Generation of peroxyhydroxycarboxylic acid and the use thereof

Patent metadata

Field	Value
Publication number	US-12371403-B2
Application number	US-202318485955-A
Country	US
Kind code	B2
Filing date	Oct 12, 2023
Priority date	Jan 31, 2020
Publication date	Jul 29, 2025
Grant date	Jul 29, 2025

Abstract

Peroxyhydroxycarboxylic acid forming compositions and methods for forming peroxyhydroxycarboxylic acids, preferably in situ, using the peroxyhydroxycarboxylic acid forming compositions are disclosed. Methods of using the peroxyhydroxycarboxylic acids, including for treating a surface or a target in need of antimicrobial or sanitizing treatment are also disclosed. Particular applications of using odor-free, low volatility peroxyhydroxycarboxylic acid sanitizers for direct food contact are disclosed.

First claim

The invention claimed is:

1. A peroxyhydroxycarboxylic acid forming composition comprising:
a) a first reagent that comprises a lactone of an alphahydroxycarboxylic acid, and
b) a second reagent that comprises an alkalinity source,
c) a third reagent that comprises hydrogen peroxide; and
d) optionally water or a solvent if the first, second and/or third reagents are powders;
wherein said reagents are provided as powders and/or liquids, and wherein the powder reagents are combined into a premix and the liquid reagents are kept separately from the powder reagents prior to contacting to generate the peroxyhydroxycarboxylic acid; and
wherein the combination of the reagents react to form a liquid that comprises the peroxyhydroxycarboxylic acid and has a pH below about 7 within about 5 minutes after the contact between said reagent.

2. The peroxyhydroxycarboxylic acid forming composition of claim 1 , wherein the lactone of the alphahydroxycarboxylic acid is a diester of lactone.

3. The peroxyhydroxycarboxylic acid forming composition of claim 2 , wherein the alphahydroxycarboxylic acid is lactic acid or glycolic acid, and wherein the lactone of the alphahydroxycarboxylic acid is correspondingly lactide or glycolide.

4. The peroxyhydroxycarboxylic acid forming composition of claim 1 , wherein the alkalinity source comprises an alkaline metal hydroxide, an alkali metal silicate, an alkali metal carbonate, borates, amines, amides or other basic nitrogen sources or mixtures thereof.

5. The peroxyhydroxycarboxylic acid forming composition of claim 1 , wherein the reagents are contacted to form a liquid solution comprising the peroxyhydroxycarboxylic acid in amounts from about 0.1 ppm to about 100,000 ppm, and/or wherein the peroxyhydroxycarboxylic acid has less than about 1 Kpa vapor pressure at 20° C.

6. The peroxyhydroxycarboxylic acid forming composition of claim 1 , further comprising a catalyst or an enzyme that catalyzes formation of the peroxyhydroxycarboxylic acid, wherein the catalyst or enzyme comprises a perhydrolytic enzyme, lipase, coronase, termanyl or esperease.

7. The peroxyhydroxycarboxylic acid forming composition of claim 1 , further comprising a stabilizing agent and/or a pH buffering agent.

8. The peroxyhydroxycarboxylic acid forming composition of claim 1 , further comprising an additional-C1-C22 peroxycarboxylic acid.

9. The peroxyhydroxycarboxylic acid forming composition of claim 1 , further comprising an ester precursor and/or a carboxylic acid precursor of an additional-C1-C22 peroxycarboxylic acid.

10. A method for treating a target, which method comprises contacting a target with an effective amount of peroxyhydroxycarboxylic acid according to claim 1 to form a treated target composition, wherein said treated target composition comprises from about 0.1 ppm to about 10,000 ppm of said peroxyhydroxycarboxylic acid, and said contacting lasts for sufficient time to bleach, remove soils, disinfect and/or stabilize or reduce microbial population in and/or on said target or said treated target composition.

11. The method of claim 10 , wherein the target is a surface in need of high-level disinfecting and the method comprises providing an effective amount of the peroxyhydroxycarboxylic acid to the surface in need of treatment, wherein said treated surface source comprises from about 1 ppm to about 1,000 ppm of said peroxyhydroxycarboxylic acid.

12. The method of claim 10 , wherein the contacting step lasts for about 1 second to about 10 minutes.

13. The method of claim 10 , wherein the contacting step is conducted at a temperature ranging from about 0° C. to about 70° C.

14. The method of claim 10 , wherein the target is a food item or a plant item and/or at least a portion of a medium, a container, an equipment, a system or a facility for growing, holding, processing, packaging, storing, transporting, preparing, cooking or serving the food item or the plant item and wherein the treatment does not induce an organoleptic effect in and/or on the food item or a plant item.

15. The method of claim 10 , wherein the target is at least a portion of a medium, a container, an equipment, a system or a facility for producing, holding, processing, packaging, storing, or transporting pulp, and is used in papermaking, textiles, food, or pharmaceutical industry.

16. The method of claim 10 , wherein the target is a water source and/or a biofilm.

17. The method of claim 10 , wherein the target is at least a portion of a medium, a surface, a container, an equipment, or a system in a health care facility and/or wherein the target is a medical instrument in need of repurposing or reprocessing.

18. The method of claim 10 , wherein the target is a laundry article and wherein the laundry article is soiled and contacted by the peroxyhydroxycarboxylic acid in a conventional laundry application, a pre-wash step, a pre-bleach step and/or outside of a washing machine.

19. The method of claim 10 , wherein the peroxyhydroxycarboxylic acid is saturated onto a wipe.

20. The method of claim 10 , wherein one or more of the reagents to generate the peroxyhydroxycarboxylic acid is saturated onto a wipe.

Assignees

• Ecolab Usa Inc

Inventors

• Li Junzhong
• Prideaux Allison
• Staub Richard

Classifications

• C12P7/42

  Hydroxy-carboxylic acids · CPC title

• C07C407/006

  Stabilisation; Use of additives · CPC title

• A01N37/16

  containing the group [IMAGE cpc-sch-A01N-0934.gif]; Thio analogues thereof · CPC title

• A01N37/36

  containing at least one carboxylic group or a thio analogue, or a derivative thereof, and a singly bound oxygen or sulfur atom attached to the same carbon skeleton, this oxygen or sulfur atom not being a member of a carboxylic group or of a thio analogue, or of a derivative thereof, e.g. hydroxy-carboxylic acids · CPC title

• C07C407/00 Primary

  Preparation of peroxy compounds · CPC title