Electrophotographic photoreceptor, electrophotographic photoreceptor cartridge, and image forming apparatus

Patent metadata

Field	Value
Publication number	US-12372889-B2
Application number	US-202318534360-A
Country	US
Kind code	B2
Filing date	Dec 8, 2023
Priority date	Jun 10, 2021
Publication date	Jul 29, 2025
Grant date	Jul 29, 2025

Abstract

The present disclosure relates to an electrophotographic photoreceptor including at least a photosensitive layer and a protective layer in sequence on a conductive support, and the protective layer contains a cured product of a curable compound, conductive particles having a band gap of 2.0 eV or more and 3.6 eV or less, and particles having a band gap of 8.0 eV or more.

First claim

The invention claimed is:

1. An electrophotographic photoreceptor comprising a photosensitive layer and a protective layer in sequence on a conductive support,
the protective layer containing: (i) a cured product of a curable compound; (ii) conductive particles having a band gap of 2.0 eV or more and 3.6 eV or less; and (iii) particles having a band gap of 8.0 eV or more,
wherein an average primary particle size of the particles having a band gap of 8.0 eV or more is ⅕ or more and ⅔ or less of the average primary particle size of the conductive particles.

2. The electrophotographic photoreceptor according to claim 1 , wherein the curable compound comprises a polyfunctional acrylate or a polyfunctional methacrylate.

3. The electrophotographic photoreceptor according to claim 1 , wherein the conductive particles comprise metal oxide particles.

4. The electrophotographic photoreceptor according to claim 1 , wherein the conductive particles include titanium oxide particles.

5. The electrophotographic photoreceptor according to claim 1 , wherein the particles having a band gap of 8.0 eV or more have a specific gravity of 3.0 g/cm 3 or less.

6. The electrophotographic photoreceptor according to claim 1 , wherein the particles having a band gap of 8.0 eV or more comprise silica particles.

7. The electrophotographic photoreceptor according to claim 1 , wherein an amount of the particles having a band gap of 8.0 eV or more is 5 parts by mass or more and 100 parts by mass or less relative to 100 parts by mass of the conductive particles contained in the protective layer.

8. The electrophotographic photoreceptor according to claim 1 , wherein the particles having a band gap of 8.0 eV or more are surface-treated with an organic metal compound.

9. The electrophotographic photoreceptor according to claim 8 , wherein the organic metal compound comprises a phenyl group-containing silane coupling agent.

10. The electrophotographic photoreceptor according to claim 1 , wherein an average primary particle size of the particles having a band gap of 8.0 eV or more is 5 nm or more and 50 nm or less.

11. The electrophotographic photoreceptor according to claim 1 , wherein an amount of the particles having a band gap of 8.0 eV or more is 20 parts by mass or more and 120 parts by mass or less relative to 100 parts by mass of the curable compound contained in the protective layer.

12. The electrophotographic photoreceptor according to claim 1 , wherein the protective layer further comprises a charge transporting material in an amount of 1 part by mass or less relative to 100 parts by mass of the curable compound.

13. The electrophotographic photoreceptor according to claim 1 , wherein the photosensitive layer is a single layer, and contains at least a charge generating material, an electron transporting material, and a hole transporting material, and a binder resin.

14. The electrophotographic photoreceptor according to claim 13 , wherein the photosensitive layer contains the hole transporting material in an amount of 70 parts by mass or more relative to 100 parts by mass of the binder resin.

15. An electrophotographic photoreceptor cartridge comprising the electrophotographic photoreceptor according to claim 1 .

16. An image forming apparatus comprising the electrophotographic photoreceptor according to claim 1 .

17. The electrophotographic photoreceptor according to claim 1 , wherein the content of the conductive particles in the protective layer is 5 parts by mass or more and 300 parts by mass or less relative to 100 parts by mass of the curable compound contained in the protective layer.

18. The electrophotographic photoreceptor according to claim 1 , wherein the content of the conductive particles in the protective layer is 10 parts by mass or more and 200 parts by mass or less relative to 100 parts by mass of the curable compound contained in the protective layer.

19. The electrophotographic photoreceptor according to claim 1 , wherein the content of the conductive particles in the protective layer is 20 parts by mass or more and 150 parts by mass or less relative to 100 parts by mass of the curable compound contained in the protective layer.

Assignees

• Mitsubishi Chem Corp

Inventors

• Choda Takahiro
• Yamazaki Daisuke
• Ando Akira

Classifications

• G03G5/14704

  comprising inorganic material · CPC title

• G03G5/047

  characterised by the charge-generation layers or charge transport layers {(G03G5/0433 and G03G5/0436 take precedence)} · CPC title

• G03G5/14734 Primary

  Polymers comprising at least one carboxyl radical, e.g. polyacrylic acid, polycrotonic acid, polymaleic acid; Derivatives thereof, e.g. their esters, salts, anhydrides, nitriles, amides · CPC title

• G03G5/14791

  Macromolecular compounds characterised by their structure, e.g. block polymers, reticulated polymers, or by their chemical properties, e.g. by molecular weight or acidity · CPC title

• G03G5/147

  Cover layers · CPC title