Hydrocyclone modification of catalyst system components for use in olefin polymerization

Patent metadata

Field	Value
Publication number	US-12370536-B2
Application number	US-202418660297-A
Country	US
Kind code	B2
Filing date	May 10, 2024
Priority date	Sep 13, 2021
Publication date	Jul 29, 2025
Grant date	Jul 29, 2025

Abstract

Methods for modifying a catalyst system component are disclosed in which a feed mixture containing a fluid and from 1 to 15 wt. % of a catalyst system component is introduced into an inlet of a hydrocyclone, an overflow stream containing from 0.1 to 5 wt. % solids and an underflow stream containing from 10 to 40 wt. % solids are discharged from the hydrocyclone, and the underflow stream is spray dried to form a modified catalyst component. Often, from 4 to 20 wt. % of the catalyst system component in the feed mixture has a particle size of less than or equal to 20 μm, or less than or equal to 10 μm.

First claim

We claim:

1. A system for modifying a catalyst system component, the system comprising:
(a) a hydrocyclone configured to separate a feed mixture containing water and from 1 to 15 wt. % of the catalyst system component, wherein a first amount of the catalyst system component in the feed mixture has a particle size of less than or equal to 20 μm, into (1) an overflow stream and (2) an underflow stream containing from 10 to 40 wt. % of the catalyst system component, wherein a second amount of the catalyst system component in the underflow stream has a particle size of less than or equal to 20 μm, and wherein the second amount is at least 50% less than the first amount;
(b) a spray dryer configured to dry the underflow stream to form a modified catalyst component, the spray dryer comprising a high-pressure nozzle, a two-fluid nozzle, or a high-speed centrifugal disk; and
(c) a particle size analyzer for determining the first amount and the second amount.

2. The system of claim 1 , wherein the second amount is at least 70% less than the first amount.

3. The system of claim 1 , wherein the second amount is at least 80% less than the first amount.

4. The system of claim 1 , wherein:
the first amount is an amount of the catalyst system component in the feed mixture having a particle size of less than or equal to 10 μm;
the second amount is an amount of the catalyst system component in the underflow stream having a particle size of less than or equal to 10 μm; and
the second amount is at least 50% less than the first amount.

5. The system of claim 4 , wherein the second amount is at least 70% less than the first amount.

6. The system of claim 4 , wherein the second amount is at least 80% less than the first amount.

7. The system of claim 4 , wherein the second amount is at least 90% less than the first amount.

8. The system of claim 4 , the second amount is less than or equal to 4 wt. %.

9. The system of claim 1 , wherein the catalyst system component in the feed mixture has a wet particle density of from 1.05 to 2.0 g/cc.

10. The system of claim 1 , wherein the catalyst system component in the feed mixture has:
a wet particle density of from 1.2 to 1.8 g/cc;
a BET surface area of from 50 to 1000 m 2 /g; and
a d50 average particle size of from 25 to 60 μm.

11. The system of claim 1 , wherein a linear velocity of the feed mixture entering the hydrocyclone is from 2 to 20 ft/sec.

12. The system of claim 1 , wherein:
the first amount is from 4 to 20 wt. %; and
the second amount is from 0.1 to 5 wt. %.

13. The system of claim 1 , wherein the catalyst system component comprises a solid oxide, a chemically-treated solid oxide, a zeolite, or a combination thereof.

14. The system of claim 13 , wherein the feed mixture contains the water and from 4 to 10 wt. % of the catalyst system component.

15. A system for modifying a catalyst system component, the system comprising:
(a) a hydrocyclone configured to separate a feed mixture containing a fluid and from 1 to 15 wt. % of the catalyst system component, wherein a first amount of the catalyst system component in the feed mixture has a particle size of less than or equal to 20 μm, into (1) an overflow stream and (2) an underflow stream containing from 10 to 40 wt. % of the catalyst system component, wherein a second amount of the catalyst system component in the underflow stream has a particle size of less than or equal to 20 μm, and wherein the second amount is at least 50% less than the first amount;
(b) a spray dryer configured to dry the underflow stream to form a modified catalyst component; and
(c) a controller for controlling the second amount of the catalyst system component in the underflow stream by adjusting a hydrocyclone processing parameter; wherein:
the system is configured to introduce the feed mixture into the hydrocyclone at a linear velocity from 2 to 20 ft/sec; and
the hydrocyclone processing parameter comprises the linear velocity of the feed mixture entering the hydrocyclone, a temperature of the feed mixture, or both.

16. The system of claim 15 , wherein the spray dryer comprises a high-pressure nozzle, a two-fluid nozzle, or a high-speed centrifugal disk.

17. The system of claim 16 , wherein the fluid comprises water.

18. The system of claim 17 , wherein the feed mixture contains the water and from 4 to 10 wt. % of the catalyst system component.

19. The system of claim 17 , wherein the system further comprises a particle size analyzer for determining the first amount and the second amount.

Assignees

• Chevron Phillips Chemical Co Lp
• The Shepherd Chemical Company

Inventors

• Scott Mark
• Merk Evan
• Mcdaniel Max P

Classifications

• B01J37/0045 Primary

  Drying a slurry, e.g. spray drying · CPC title

• B01J35/61

  Surface area · CPC title

• B01J35/40

  characterised by dimensions, e.g. grain size (in a colloidal state B01J35/23; crystallite size B01J35/77) · CPC title

• C08F2410/06

  Catalyst characterized by its size · CPC title

• C08F4/00

  Polymerisation catalysts · CPC title