Long-life and ultra-high energy density lithium secondary battery
US-2020251728-A1 · Aug 6, 2020 · US
US12374727B2 · US · B2
| Field | Value |
|---|---|
| Publication number | US-12374727-B2 |
| Application number | US-202017635254-A |
| Country | US |
| Kind code | B2 |
| Filing date | Sep 22, 2020 |
| Priority date | Sep 23, 2019 |
| Publication date | Jul 29, 2025 |
| Grant date | Jul 29, 2025 |
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The present invention provides a battery system including one or more secondary batteries each including a negative electrode including a silicon-based active material, a positive electrode facing the negative electrode, a separator interposed between the negative electrode and the positive electrode, and an electrolyte and a control unit configured to set a driving voltage range for charging and discharging of the secondary batteries, wherein a maximum driving voltage of the secondary battery set by the control unit is in a range of 4.00 V to 4.08 V, and a minimum driving voltage of the secondary battery set by the control unit is in a range of 2.98 V to 3.07 V.
Opening claim text (preview).
The invention claimed is: 1. A battery system comprising: one or more secondary batteries each including a negative electrode including a silicon-based active material, a positive electrode facing the negative electrode, a separator interposed between the negative electrode and the positive electrode, and an electrolyte; and a control unit configured to set a driving voltage range for charging and discharging of the secondary batteries, wherein a maximum driving voltage of the secondary battery set by the control unit is in a range of 4.00 V to 4.08 V, and a minimum driving voltage of the secondary battery set by the control unit is in a range of 2.98 V to 3.07 V. 2. The battery system of claim 1 , wherein the silicon-based active material is silicon (Si). 3. The battery system of claim 1 , wherein the negative electrode includes a negative electrode current collector and a negative electrode active material layer disposed on the negative electrode current collector, and the negative electrode active material layer includes the silicon-based active material, a binder, and a conductive material. 4. The battery system of claim 3 , wherein the binder includes at least one selected from the group consisting of styrene butadiene rubber, acrylonitrile butadiene rubber, acrylic rubber, butyl rubber, fluoro rubber, polyvinyl alcohol, carboxymethylcellulose, starch, hydroxypropylcellulose, regenerated cellulose, polyvinyl alcohol, polyacrylic acid, polyethylene glycol, polyacrylonitrile, and polyacryl amide. 5. The battery system of claim 3 , wherein the silicon-based active material is included in the negative electrode active material layer in an amount of 60 wt % to 90 wt %, the binder is included in the negative electrode active material layer in an amount of 5 wt % to 30 wt %, and the conductive material is included in the negative electrode active material layer in an amount of 5 wt % to 20 wt %. 6. The battery system of claim 3 , wherein the negative electrode active material layer has a thickness of 35 μm to 50 μm. 7. The battery system of claim 1 , wherein an N/P ratio of the secondary battery calculated by Equation 1 below is in a range of 1.5 to 3.5, N/P ratio=discharge capacity per unit area of negative electrode/discharge capacity per unit area of positive electrode. [Equation 1] 8. The battery system of claim 1 , wherein: a positive electrode active material includes a lithium-transition metal composite oxide, and the lithium-transition metal composite oxide includes lithium and at least one transition metal selected from the group consisting of nickel, cobalt, manganese, and aluminum. 9. A battery pack comprising the battery system of claim 1 . 10. A method of using a battery system, comprising: manufacturing a battery system including one or more secondary batteries and a control unit that is configured to set a driving voltage range for charging and discharging of the secondary batteries; and setting the driving voltage range such that a maximum driving voltage of the secondary battery is in a range of 4.00 V to 4.08 V and a minimum driving voltage of the secondary battery is in a range of 2.98 V to 3.07 V through the control unit and the charging and discharging the secondary battery for at least one cycle, wherein the secondary battery includes a negative electrode including a silicon-based active material, a positive electrode facing the negative electrode, a separator interposed between the negative electrode and the positive electrode, and an electrolyte.
acting upon multiple batteries simultaneously or sequentially · CPC title
Positive electrodes · CPC title
Negative electrodes · CPC title
Physical characteristics, e.g. porosity, surface area · CPC title
Rocking-chair batteries, i.e. batteries with lithium insertion or intercalation in both electrodes; Lithium-ion batteries · CPC title
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