Two-component solvent-based coating composition, method for coating a substrate, coated substrate, and use of such coating composition for improving erosion resistance

Patent metadata

Field	Value
Publication number	US-12344761-B2
Application number	US-202418414042-A
Country	US
Kind code	B2
Filing date	Jan 16, 2024
Priority date	Jul 2, 2018
Publication date	Jul 1, 2025
Grant date	Jul 1, 2025

Abstract

The present disclosure relates to a two-component, solvent-based coating composition comprising i) a base component comprising one or more polyesterdiols with a hydroxyl value in the range of from 150 to 500 mg KOH/g and one or more organosilane-modified inorganic fillers, and ii) a polyisocyanate curing component. Said composition can be formulated such that it has a viscosity suitable for spray application (low viscosity under high shear rate) and yield coatings with very good erosion resistance. The present disclosure further relates to a method for coating a substrate using said two-component coating composition, to a coated substrate obtainable by such method, and to use of such coating composition for improving erosion resistance of a substrate.

First claim

The invention claimed is:

1. A method for coating a substrate selected from rotor blades of wind turbines, rotor blades of helicopters, ship screws and aircraft, the method comprising:
applying a two-component solvent-based coating composition to the substrate; and
allowing the applied coating composition to cure,
wherein the two-component, solvent-based coating composition comprises
i) a base component comprising
(A) one or more polyester diols having a hydroxyl value in the range of from 150 to 500 mg KOH/g polyester diol;
(B) optionally one or more hydroxyl-functional acrylate resins having a hydroxyl value in the range of from 75 to 500 mg KOH/g resin; and
(C) one or more organosilane-modified inorganic fillers; and
ii) a curing component comprising
(D) one or more polyisocyanates,
in such amounts that the coating composition comprises:
5 to 50 wt % of the one or more polyester diols (A);
0 to 25 wt % of the one or more hydroxyl-functional acrylate resins (B);
10 to 70 wt % of the one or more organosilane-modified inorganic fillers (C);
5 to 40 wt % of the one or more polyisocyanates (D);

wherein the base component comprises no resins other than the one or more polyester diols (A) and any hydroxyl-functional acrylate resins (B);
the one or more polyisocyanates (D) are selected from trimers of di-isocyanates;
the coating composition comprises one or more organic solvents in an amount in the range of from 5 to 35 wt %; and
the coating composition has a viscosity in the range of from 50 to 2,000 mPa·s as measured by means of a rotary viscometer at a shear rate of 1000 s −1 and a temperature of 23° C., 30 seconds after combining and mixing the base component and the curing component.

2. A method according to claim 1 wherein the two-component coating composition is applied to the substrate by spray application.

3. A method according to claim 1 , wherein the substrate is a substrate comprising one or more coating layers and the two-component coating composition is applied as a topcoat layer.

4. The method of claim 1 , further comprising improving erosion resistance of the substrate.

5. The method of claim 1 , further comprising allowing the applied coating composition to cure at a temperature of at most 80° C.

6. The method of claim 1 , wherein the polyester diol of (A) is prepared by esterification of one or more carboxylic diacids with one or more diols.

7. The method of claim 6 , wherein the one or more carboxylic diacids are selected from phthalic acid, isophthalic acid, terephthalic acid, tetrahydrophthalic acid, hexahydrophthalic acid, tetrachlorophthalic acid, cyclohexane dicarboxylic acid, succinic acid, adipic acid, azelaic acid, sebacic acid, maleic acid, fumaric acid, glutaric acid and dimerized fatty acids.

8. The method of claim 6 , wherein the one or more diols are selected from ethylene glycol, propylene glycol, butylene glycol, 1,4-butanediol, 1,6-hexanediol, neopentyl glycol and dimethylolcyclohexane.

9. The method of claim 1 , wherein the one or more trimers of di-isocyanates are selected from trimers of aliphatic di-isocyanates.

10. The method of claim 9 , wherein the trimers of aliphatic di-isocyanates are selected from trimers of hexamethylene di-isocyanate, isophorone di-isocyanate and mixtures thereof.

11. The method of claim 1 , wherein the cured coating composition has a rain erosion resistance of greater than 300 minutes when tested in accordance with ASTM G73 at 20 to 25° C., using a rain volume of 30 litres/hour, an average water droplet size of 5-6 mm, a specimen spin velocity of 140 m/s, and visual inspection at time intervals of 15 minutes, the erosion resistance corresponding to the time until the substrate is visible through the coating.

12. The method of claim 1 , wherein the substrate is a wind turbine rotor blade.

Assignees

• Akzo Nobel Coatings Int Bv

Inventors

• Meyerjürgens Andreas
• Seeger Dirk
• Shishkov Igor
• Wickbold Miriam

Classifications

• C08G18/4238

  derived from dicarboxylic acids and dialcohols · CPC title

• C09D7/62

  modified by treatment with other compounds · CPC title

• C09D7/20

  Diluents or solvents · CPC title

• C08G18/78

  Nitrogen {(C08G18/775, C08G18/776 take precedence)} · CPC title

• C08G18/7893

  having three nitrogen atoms in the ring · CPC title