Polymer composite

Patent metadata

Field	Value
Publication number	US-12378374-B2
Application number	US-202217925484-A
Country	US
Kind code	B2
Filing date	Mar 7, 2022
Priority date	Mar 5, 2021
Publication date	Aug 5, 2025
Grant date	Aug 5, 2025

Abstract

The present disclosure relates to a polymer composite. According to the present disclosure, there is provided a polymer composite capable of exhibiting improved light resistance while being environmentally friendly by containing microcellulose fibers fibrillated by the growth of inorganic particles as a reinforcing material.

First claim

The invention claimed is:

1. A polymer composite containing a polymer matrix;
microcellulose fibers; and a compatibilizer, and satisfying Equation 1:
2 ≤Δ E* ab ≤15  [Equation 1]

in the Equation 1,
ΔE* ab is a color difference of the polymer composite, and the color difference is obtained according to formula of [(L* t −L* 0 ) 2 + (a* t −a* 0 ) 2 + (b* t −b* 0 ) 2 ] 1/2 in L*a*b* color space measured using a colorimeter,
wherein L* 0 , a* 0 and b* 0 are initial chromaticity values of the polymer composite, and
L* t , a* t and b* t are chromaticity values of the polymer composite after exposing the polymer composite to a fluorescent UV lamp for 480 hours under conditions of 0.75 W/(m 2 ·nm) at 340 nm and 45±1° C.,
wherein the microcellulose fibers comprise nanofibrils and inorganic particles, wherein the nanofibrils are bonded to a surface of the microcellulose fibers, and the inorganic particles are bonded to the nanofibrils or bonded to a surface or inside of the microcellulose fibers.

2. The polymer composite of claim 1 ,
wherein the microcellulose fibers have a minor axis diameter of 1 μm to 30 μm, and
the nanofibrils have a minor axis diameter of 10 nm to 400 nm.

3. The polymer composite of claim 1 ,
wherein the inorganic particles comprise spherical particles having a diameter of 0.01 μm to 10 μm; columnar particles having a diameter of 0.01 μm to 10 μm on one axis and a diameter of 0.02 μm to 30 μm on another axis; or a mixture thereof.

4. The polymer composite of claim 1 ,
wherein the inorganic particles comprise at least one element of copper, zinc, calcium, aluminum, iron, silver, platinum, palladium, ruthenium, iridium, rhodium, osmium, chromium, cobalt, nickel, manganese, vanadium, molybdenum, magnesium, strontium, titanium, zirconium, hafnium, or gallium.

5. The polymer composite of claim 1 ,
wherein the inorganic particles are contained in an amount of 1 to 40 parts by weight based on 100 parts by weight of the microcellulose fibers.

6. The polymer composite of claim 1 ,
wherein the polymer composite contains 30 to 90 wt % of the polymer matrix;
5 to 60 wt % of the microcellulose fibers; and
1 to 20 wt % of the compatibilizer.

7. The polymer composite of claim 1 ,
wherein the polymer matrix is at least one polymer selected from the group consisting of polyolefin, polyamide, styrenic polymer, and polycarbonate.

8. The polymer composite of claim 1 ,
wherein the compatibilizer comprises a modified polyolefin.

9. The polymer composite of claim 1 ,
wherein the polymer composite has a tensile strength of 35 MPa to 65 MPa as measured according to ASTM D638-5 for an ASTM D638-5 standard specimen prepared from the polymer composite is 35 MPa to 65 MPa.

10. The polymer composite of claim 1 ,
wherein the polymer composite has a flexural strength of 50 MPa to 85 MPa as measured according to ISO 178 for a specimen having a size of 80 mm×10 mm×4 mm prepared from the polymer composite.

11. The polymer composite of claim 1 ,
wherein the polymer composite has a flexural modulus of 1.0 GPa to 3.5 GPa as measured according to ISO 178 for a specimen having a size of 80 mm×10 mm×4 mm prepared from the polymer composite.

12. The polymer composite of claim 1 ,
wherein the microcellulose fibers and the compatibilizer are dispersed in the polymer matrix.

13. The polymer composite of claim 8 ,
wherein the modified polyolefin is a resin obtained by modifying a polyolefin with an unsaturated carboxylic acid or a derivative thereof.

Assignees

• Lg Chemical Ltd

Inventors

• Kim Yulliana
• Kim In Young
• Jeon Kwang Seoung
• Park Minsung
• Choi Ji Hwan

Classifications

• C08K7/02

  Fibres or whiskers · CPC title

• C08J2323/12

  Polypropene · CPC title

• C08J2301/02

  Cellulose; Modified cellulose · CPC title

• C08J3/22

  using masterbatch techniques · CPC title

• C08L2205/16

  Fibres; Fibrils · CPC title