Methods for improving production in gas phase polymerization
US-12152095-B2 · Nov 26, 2024 · US
US8993692B2 · US · B2
| Field | Value |
|---|---|
| Publication number | US-8993692-B2 |
| Application number | US-201113700503-A |
| Country | US |
| Kind code | B2 |
| Filing date | Jun 29, 2011 |
| Priority date | Jun 30, 2010 |
| Publication date | Mar 31, 2015 |
| Grant date | Mar 31, 2015 |
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A process for polymerizing ethylene to produce an ethylene-based polymer including contacting ethylene with a Ziegler-Natta procatalyst, an alkylaluminum cocatalyst and a self limiting agent selected from the group of aliphatic, cycloaliphatic, substituted cycloaliphatic or aromatic esters, anhydrides and amides such that the self limiting agent reduces polymerization rates to no greater than 40% of the polymerization rate in the absence of the self limiting agent at temperatures equal to or greater than 120° C. is provided.
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We claim: 1. A process for polymerizing ethylene comprising: (i) contacting, in a first reactor, ethylene; optionally at least one comonomer; with a catalyst composition comprising one or more Group 3-10 transition metal containing Ziegler-Natta procatalyst compounds, one or more alkylaluminum cocatalysts; and one or more self limiting agents, wherein the one or more self limiting agents are selected from the group of consisting dihydro-2H-pyran-2,6(3H)-dione; 4-methylcyclohexane-1…
Chemistry & Metallurgy · mapped topic
Chemistry & Metallurgy · mapped topic
Chemistry & Metallurgy · mapped topic
Chemistry & Metallurgy · mapped topic
Chemistry & Metallurgy · mapped topic
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