Process and apparatus for improved recovery of argon

Patent metadata

Field	Value
Publication number	US-12385692-B2
Application number	US-202217968203-A
Country	US
Kind code	B2
Filing date	Oct 18, 2022
Priority date	Oct 18, 2022
Publication date	Aug 12, 2025
Grant date	Aug 12, 2025

Abstract

A process and apparatus for recovering at least argon from a feed gas that can provide an improved recovery of argon as well as an improvement in operational efficiency. Some embodiments can be adapted so that the improved argon recovery can also be obtained with improved condenser operation for an argon column without requiring an increase in power for the recovery of the argon. Some embodiments can utilize a reboiler positioned near or at the bottom of argon recovery column to increase boil-up therein and/or provide added heat duty to drive a condenser of the argon recovery column to provide improved argon recovery.

First claim

What is claimed is:

1. A process for separation of a feed gas comprising oxygen, nitrogen, and argon, the process comprising:
compressing a feed gas via a compression system of a separation system having a first column and a second column, the first column being a high pressure (HP) column operating at a pressure that is higher than the second column, the second column being a low pressure (LP) column operating at a pressure that is lower than the first column;
feeding the compressed feed gas to a first heat exchanger to cool the compressed feed gas;
feeding at least a first portion of the compressed and cooled feed gas to the HP column to produce an HP oxygen-enriched stream;
passing the HP oxygen-enriched stream output from the HP column through a reboiler positioned between the HP column and an argon enrichment column;
passing an argon depleted fluid stream output from the argon enrichment column to the reboiler so that the HP oxygen-enriched stream is cooled via heat transfer with the argon depleted fluid stream or passing an LP argon-enriched stream output from the LP column to the reboiler so that the HP oxygen-enriched stream is cooled via heat transfer with the LP argon-enriched stream;
the reboiler outputting the HP oxygen-enriched stream after the HP oxygen-enriched stream is cooled; and
passing at least a portion of the HP oxygen-enriched stream output from the reboiler to a reboiler-condenser of the argon enrichment column for condensing at least a portion of an argon-enriched vapor output from the argon enrichment column that is fed to the reboiler-condenser.

2. The process of claim 1 , wherein the reboiler is positioned in a bottom of the argon enrichment column or within the argon enrichment column.

3. The process of claim 1 , wherein the passing of at least a portion of the HP oxygen-enriched stream output from the reboiler to the reboiler-condenser of the argon enrichment column for condensing at least a portion of the argon-enriched vapor output from the argon enrichment column that is fed to the reboiler-condenser comprises:
splitting the HP oxygen-enriched stream output from the reboiler to form a first oxygen-enriched stream to feed to the LP column and a second oxygen-enriched stream to feed to the reboiler-condenser of the argon enrichment column.

4. The process of claim 1 , wherein the passing of at least a portion of the HP oxygen-enriched stream output from the reboiler to the reboiler-condenser of the argon enrichment column for condensing at least a portion of the argon-enriched vapor output from the argon enrichment column that is fed to the reboiler-condenser comprises:
passing an entirety of the HP oxygen-enriched stream output from the reboiler to the reboiler-condenser of the argon enrichment column.

5. The process of claim 1 , comprising:
the HP column outputting a second column reflux stream to feed the second column reflux stream to the LP column.

6. The method of claim 1 , wherein the passing of the argon depleted fluid stream output from the argon enrichment column to the reboiler so that the HP oxygen-enriched stream is cooled via heat transfer with the argon depleted fluid stream is performed.

7. The method of claim 1 , wherein the passing of the LP argon-enriched stream output from the LP column to the reboiler so that the HP oxygen-enriched stream is cooled via heat transfer with the LP argon-enriched stream is performed.

