Colored watch glass

Patent metadata

Field	Value
Publication number	US-12428335-B2
Application number	US-202016791453-A
Country	US
Kind code	B2
Filing date	Feb 14, 2020
Priority date	Feb 18, 2019
Publication date	Sep 30, 2025
Grant date	Sep 30, 2025

Abstract

A transparent timepiece component, in particular a watch glass, has a substantially planar or curved interior surface, and has mainly a transparent material colored by a zone of modified chemical composition within the component through an introduction of at least one coloring chemical element of the transparent material, this zone of modified chemical composition extending in one part only of the total thickness of the timepiece component.

First claim

The invention claimed is:

1. A timepiece comprising a watch case and a transparent timepiece component which is a watch glass assembled with the watch case, the watch glass comprising:
a substantially planar or curved interior surface, the interior surface being oriented towards an inside of the watch case,
an exterior surface opposed to the interior surface, the exterior surface being oriented towards an outside of the watch case,
a peripheral lateral surface linking the exterior surface and the interior surface, and
mainly a transparent material, wherein the transparent material is an inorganic and/or mineral material or a material composed at least partially of inorganic and/or mineral matter,
wherein the transparent material is colored by a zone of modified chemical composition within the timepiece component through an introduction of at least one coloring chemical element into the transparent material, wherein the at least one coloring chemical element is selected from the group consisting of metals, metal oxides, metal compounds, metal alloys, transition metals, transition metal oxides, metalloids, non-metals, and gases,
wherein the zone of modified chemical composition extends in only an interior surface layer having a thickness representing on average at most 25% of a total thickness of the timepiece component, the interior surface layer including the interior surface, wherein the zone of modified chemical composition does not extend to the exterior surface,
wherein, in the zone of modified chemical composition observed from outside of the exterior surface, (i) a color is seen as uniform on at least a portion of the exterior surface and at least a portion of the lateral surface, the portion of the exterior surface and the portion of the lateral surface having an inclination in a range of from 10 degrees to 60 degrees relative to each other, and/or (ii) a color is seen as forming a color gradient on at least a portion of the exterior surface,
wherein the zone of modified chemical composition includes a gradient of thickness that modulates a watch glass coloring effect to obtain (i) the color seen as uniform on the at least one portion of the exterior surface and the at least one portion of the lateral surface, and/or (ii) the color seen as forming the color gradient on the at least one portion of the exterior surface.

2. The timepiece as claimed in claim 1 , wherein the zone of modified chemical composition extends on the side of the interior surface over a thickness representing on average at least 0.0002% of the total thickness of the timepiece component.

3. The timepiece as claimed in claim 1 , wherein the at least one coloring chemical element is selected from the group consisting of cobalt, iron, chromium, gold, titanium, vanadium, copper, manganese, magnesium, zinc, silver, boron, and nitrogen.

4. The timepiece as claimed in claim 1 , wherein
the zone of modified chemical composition comprises cobalt aluminate and/or cobalt so that the timepiece component has a blue and/or green color, or
the zone of modified chemical composition comprises gold so that the timepiece component has a pink or red color.

5. The timepiece as claimed in claim 1 , wherein the interior surface has an area greater than or equal to 20 mm 2 and the timepiece component has a thickness greater than or equal to 0.85 mm.

6. The timepiece as claimed in claim 5 , wherein at least one of the following:
the timepiece component is transparent, so as to allow indications to be read through the thickness of the component, and/or charging and/or discharging of a photoluminescent material through the thickness of the component, and/or
the timepiece component comprises a transmission factor greater than or equal to 68%.

7. The timepiece as claimed in claim 6 , wherein at least one of the following:
the timepiece component comprises raised and/or set-back structured zones on at least one surface of the timepiece component,
the timepiece component comprises structured zones within the thickness of the timepiece component.

8. The timepiece as claimed in claim 7 , wherein an area of the portion of the lateral surface having an inclination of from 10 degrees or more to 60 degrees relative to the portion of the exterior surface represents from 1% to 30% of an area of the interior surface.

9. The timepiece as claimed in claim 1 , wherein the interior surface has an area greater than or equal to 80 mm 2 , and the timepiece component has a thickness in a range of from 0.2 mm to 15 mm.

10. The timepiece as claimed in claim 1 , wherein, in the zone of modified chemical composition observed from outside of the exterior surface, the color is seen as uniform on at least the portion of the external surface and the portion of the lateral surface having an inclination in the range of from 10 degrees to 60 degrees relative to each other.

11. The timepiece as claimed in claim 1 , wherein, in the zone of modified chemical composition observed from outside of the exterior surface, the color is seen as forming the color gradient on at least the portion of the external surface.

12. A process for manufacturing a colored and transparent timepiece, wherein the process comprises:
a) providing an initial substrate which comprises a substantially planar or curved interior surface composed mainly of a transparent material;
b) introducing at least one coloring chemical element via at least one exterior or interior surface of the initial substrate;
c) performing heat treatment of the substrate resulting from the introducing and comprising at least one coloring chemical element,
so as to obtain the timepiece as claimed in claim 1 wherein the timepiece component is a transparent and colored piece.

13. The process as claimed in claim 12 , wherein the introducing comprises at least one of the following:
depositing a coating comprising at least one coloring chemical element on at least one surface of the initial substrate, and/or
performing recoil ion implantation of at least one coloring chemical element.

14. The process as claimed in claim 13 , wherein the introducing comprises depositing a coating having a thickness in a range from 1 nm to 10 μm.

15. The process as claimed in claim 12 , wherein the introducing comprises depositing a coating and before the depositing, masking a surface of the substrate so as to prevent the substrate from receiving the coating and/or so as to form the coating having a variable thickness.

16. The process as claimed in claim 12 , wherein the heat treatment comprises a hold at a hold temperature in a range of from 500° C. to 1850° C., for a duration in a range of from 0.5 hour to four days.

17. The process as claimed in claim 12 , wherein the process comprises all or some of the following additional actions:
a) machining the transparent and colored piece so as to form the timepiece component;
b) machining at least one surface of the transparent and colored piece so as to modify a shape of the timepiece component and/or to form a feature of the timepiece component and/or to form a lateral surface inclined relative to an exterior surface of the timepiece component, having an inclination greater than or equal to 10 degrees relative to the direction perpendicular to the interior surface, so as to modulate the timepiece component coloring effect;
c) assembling the transparent and colored piece with another timepiece component;
d) removing a residue of coloring chemical element from a surface of the transparent and colored piece; and/or
e) etching a feature into the timepiece component.

Assignees

• Rolex Sa

Inventors

• Borges-Machado Maria-Isabel
• Roulet Alexandra

Classifications

• C30B33/08

  Etching · CPC title

• C30B33/02

  Heat treatment (C30B33/04, C30B33/06 take precedence) · CPC title

• C30B29/20 Primary

  Aluminium oxides · CPC title

• C23C14/0015

  characterized by the colour of the layer · CPC title

• C30B31/02

  by contacting with diffusion materials in the solid state · CPC title