Photo conductor overcoat comprising radical polymerizable charge transport molecules and hexa-functional urethane acrylates

Patent metadata

Field	Value
Publication number	US-9417538-B2
Application number	US-201414569948-A
Country	US
Kind code	B2
Filing date	Dec 15, 2014
Priority date	Dec 31, 2012
Publication date	Aug 16, 2016
Grant date	Aug 16, 2016

Abstract

A method of preparing a photoconductor drum having an overcoat layer is provided. The photoconductor drum is used in an electrophotographic image forming device. The photoconductor drum is prepared from a curable composition including a urethane resin having at least six radical polymerizable functional groups and a charge transport molecule having at least one radical polymerizable functional group. The amount of the urethane resin having at least six radical polymerizable functional groups in the curable composition is about 35 percent to about 65 percent by weight. The amount of the charge transport molecules having at least one radical polymerizable functional group in the curable composition is about 35 percent to about 65 percent by weight. This overcoat layer improves wear resistance of the photoconductor drum without negatively altering the electrophotographic properties, thus protecting the photoconductor drum from damage and extending its useful life.

First claim

What is claimed is:

1. A method of preparing a photoconductor comprising:
providing an electrically conductive substrate;
preparing a charge generation layer dispersion;
coating the charge generation layer dispersion onto the electrically conductive substrate to form a charge generation layer;
preparing a charge transport formulation;
coating the charge transport formulation over the charge generation layer to form a charge transport layer;
preparing an overcoat layer formulation including a charge transport molecule at least one radical polymerizable functional group, a urethane acrylate resin having at least six radical polymerizable functional groups, an organic solvent and a photoinitiator;
coating the overcoat layer formulation over the charge transport layer; and
curing the overcoat layer formulation to form a photoconductor having an overcoat layer over the charge transport layer and the charge generation layers.

2. The method of claim 1 , wherein the urethane acrylate resin having at least six radical polymerizable functional groups is a hexa-functional aromatic urethane acrylate resin.

3. The method of claim 1 , wherein the urethane acrylate resin having at least six radical polymerizable functional groups is a hexa-functional aliphatic urethane acrylate resin.

4. The method of claim 1 , wherein the charge transport molecule comprises a tryarylamine having at least one radical polymerizable functional group.

5. The method of claim 1 , wherein the charge transport molecule comprises a tetraphenylbenzidine having at least one radical polymerizable functional group.

6. The method of claim 1 , wherein the overcoat layer formulation further includes a monomer or oligomer having at most five radical polymerizable functional groups.

7. The method of claim 1 , wherein the overcoat layer formulation further includes a non-radical polymerizable additive at an amount equal to or less than about 10 percent by weight of the overcoat composition.

8. The method of claim 7 , wherein the amount of the non-radical polymerizable additive is about 0.1 to about 5 percent by weight of the overcoat layer formulation.

9. The method of claim 1 , wherein the overcoat layer has a thickness of about 0.1 μm to about 10 μm after curing.

10. The method of claim 1 , wherein the urethane acrylate resin having at least six polymerizble functional groups is about 35 percent to about 65 percent by weight of the overcoat formulation and the charge transport molecule having at least one functional group is about 35 percent to about 65 percent by weight of the overcoat formulation.

11. The method of preparing an overcoat layer formulation comprising the steps of:
mixing a charge transport molecule having at least one radical polymerizable functional group in a solvent;
mixing a urethane acrylate resin having at least six radical polymerizable functional groups in the solvent containing the charge transport molecule having at least one radical polymerizable functional group; and
mixing a photoinitiator in the solvent containing the charge transport molecule having at least one radical polymerizable functional group and the urethane acrylate resin having at least six radical polymerizable functional groups.

12. The method of claim 11 , further comprising mixing a non-radical polymerizable additive in the solvent containing the charge transport molecule having at least one radical polymerizable functional group, the urethane acrylate resin having at least six radical polymerizable functional groups, and the photoinitiator.

13. The method of claim 11 , wherein the urethane acrylate resin having at least six polymerizble functional groups is about 35 percent to about 65 percent by weight of the overcoat layer formulation and the charge transport molecule having at least one functional group is about 35 percent to about 65 percent by weight of the overcoat layer formulation.

Assignees

• Lexmark Int Inc

Inventors

• Bellino Mark Thomas
• Black David Glen
• Luo Weimei
• Reeves Scott Daniel

Classifications

• G03G5/14769

  Other polycondensates comprising nitrogen atoms with or without oxygen atoms in the main chain · CPC title

• G03G5/14791

  Macromolecular compounds characterised by their structure, e.g. block polymers, reticulated polymers, or by their chemical properties, e.g. by molecular weight or acidity · CPC title

• G03G5/0618 Primary

  containing oxygen and nitrogen · CPC title

• G03G5/14786

  Macromolecular compounds characterised by specific side-chain substituents or end groups · CPC title

• G03G5/14734

  Polymers comprising at least one carboxyl radical, e.g. polyacrylic acid, polycrotonic acid, polymaleic acid; Derivatives thereof, e.g. their esters, salts, anhydrides, nitriles, amides · CPC title