8. A separation system comprising:
a first column and a second column, the first column being a high pressure (HP) column operating at a pressure that is higher than the second column, the second column being a low pressure (LP) column operating at a pressure that is lower than the first column, the HP column being connected to the LP column;
an argon enrichment column;
a reboiler;
the HP column connected to the reboiler so that an HP oxygen-enriched stream output from the HP column is feedable to the reboiler for cooling of the HP oxygen-enriched stream;
the reboiler positioned to receive an argon depleted fluid stream output from the argon enrichment column so that the HP oxygen-enriched stream is coolable via heat transfer with the argon depleted fluid stream; and
the reboiler connected to a reboiler-condenser of the argon enrichment column so that at least a portion of the HP oxygen-enriched stream is feedable to the reboiler-condenser for condensing at least a portion of an argon-enriched vapor output from the argon enrichment column that is feedable to the reboiler-condenser.

9. The separation system of claim 8 , wherein the reboiler is positioned in a bottom of the argon enrichment column.

10. The separation system of claim 8 , wherein the HP column is connected to the LP column such that a second column reflux stream outputtable from the HP column is feedable to the second column reflux stream to the LP column.

11. The separation system of claim 8 , wherein the reboiler is connected to the reboiler-condenser of the argon enrichment column and the LP column such that the HP oxygen-enriched stream outputtable from the reboiler is splittable into a first oxygen-enriched stream to feed to the LP column and a second oxygen-enriched stream to feed to the reboiler-condenser of the argon enrichment column.

12. The separation system of claim 8 , wherein the reboiler is connected to the reboiler-condenser of the argon enrichment column such than an entirety of the HP oxygen-enriched stream outputtable from the reboiler is feedable to the reboiler-condenser of the argon enrichment column.

13. A method of retrofitting an air separation unit, comprising:
positioning a reboiler between a high pressure (HP) column and an argon enrichment column so that an HP oxygen-enriched stream output from an HP column is feedable to the reboiler to cool the HP oxygen-enriched stream and (i) so that an argon depleted fluid stream output from the argon enrichment column is feedable to the reboiler so that the HP oxygen-enriched stream feedable to the reboiler is coolable via heat transfer with the argon depleted fluid stream or (ii) so that a low pressure (LP) argon-enriched stream output from a second column is feedable to the reboiler so that the HP oxygen-enriched stream is coolable via heat transfer with the LP argon-enriched stream;
connecting the reboiler to a reboiler-condenser of the argon enrichment column so that at least a portion of the HP oxygen enriched stream output from the reboiler is feedable to the reboiler-condenser for condensing at least a portion of an argon-enriched vapor outputtable from the argon enrichment column that is feedable to the reboiler-condenser.

14. The method of claim 13 , wherein the reboiler is positioned in a bottom of the argon enrichment column or within a lower portion of the argon enrichment column.

15. The method of claim 13 , wherein the positioning of the reboiler includes adjusting conduits to accommodate use of the reboiler.

16. The method of claim 13 , wherein the reboiler is positioned so that the argon depleted fluid stream output from the argon enrichment column is feedable to the reboiler so that the HP oxygen-enriched stream feedable to the reboiler is coolable via heat transfer with the argon depleted fluid stream.

17. The method of claim 13 , wherein the reboiler is positioned so that the LP argon-enriched stream output from the second column is feedable to the reboiler so that the HP oxygen-enriched stream is coolable via heat transfer with the LP argon-enriched stream.

Assignees

• Air Prod & Chem

Inventors

• Thakkar Jay A
• Herron Donn Michael
• Zhao Qiao

Classifications

• F25J2270/50

  Quasi-closed internal or closed external oxygen refrigeration cycle · CPC title

• F25J2270/42

  Quasi-closed internal or closed external nitrogen refrigeration cycle · CPC title

• F25J2200/74

  Refluxing the column with at least a part of the partially condensed overhead gas · CPC title

• F25J2200/40

  Features relating to the provision of boil-up in the bottom of a column · CPC title

• F25J2200/34

  using a side column fed by a stream from the low pressure column · CPC title