Production of amorphous calcium carbonate

Patent metadata

Field	Value
Publication number	US-10745288-B2
Application number	US-201716306762-A
Country	US
Kind code	B2
Filing date	Jul 20, 2017
Priority date	Jul 25, 2016
Publication date	Aug 18, 2020
Grant date	Aug 18, 2020

Abstract

The present invention relates to a process for preparing amorphous calcium carbonate, the amorphous calcium carbonate obtainable by the process, its use as well as a product comprising the amorphous calcium carbonate and the use of a spray dryer for the preparation of amorphous calcium carbonate.

First claim

The invention claimed is:

1. A process for preparing amorphous calcium carbonate, the process comprising the steps of:
a) providing at least one calcium oxide containing material;
b) providing at least one gaseous CO 2 source,
c) preparing a milk of lime by mixing the at least one calcium oxide containing material of step a) with water to convert the calcium oxide at least partially into dissolved calcium hydroxide,
d) separating the dissolved calcium hydroxide in the milk of lime obtained in step c) from undissolved materials to obtain a solution of dissolved calcium hydroxide,
e) drying the solution of dissolved calcium hydroxide obtained in step d), and
f) carbonating the dissolved calcium hydroxide obtained in step d) with the at least one gaseous CO 2 source of step b) to convert the calcium hydroxide at least partially into amorphous calcium carbonate,
wherein process steps e) and f) are carried out simultaneously.

2. The process according to claim 1 , wherein the at least one gaseous CO 2 source comprises 50 to 99% by volume CO 2 .

3. The process according to claim 1 , wherein the at least one gaseous CO 2 source consists of CO 2 .

4. The process according to claim 1 , wherein the amorphous calcium carbonate produced in element f) has a moisture content of less than or equal to 10 wt%.

5. The process according to claim 1 , wherein element d) is performed in with vacuum filter.

6. The process according to claim 1 , wherein step c) is carried out in that the at least one calcium oxide containing material is mixed with water in a weight ratio from 1:2 to 1:25 and/or in that the temperature of the water, which is used in step c), is adjusted to be in the range from >0° C. and <100° C.

7. The process according to claim 6 , wherein the weight ratio is from 1:3 to 1:15.

8. The process according to claim 1 , wherein the process further comprises a step of removing particles having an average particle size of >100 μm from the milk of lime obtained in step c) before separating step d) is carried out.

9. The process according to claim 1 , wherein the milk of lime obtained in step c) has a Brookfield viscosity from 1 to 1 000 mPas at 25° C.; and/or solids content in the range from 5.0 to 40.0 wt.-%, based on the total weight of the milk of lime.

10. The process according to claim 9 , wherein the Brookfield viscosity at 25° C. of the milk of lime obtained in step c) is from 10 to 600 mPa·s.

11. The process according to claim 9 , wherein the solids content of the milk of lime obtained in step c) is from 8.0 to 20.0 wt.-%, based on the total weight of the milk of lime.

12. The process according to claim 1 , wherein separating step d) is carried out via mechanical separation techniques.

13. The process according to claim 1 , wherein the solution of dissolved calcium hydroxide obtained in step d) is adjusted to a temperature in the range from 10° C. and less than 60° C.

14. The process according to claim 1 , wherein drying step e) and carbonating step f) are carried out in a spray drier.

15. The process according to claim 14 , wherein the spray dryer has an inlet temperature in the range of 100° C. to 375° C.

16. The process according to claim 1 , wherein drying step e) and carbonating step f) are carried out at an inlet temperature in the range from 50° C. to 400° C.

17. The process according to claim 1 , wherein the carbonating in step f) is carried out at a gas pressure of 1 to 20 bar.

18. The process according to claim 1 , wherein the amorphous calcium carbonate
i) has an average particle size of 30 to 150 nm, and/or
ii) has a moisture content of ≤10.0 wt.-%, based on the total dry weight of the amorphous calcium carbonate, and/or
iii) has a specific BET surface area of 1.0 m 2 /g to 60.0 m 2 /g, and/or
iv) forms aggregates, and/or
v) is present in the form of deagglomerated particles.

19. The process according to claim 1 , wherein the at least one gaseous CO 2 source contains at least 20 vol.-%, based on the total volume of the gas, of CO 2 .

20. The process according to claim 1 , wherein temperature of the water used in step c) is adjusted to be in the range from 35° C. and 45° C.

Assignees

• Omya Int Ag

Inventors

• Schlotterbach Thomas

Classifications

• C09C3/08

  Treatment with low-molecular-weight {non-polymer} organic compounds {(C09C3/006, C09C3/048 take precedence)} · CPC title

• C01P2004/62

  Submicrometer sized, i.e. from 0.1-1 micrometer · CPC title

• C01P2002/72

  by d-values or two theta-values, e.g. as X-ray diagram · CPC title

• C01P2002/02

  Amorphous compounds · CPC title

• C01P2004/03

  obtained by SEM · CPC title