Alkali-based removal of chemical moieties from gas streams with chemical co-generation
US-2023226487-A1 · Jul 20, 2023 · US
US12357946B2 · US · B2
| Field | Value |
|---|---|
| Publication number | US-12357946-B2 |
| Application number | US-202418916589-A |
| Country | US |
| Kind code | B2 |
| Filing date | Oct 15, 2024 |
| Priority date | Dec 3, 2019 |
| Publication date | Jul 15, 2025 |
| Grant date | Jul 15, 2025 |
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Systems and methods for direct air capture of carbon dioxide or other gases utilize a calcium sorbent in a manner that allows for wide scale, relatively low cost implementation. In particular, a calcium sorbent may be provided as a substantially thin coating on one or more substrates and utilized for direct air capture of carbon dioxide through chemisorption. The carbonated sorbent may be disposed of for sequestration of the carbon dioxide or regenerated with capture of carbon dioxide released from the carbonated sorbent during the regeneration process.
Opening claim text (preview).
The invention claimed is: 1. A system for direct air capture of carbon dioxide, the system comprising: a coating system configured for application of a liquid, calcium sorbent material on a substrate that is configured as a sheet to form a coating layer of the calcium sorbent material across at least a portion of a surface of the substrate that is configured as a sheet; a storage unit configured for positioning of the substrate for a time wherein the substrate is in contact with air such that carbon dioxide in the air reacts with the calcium sorbent material to form carbonated calcium sorbent material; and a collection unit configured for removal and collection of the carbonated calcium sorbent material from the substrate. 2. The system of claim 1 , wherein the coating system comprises one or more reservoirs of the liquid, calcium sorbent material. 3. The system of claim 1 , wherein the coating system further comprises a dipping unit configured for dipping of the substrate into the one or more reservoirs of the liquid, calcium sorbent material. 4. The system of claim 1 , wherein the coating system comprises a hanging unit configured for retaining the substrate in a substantially vertical position. 5. The system of claim 4 , wherein the coating system further comprises one or more drip pipes configured for dripping calcium sorbent material onto the substrate. 6. The system of claim 4 , further comprising a calciner configured to receive the carbonated calcium sorbent material and convert the carbonated calcium sorbent material into calcium oxide and carbon dioxide. 7. The system of claim 6 , further comprising a solids separator configured to separate the calcium oxide from the carbon dioxide. 8. The system of claim 7 , further comprising a lime slaking unit configured to receive the calcium oxide and form calcium hydroxide for use as the calcium sorbent material. 9. The system of claim 1 , wherein the coating system is configured to form the coating layer of the calcium sorbent material on the substrate that is configured as a sheet so that the coating layer of the calcium sorbent materials has a thickness of about 0.01 mm to about 1 cm. 10. The system of claim 1 , wherein the coating system is configured to form the coating layer of the calcium sorbent material on the substrate that is configured as a sheet so that the coating layer of the calcium sorbent materials has a density of about 0.1 kg per square meter to about 5 kg per square meter. 11. The system of claim 1 , wherein the collection unit is configured for removal of the carbonated calcium sorbent from the substrate that is configured as a sheet by subjecting the substrate to a force that causes the carbonated calcium sorbent to break apart and fall from the surface of the substrate that is configured as a sheet. 12. The system of claim 11 , wherein the collection unit is configured to cause the substrate that is configured as a sheet to bend or flex. 13. The system of claim 11 , wherein the collection unit is configured to subject the substrate that is configured as a sheet to a mechanical force. 14. The system of claim 11 , wherein the collection unit is configured to subject the substrate that is configured as a sheet to shock forces or impulses. 15. The system of claim 11 , wherein the collection unit is configured to subject the substrate that is configured as a sheet to one or more of shaking, scraping, blowing, vibrating, rolling, squeeze rolling, electrostatic impulse, electromagnetic impulse, and magnetic force. 16. A system for direct air capture of carbon dioxide, the system comprising: a coating system configured for application of a liquid, calcium sorbent material on a substrate that is configured as a sheet to form a coating layer of the calcium sorbent material across at least a portion of a surface of the substrate that is configured as a sheet, the coating system including a dipping unit configured for dipping of the substrate into the one or more reservoirs of the liquid, calcium sorbent material; a storage unit configured for positioning of the substrate for a time wherein the substrate is in contact with air such that carbon dioxide in the air reacts with the calcium sorbent material to form carbonated calcium sorbent material; and a collection unit configured for removal and collection of the carbonated calcium sorbent material from the substrate. 17. A system for direct air capture of carbon dioxide, the system comprising: a coating system configured for application of a liquid, calcium sorbent material on a substrate that is configured as a sheet to form a coating layer of the calcium sorbent material across at least a portion of a surface of the substrate that is configured as a sheet, the coating system including a hanging unit configured for retaining the substrate in a substantially vertical position and one or more drip pipes configured for dripping calcium sorbent material onto the substrate; a storage unit configured for positioning of the substrate for a time wherein the substrate is in contact with air such that carbon dioxide in the air reacts with the calcium sorbent material to form carbonated calcium sorbent material; and a collection unit configured for removal and collection of the carbonated calcium sorbent material from the substrate. 18. A system for direct air capture of carbon dioxide, the system comprising: a coating system configured for application of a liquid, calcium sorbent material on a substrate that is configured as a sheet to form a coating layer of the calcium sorbent material across at least a portion of a surface of the substrate that is configured as a sheet, the coating system including a hanging unit configured for retaining the substrate in a substantially vertical position; a storage unit configured for positioning of the substrate for a time wherein the substrate is in contact with air such that carbon dioxide in the air reacts with the calcium sorbent material to form carbonated calcium sorbent material; a collection unit configured for removal and collection of the carbonated calcium sorbent material from the substrate; and a calciner configured to receive the carbonated calcium sorbent material and convert the carbonated calcium sorbent material into calcium oxide and carbon dioxide.
by thermal treatment not covered by groups B01J20/3441 - B01J20/3475, e.g. by heating or cooling · CPC title
of sorbents or filter aids other than those covered by B01J20/3408 - B01J20/3425 · CPC title
Coatings in the shape of a sheet · CPC title
containing metal, other than zeolites, e.g. oxides, hydroxides, sulphides or salts · CPC title
Membrane, sheet, cloth, pad, lamellar or mat · CPC title
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