Fiber reinforced polypropylene composite

Patent metadata

Field	Value
Publication number	US-10450452-B2
Application number	US-201716318682-A
Country	US
Kind code	B2
Filing date	Jul 18, 2017
Priority date	Aug 3, 2016
Publication date	Oct 22, 2019
Grant date	Oct 22, 2019

Abstract

The present invention relates to a new composite comprising cellulose-based fiber and polymer-based fiber as well as to a process for the preparation of the composite and molded articles made from said composite.

First claim

The invention claimed is:

1. A composite having an elongation at break in the range from 2.5 to 7.5%, the composite comprising:
a) 25 to 92.5 wt. %, based on the total weight of the composite, of a polypropylene base material having a melt flow rate MFR 2 (230° C., 2.16 kg) measured according to ISO 1133 in the range of from 3.0 to 140.0 g/10 min, wherein the polypropylene base material is;
i) a heterophasic propylene copolymer (HECO) comprising a (semicrystalline) polypropylene (PP) as a matrix in which an elastomeric propylene copolymer (EC) is dispersed; or
ii) a propylene homopolymer (hPP); and

b) 5 to 50 wt. %, based on the total weight of the composite, of a cellulose-based fiber (CF); and
c) 2.5 to 25 wt. %, based on the total weight of the composite, of a polymer-based fiber (PF) having a melting temperature of ≥210° C.,
wherein the weight ratio of the cellulose-based fiber (CF) and the polymer-based fiber (PF) [(CF)/(PF)] is in the range of 2.0 to 20.0.

2. The composite according to claim 1 , wherein the heterophasic propylene copolymer (HECO) has:
a) a melt flow rate MFR 2 (230° C., 2.16 kg) in the range of from 5.0 to 120.0 g/10 min, and/or
b) a xylene cold soluble (XCS) fraction (25° C.) of from 15.0 to 50.0 wt. %, based on the total weight of the heterophasic propylene copolymer (HECO), and/or
c) a comonomer content of ≤30.0 mol. %, based on the heterophasic propylene copolymer (HECO).

3. The composite according to claim 1 , wherein the amorphous fraction (AM) of the heterophasic propylene copolymer (HECO) has:
a) a comonomer content in the range of 30.0 to 60.0 mol. %, based on the amorphous fraction (AM) of the heterophasic propylene copolymer (HECO), and/or
b) an intrinsic viscosity (IV) in the range of 1.8 to 4.0 dl/g.

4. The composite according to claim 1 , wherein the propylene homopolymer (hPP) has:
a) a melt flow rate MFR 2 (230° C., 2.16 kg) in the range of from 5.0 to 120.0 g/10 min, and/or
b) a melting temperature measured according to ISO 11357-3 of at least 150° C., and/or
c) a xylene cold soluble (XCS) content, below 4.5 wt. %, based on the total weight of the propylene homopolymer (hPP).

5. The composite according to claim 1 , wherein the cellulose-based fiber (CF):
a) is selected from the group consisting of wood, flax, hem, jute, straw, rice, hardboard, cardboard, paper, pulp, raw cellulose, cellulose, cellulose acetate, cellulose triacetate, cellulose propionate, cellulose acetate propionate, cellulose acetate butyrate, nitrocellulose, methylcellulose, ethylcellulose, ethyl methyl cellulose, hydroxyethyl cellulose, hydroxypropyl cellulose (HPC), hydroxyethyl methyl cellulose, hydroxypropyl methyl cellulose (HPMC), ethyl hydoxyethyl cellulose, carboxymethyl cellulose (CMC), and any mixtures thereof, and/or
b) has a volume moment mean (D[4.3]) diameter between 1 and 1 200 μm.

6. The composite according to claim 1 , wherein the polymer-based fiber (PF) is selected from a poly vinyl alcohol (PVA) fiber, a polyethylene terephthalate (PET) fiber, a polyamide (PA) fiber and mixtures thereof.

7. The composite according to claim 1 , wherein the polymer-based fiber (PF) has:
i) a fiber average diameter in the range of 10 to 30 μm, and/or
ii) a tenacity of from 3.0 cN/dtex to 17 cN/dtex.

8. The composite according to claim 1 , wherein the polymer-based fiber (PF) has a melting temperature Tm according to ISO 11357-3 which is ≥42° C., above the melting temperature Tm according to ISO 11357-3 of the polypropylene base material.

9. The composite according to claim 1 , wherein the weight ratio of the cellulose-based fiber (CF) and the polymer-based fiber (PF) [(CF)/(PF)] is in the range of 2.0 to 10.0.

10. The composite according to claim 1 , wherein the composite comprises an adhesion promoter (AP) in an amount from 0.1 to 6.0 wt. %, based on the total weight of the composite.

11. A process for the preparation of a composite according to claim 1 , comprising the steps of:
a) providing a polypropylene base material,
b) providing a cellulose-based fiber (CF),
c) providing a polymer-based fiber (PF),
d) melt-blending the cellulose-based fiber (CF) of step b) with the polypropylene base material of step a) such as to obtain a cellulose-based fiber reinforced polypropylene base material,
e) impregnating the polymer-based fiber (PF) of step c) with the polypropylene base material of step a) such as to obtain a polymer-based fiber reinforced polypropylene base material,
f) blending the cellulose-based fiber reinforced polypropylene base material obtained in step d) and the polymer-based fiber reinforced polypropylene base material obtained in step e), and
g) injection molding the blend obtained in step f),
wherein step e) is carried out by pultrusion.

12. The process according to claim 11 , wherein process step d) is carried out by extrusion and/or the polymer-based fiber (PF) of step c) is a continuous fiber.

13. The process according to claim 11 , wherein process step e) comprises impregnating and coating the polymer-based fiber (PF) of step c) with the polypropylene base material (PBM) of step a), wherein impregnating and coating is carried out with the same or different polypropylene base material (PBM).

14. A molded article comprising a composite according to claim 1 .

15. The molded article according to claim 14 being an automotive article.

Assignees

• Borealis Ag

Inventors

• Lummerstorfer Thomas
• Jerabek Michael
• Sobczak Lukas
• Pretschuh Claudia

Classifications

• C08L2205/16

  Fibres; Fibrils · CPC title

• C08L2207/02

  Heterophasic composition · CPC title

• B29K2201/12

  Cellulose acetate · CPC title

• C08L77/00

  Compositions of polyamides obtained by reactions forming a carboxylic amide link in the main chain (of polyhydrazides C08L79/06; of polyamideimides or polyamide acids C08L79/08); Compositions of derivatives of such polymers · CPC title

• C08L23/12 Primary

  Polypropene · CPC title