Fluid recovery process and apparatus

Patent metadata

Field	Value
Publication number	US-11512897-B2
Application number	US-202117148758-A
Country	US
Kind code	B2
Filing date	Jan 14, 2021
Priority date	Jan 14, 2021
Publication date	Nov 29, 2022
Grant date	Nov 29, 2022

Abstract

A process for recovering at least one fluid (e.g. argon gas and/or nitrogen gas, etc.) from a feed gas (e.g. air) can include utilization of a compression system, primary heat exchanger unit, plant processing units to separate and recover at least one desired fluid (e.g. nitrogen gas, argon gas, etc.). In some embodiments, the process can be configured so that fluid flows output from a low pressure column and/or high pressure column of the plant can provide a condensation duty or refrigeration duty that is utilized to process certain fluid flows for recovery of argon and/or nitrogen gases. Some embodiments can be configured to provide an improved recovery of argon and/or nitrogen as well as an improvement in operational efficiency by reducing an amount of power (e.g. electrical power) needed to recover the nitrogen and/or argon.

First claim

What is claimed is:

1. A process for separation of a feed gas comprising oxygen, nitrogen, and argon, the process comprising:
compressing a feed gas via a compression system of a separation system having a first column and a second column, the first column being a high pressure (HP) column operating at a pressure that is higher than the second column, the second column being a low pressure (LP) column operating at a pressure that is lower than the first column;
feeding the compressed feed gas to a first heat exchanger to cool the compressed feed gas;
feeding at least a first portion of the compressed and cooled feed gas to the HP column to produce a first HP nitrogen-enriched vapor and a first HP oxygen-enriched stream;
condensing at least a portion of the first HP nitrogen-enriched vapor via a first reboiler-condenser to form an HP condensate so that a first portion of the HP condensate is recyclable to the HP column;
outputting a first nitrogen-enriched stream, a first LP oxygen-rich liquid steam, and a first argon-enriched vapor stream from the LP column, the first LP oxygen-rich liquid having an oxygen content of at least 98 mol % oxygen;
feeding the first argon-enriched vapor stream to an argon column to form a first argon-rich vapor stream that is feedable to a second reboiler-condenser and an argon-depleted liquid stream that is feedable to the LP column;
at least partially condensing the first argon-rich vapor stream output from the argon column via the second reboilier-condenser;
mixing the first nitrogen-enriched stream output from the LP column with the first LP oxygen-rich liquid stream output from the LP column for forming a mixed nitrogen-oxygen fluid stream to feed to the second reboiler-condenser to provide at least a portion of a refrigeration duty of the second reboiler-condenser for the at least partially condensing of the first argon-rich vapor stream.

2. The process of claim 1 , the process also comprising:
splitting the compressed feed gas into the first portion and a second portion; and
feeding the second portion of the compressed feed gas to an expander for reducing its pressure for feeding it to the LP column after the second portion of the compressed feed gas is passed through the first heat exchanger.

3. The process of claim 1 , wherein the feed gas is air and the compression system includes a purification unit that removes at least one of carbon dioxide and water from the feed gas after the feed gas is compressed, and wherein the process also comprises:
passing a first nitrogen-rich vapor stream output from the LP column and a second portion of the HP condensate output from the first reboiler-condenser through a subcooler so that the second portion of the HP condensate is cooled via the subcooler before the second portion of the HP condensate is fed to the LP column.

4. The process of claim 1 , wherein the first nitrogen-enriched stream is a first nitrogen-enriched liquid waste stream and wherein the mixed nitrogen-oxygen fluid stream is a mixture of the first nitrogen-enriched liquid waste stream and the first LP oxygen-rich liquid stream.

5. The process of claim 1 , wherein the first nitrogen-enriched stream is a first nitrogen-enriched vapor waste stream and wherein the mixed nitrogen-oxygen fluid stream is a mixture of the first nitrogen-enriched vapor waste stream and the first LP oxygen-rich liquid stream.

