Separator for lithium ion secondary battery and lithium ion secondary battery comprising the same

Patent metadata

Field	Value
Publication number	US-2020127265-A1
Application number	US-201716088719-A
Country	US
Kind code	A1
Filing date	Sep 29, 2017
Priority date	Oct 7, 2016
Publication date	Apr 23, 2020
Grant date	—

Abstract

The present disclosure relates to a separator for a lithium ion secondary battery and a battery comprising the separator. The separator supplements the irreversible capacity of a negative electrode. The separator comprises composite particles (A), and the composite particles (A) include a core portion comprising lithium composite metal oxide particles and a shell portion comprising a carbonaceous material with which the core surface is coated at least partially; the composite particles (A) cause lithium deintercalation at 0.1 V to 2.5 V (vs. Li+/Li); the battery has a positive electrode potential of 3 V or more (vs. Li+/Li); and the battery has a driving voltage of 2.5 V to 4.5 V.

First claim

What is claimed is:

1 . A lithium ion secondary battery comprising a negative electrode, a positive electrode and a separator interposed between the negative electrode and the positive electrode,
wherein the separator comprises composite particles (A); the composite particles (A) comprise a core portion comprising lithium composite metal oxide particles and a shell portion comprising a carbonaceous material with which the core surface is coated at least partially; the composite particles (A) cause lithium deintercalation at 0.1 V to 2.5 V (vs. Li + /Li); the battery has a positive electrode potential of 3 V or more (vs. Li + /Li); and the battery has a driving voltage of 2.5 V to 4.5 V.

2 . The lithium ion secondary battery according to claim 1 , wherein the negative electrode comprises a negative electrode active material comprising Si and/or Sn, or an oxide thereof.

3 . The lithium ion secondary battery according to claim 1 , wherein the positive electrode comprises, as a positive electrode active material, any one selected from the group consisting of: a lithium manganese oxide represented by the chemical formula of Li 1+x Mn 2−x O 4 (wherein x is 0 to 0.33), LiMnO 3 , LiMn 2 O 3 or LiMnO 2 ; a Ni-site type lithium nickel oxide represented by the chemical formula of LiNi 1−x M x O 2 (wherein M is Mn and x is 0.01 to 0.3); a lithium manganese composite oxide represented by the chemical formula of LiMn 2−x M x O 2 (wherein M=Co, Ni, Fe, Cr, Zn or Ta, and x is 0.01 to 0.1) or Li 2 Mn 3 MO 8 (wherein M=Fe, Co, Ni, Cu or Zn); LiMn 2 O 4 in which Li is partially substituted with an alkaline earth metal ion; LiNi x Mn 2−x O 4 (0.01≤x≤0.6); LiCoO 2 , LiNiO 2 , LiMn 2 O 4 , LiCoPO 4 , LiFePO 4 , LiNiMnCoO 2 and LiNi 1−x−y−z Co x M1 y M2 z O 2 (wherein each of M1 and M2 is independently selected from the group consisting of Al, Ni, Co, Fe, Mn, V, Cr, Ti, W, Ta, Mg and Mo, each of x, y and z independently represents an atomic proportion of elements forming the oxide, and 0≤x<0.5, 0≤y<0.5, 0≤z<0.5, x+y+z≤1); or a combination of two or more of them.

4 . The lithium ion secondary battery according to claim 1 , wherein the composite particles (A) cause lithium deintercalation during the initial charge/discharge of the battery to supplement irreversible capacity of the negative electrode and do not contribute to the battery capacity from the second charge/discharge.

5 . The lithium ion secondary battery according to claim 1 , wherein the separator comprises:
a porous film comprising a polymer resin; and a lithium-providing layer formed on at least one surface of the porous film, and wherein the lithium-providing layer comprises the composite particles (A).

6 . The lithium ion secondary battery according to claim 5 , wherein the lithium-providing layer is patterned to have a non-coated region.

7 . The lithium ion secondary battery according to claim 1 , wherein the separator comprises:
a porous film comprising a polymer resin; a lithium-providing layer formed on one surface of the porous film; and a heat resistant layer formed on the other surface of the porous film, and wherein the first lithium-providing layer comprises the composite particles (A) and the heat resistant layer comprises inorganic particles (B) not comprising lithium as an ingredient.

8 . The lithium ion secondary battery according to claim 5 , wherein the composite particles (A) are present in an amount of 90 wt % or more based on 100 wt % of the lithium-providing layer.

9 . The lithium ion secondary battery according to claim 1 , wherein the separator comprises, as lithium composite metal oxide particles, any one selected from the group consisting of lithium phosphate (Li 3 PO 4 ), lithium titanium phosphate (Li x Ti y (PO 4 ) 3 , 0<x<2, 0<y<3), lithium aluminum titanium phosphate (Li x Al y Ti z (PO4) 3 , 0<x<2, 0<y<1, 0<z<3), (LiAlTiP) x O y -based glass (0<x<4, 0<y<13), lithium lanthanum titanate (Li x La y TiO 3 , 0<x<2, 0<y<3), lithium germanium thiophosphate (LixGe y P z S w , 0<x<4, 0<y<1, 0<z<1, 0<w<5), lithium nitride (Li x N y , 0<x<4, 0<y<2), SiS 2 (Li x Si y S z , 0<x<3, 0<y<2, 0<z<4)-based glass and P 2 S 5 (Li x P y S z , 0<x<3, 0<y<3, 0<z<7)-based glass, or a combination of two or more of them.

10 . The lithium ion secondary battery according to claim 1 , wherein the carbonaceous material coating is formed by carbonization of a carbonaceous precursor.

11 . The lithium ion secondary battery according to claim 10 , wherein the carbonaceous precursor is any one selected from the group consisting of pitch, furfuryl alcohol, glucose, sucrose, phenolic resin, phenolic oligomer, resorcinol resin, resorcinol oligomer, phloroglucinol resin, phloroglucinol oligomer and unsaturated hydrocarbon gases, such as ethylene, propylene or acetylene, or a combination of two or more of them.

12 . A separator for a lithium ion secondary battery which comprises composite particles (A), and the composite particles (A) cause lithium deintercalation at 0.1 V to 2.5 V (vs. Li + /Li).

Assignees

• Lg Chemical Ltd

Inventors

• Min Ji-Won
• Kim Seok-Koo
• Hah Hoe-Jin
• Doelle Janis

Classifications

• H01M2300/0094

  in the form of layered products, e.g. coatings · CPC title

• H01M4/36

  Selection of substances as active materials, active masses, active liquids · CPC title

• H01M4/38

  of elements or alloys · CPC title

• H01M4/505

  of mixed oxides or hydroxides containing manganese for inserting or intercalating light metals, e.g. LiMn2O4 or LiMn2OxFy · CPC title

• H01M2300/0082

  Organic polymers · CPC title