The invention claimed is:

1. A resin composition comprising:
a modified polyphenylene ether compound of which a terminal is modified with a substituent having a carbon-carbon unsaturated double bond; and
a free radical compound,
wherein the free radical compound has at least one free radical group selected from the group consisting of structures represented by the following Formulas (1), (2), (3), and (4) in a molecule;

wherein T2 denotes a lowest melt viscosity of the resin composition and T1 denotes a melt viscosity of the resin composition at a temperature higher than a temperature having the lowest melt viscosity by 10° C., and
T1/T2 is more than 1.0 and 10.0 or less; and
wherein the free radical compound includes at least one compound selected from compounds represented by the following Formulas (7) to (9):

wherein in Formulas (7) and (8), X A represents an amino group, a cyano group, a hydroxy group, an isothiocyanate, a methoxy group, a carboxy group, a carbonyl group, an amide group, a benzoyloxy group, or an ether bond, and X B represents a hydrogen atom, an amino group, a cyano group, a hydroxy group, an isothiocyanate, a methoxy group, a carboxy group, a carbonyl group, an amide group, a benzoyloxy group, or an ether bond, and
wherein in Formula (9), X C represents an alkylene group, an aromatic structure, a carbonyl group, an amide group, or an ether bond.

2. The resin composition according to claim 1 , wherein
the substituent include at least one selected from a group represented by the following Formula (5) or a group represented by the following Formula (6) in the modified polyphenylene ether compound:

wherein in Formula (5), p represents an integer 0 to 10, Z represents an arylene group, and R 1 to R 3 each independently represent a hydrogen atom or an alkyl group,

wherein in Formula (6), R 4 represents a hydrogen atom or an alkyl group.

3. The resin composition according to claim 1 , further comprising a curing agent.

4. The resin composition according to claim 3 , wherein a content of the free radical compound is 0.01 to 0.4 parts by mass with respect to 100 parts by mass of a sum of the modified polyphenylene ether compound and the curing agent.

5. The resin composition according to claim 3 , wherein the curing agent contains at least one selected from the group consisting of a polyfunctional acrylate compound having two or more acryloyl groups in a molecule, a polyfunctional methacrylate compound having two or more methacryloyl groups in a molecule, a polyfunctional vinyl compound having two or more vinyl groups in a molecule, a styrene derivative, an allyl compound having an allyl group in a molecule, a maleimide compound having a maleimide group in a molecule, an acenaphthylene compound having an acenaphthylene structure in a molecule, and an isocyanurate compound having an isocyanate group in a molecule.

6. The resin composition according to claim 3 , further comprising a reaction initiator.

7. The resin composition according to claim 6 , wherein the reaction initiator contains at least one selected from a metal peroxide, an azo compound, or an organic peroxide.

8. The resin composition according to claim 6 , wherein a content of the reaction initiator is 0.5 to 8.0 parts by mass with respect to 100 parts by mass of a sum of the modified polyphenylene ether compound and the curing agent.

9. The resin composition according to claim 6 , wherein a proportion (mass ratio) of the free radical compound to the reaction initiator is 0.005:1.0 to 0.2:1.0.

10. The resin composition according to claim 1 , further comprising an inorganic filler.

11. A prepreg comprising:
the resin composition according to claim 1 or a semi-cured product of the resin composition; and
a fibrous base material.

12. A film with resin comprising:
a resin layer containing the resin composition according to claim 1 or a semi-cured product of the resin composition; and
a support film.

13. A metal foil with resin comprising:
a resin layer containing the resin composition according to claim 1 or a semi-cured product of the resin composition; and
a metal foil.

14. A metal-clad laminate comprising:
an insulating layer containing a cured product of the resin composition according to claim 1 ; and
a metal foil.

15. A wiring board comprising:
an insulating layer containing a cured product of the resin composition according to claim 1 ; and
wiring.

16. The wiring board according to claim 15 , comprising
a plurality of the insulating layers,
wherein the wiring is disposed between the insulating layers.

17. The resin composition according to claim 1 , wherein T2 is 12000 (poise) or less and T1 is 15000 (poise) or less.

Assignees

• Panasonic Ip Man Co Ltd

Inventors

• Wada Atsushi
• Koda Masashi
• Kozawa Ryusei
• Kitai Yuki

Classifications

• C08K5/34924

  containing cyanurate groups; Tautomers thereof · CPC title

• C08K5/3432

  Six-membered rings · CPC title

• C08K5/3415

  Five-membered rings · CPC title

• C08K5/22

  Compounds containing nitrogen bound to another nitrogen atom · CPC title

• C08K5/01

  Hydrocarbons {(C08K5/0091 takes precedence)} · CPC title