6. The process of claim 1 , wherein the first nitrogen-enriched stream is a first nitrogen-enriched vapor waste stream and wherein the mixing includes:
mixing the first nitrogen-enriched vapor waste stream with the first LP oxygen-rich liquid stream to form a mixture and subsequently feeding the mixture to a phase separator to form the mixed nitrogen-oxygen fluid stream.

7. The process of claim 6 , wherein the mixed nitrogen-oxygen fluid stream is a liquid.

8. The process of claim 1 , wherein the first nitrogen-enriched waste stream is a first nitrogen-enriched vapor waste stream and wherein the mixing is performed via a mixing column, the first nitrogen-enriched vapor waste stream and the first LP oxygen-rich liquid stream being fed to the mixing column to perform the mixing to form the mixed nitrogen-oxygen fluid stream.

9. The process of claim 8 , wherein the mixed nitrogen-oxygen fluid stream is a liquid.

10. The process of claim 1 , wherein a second nitrogen-enriched stream is output from the LP column, the first nitrogen-enriched stream being a first nitrogen-enriched vapor waste stream and the second nitrogen-enriched stream being a first nitrogen-enriched liquid waste stream, and wherein the mixing is performed via a mixing column, the first nitrogen-enriched liquid waste stream, the first nitrogen-enriched vapor waste stream and the first LP oxygen-rich liquid stream being fed to the mixing column to perform the mixing to form the mixed nitrogen-oxygen fluid stream.

11. The process of claim 10 , wherein the first nitrogen-enriched liquid waste stream is fed adjacent to or at a bottom of the mixing column and the first LP oxygen-rich liquid is fed adjacent a top of the mixing column.

12. The process of claim 1 , wherein the at least the portion of the refrigeration duty of the second reboiler-condenser for the at least partially condensing of the first argon-rich vapor stream is an entirety of the refrigeration duty for the at least partially condensing of the first argon-rich vapor stream.

13. The process of claim 1 , wherein the at least partially condensing of the first argon-rich vapor stream is a complete condensing of the first argon-rich vapor so that a second reboiler-condenser output stream of the second reboiler-condenser is an argon-rich liquid.

14. A separation system comprising:
a compression system;
a first heat exchanger;
a first column and a second column, the first column being a high pressure (HP) column operating at a pressure that is higher than the second column, the second column being a low pressure (LP) column operating at a pressure that is lower than the first column;
a first reboiler-condenser; and
a second reboiler-condenser;
the compression system, the first heat exchanger, and the HP column positioned and arranged so that a feed gas is compressible via the compression system before the compressed feed gas is fed to the first heat exchanger and at least a first portion of the compressed feed gas is feedable to the HP column after passing through the first heat exchanger;
the HP column positioned and configured to produce a first HP nitrogen-enriched vapor stream and a first HP oxygen-enriched stream;
the first reboiler-condenser positioned to receive at least a portion of the first HP nitrogen-enriched vapor to form an HP condensate so that a first portion of the HP condensate is recyclable to the HP column;
the LP column positioned and configured to output a first nitrogen-enriched stream, a first LP oxygen-rich liquid steam, and a first argon-enriched vapor stream, the first LP oxygen-rich liquid stream having an oxygen content of at least 98 mol % oxygen;
an argon column positioned and configured to receive the first argon-enriched vapor stream output from the LP column to form a first argon-rich vapor stream that is feedable to the second reboiler-condenser and an argon-depleted liquid stream that is feedable to the LP column;
the second reboiler-condenser positioned and configured to at least partially condense the first argon-rich vapor stream; and
separation the system configured such that the first nitrogen-enriched waste stream output from the LP column is mixable with the first LP oxygen-rich stream output from the LP column for forming

Assignees

• Air Prod & Chem

Inventors

• Herron D Michael
• Berger Alan D

Classifications

• F25J2250/42

  One fluid being nitrogen · CPC title

• F25J3/04084

  of nitrogen · CPC title

• F25J2210/58

  Argon · CPC title

• F25J2245/42

  the recycled stream being nitrogen · CPC title

• F25J3/0423

  Subcooling of liquid process streams · CPC title