Synthetic fuels by electrically heated steam methane reforming

Patent metadata

Field	Value
Publication number	US-12344525-B2
Application number	US-202017782391-A
Country	US
Kind code	B2
Filing date	Dec 2, 2020
Priority date	Dec 4, 2019
Publication date	Jul 1, 2025
Grant date	Jul 1, 2025

Abstract

A method for producing a synthesis gas for use in the production of a hydrocarbon product, particularly a synthetic fuel, the method including the steps of: providing a hydrocarbon feed gas; optionally, purifying the hydrocarbon feed gas in a gas purification unit; optionally, prereforming the hydrocarbon feed gas together with a steam feedstock in a prereforming unit; carrying out steam methane reforming in a reforming reactor heated by means of an electrical power source; providing the synthesis gas to a synthetic fuel synthesis unit, preferably a Fischer-Tropsch synthesis unit, for converting the synthesis gas into hydrocarbon product and producing a tail gas. Also, a system for producing a synthesis gas for use in the production of a hydrocarbon product, particularly a synthetic fuel.

First claim

The invention claimed is:

1. A method for producing a synthesis gas for use in the production of a hydrocarbon product, said method comprising the steps of:
providing a hydrocarbon feed gas,
carrying out steam methane reforming in a reforming reactor comprising a pressure shell housing a structured catalyst arranged to catalyze steam reforming of said hydrocarbon feed gas, said structured catalyst comprising a macroscopic structure of an electrically conductive material, said macroscopic structure supporting a ceramic coating, where said ceramic coating supports a catalytically active material; said steam methane reforming comprising the following steps:
i) supplying said hydrocarbon feed gas to the reforming reactor,
ii) allowing the hydrocarbon feed gas to undergo steam methane reforming reaction over the structured catalyst and out-letting a synthesis gas from the reforming reactor, and
iii) supplying electrical power via electrical conductors connecting an electrical power supply placed outside said pressure shell to said structured catalyst, allowing an electrical current to run through said macroscopic structure material, thereby heating at least part of the structured catalyst to a temperature of at least 500° C.,
providing at least part of the synthesis gas from step ii) to a synthetic fuel synthesis unit for converting said synthesis gas into said hydrocarbon product and producing a tail gas.

2. The method of claim 1 , further comprising autothermal reforming in an autothermal reforming unit (ATR) after conducting said steam methane reforming for producing said synthesis gas.

3. The method of claim 1 , comprising recycling at least part of said tail gas to upstream said reforming reactor and/or upstream said ATR.

4. The method according to claim 1 , wherein the electrical power supplied is generated at least partly by means of renewable energy sources.

5. The method according to claim 1 , further comprising:
providing a hydrogen separation unit downstream the reforming reactor and separating excess hydrogen from the synthesis gas stream,

and/or
adding CO 2 to the hydrocarbon feed gas.

6. The method according to claim 1 , further comprising: providing a reforming unit for separate reforming of the tail gas and optionally recycling at least a portion of the reformed tail gas to said synthetic fuel synthesis unit.

7. The method according to claim 1 , wherein a combination of steam superheating and steam generation is integrated in waste heat recovery of said synthesis gas from the reforming reactor and/the ATR, and wherein the superheated steam is used as steam feedstock in said step of carrying out said steam methane reforming.

8. The method according to claim 1 , wherein the pressure of the gas inside said reforming reactor is between 20 and 100 bar, and the temperature of the exit gas from said reforming reactor is between 85° and 1150° C.

9. The method according to claim 1 , further comprising:
pre-reforming of the hydrocarbon gas together with a steam feedstock in a pre-reforming unit prior to said steam reforming,

and/or
purifying the hydrocarbon feed gas in a gas purification unit prior to said steam reforming, and/or prior to said pre-reforming.

10. A system for producing a synthesis gas for use in the production of a hydrocarbon product, said system comprising:
a reforming reactor comprising a pressure shell housing a structured catalyst arranged to catalyze steam reforming of a feed gas comprising hydrocarbons, said structured catalyst comprising a macroscopic structure of an electrically conductive material, said macroscopic structure supporting a ceramic coating, where said ceramic coating supports a catalytically active material; wherein the reforming reactor moreover comprises an electrical power supply placed outside said pressure shell and electrical conductors connecting said electrical power supply to said structured catalyst, allowing an electrical current to run through said macroscopic structure material to thereby heat at least part of the structured catalyst to a temperature of at least 500° C.,
a synthetic fuel synthesis unit arranged to receive at least part of the synthesis gas from said reforming reactor for converting said synthesis gas into said hydrocarbon product and producing a tail gas.

11. The system according to claim 10 , comprising an autothermal reforming unit (ATR) downstream said reforming reactor, and/or a prereforming unit upstream said reforming reactor, and/or a gas purification unit for purification of the hydrocarbon gas upstream said prereforming unit and/or upstream said reforming reactor.

12. The system according to claim 10 , wherein the system is absent of an autothermal reformer unit (ATR) downstream said reforming reactor.

13. The system according to claim 10 , comprising a reforming unit for separate reforming of the tail gas and optionally also means for recycling at least a portion of the reformed tail gas to said synthetic fuel synthesis unit.

14. The system according to claim 10 , wherein catalyst pellets are loaded on top of, around, inside, or below the structured catalyst of the reforming reactor.

15. The system according to claim 10 , wherein the reforming reactor comprises at least two conductors electrically connected to said structured catalyst and to an electrical power supply placed outside said pressure shell, wherein said electrical power supply is dimensioned to heat at least part of said structured catalyst to a temperature of at least 500° C. by passing an electrical current through said macroscopic structure, wherein said at least two conductors are connected to the structured catalyst at a position on the structured catalyst closer to a first end of said structured catalyst than to a second end of said structured catalyst, and wherein the structured catalyst is constructed to direct an electrical current to run from one conductor substantially to the second end of the structured catalyst and return to a second of said at least two conductors.

16. The system according to claim 10 , wherein the length of the gas passage through the structured catalyst is less than the length of passage of current from one conductor through the structured catalyst and to the next conductor.

17. The method according to claim 1 , wherein the method is configured for producing a synthesis gas for use in the production of a synthetic fuel.

18. The system according to claim 10 , wherein the system is configured for producing a synthesis gas for use in the production of a synthetic fuel.

Assignees

• Topsoe As

Inventors

• Mortensen Peter Mølgaard
• Aasberg-Petersen Kim
• Nielsen Charlotte Stub

Classifications

• C01B3/38 Primary

  using catalysts · CPC title

• C01B2203/1241

  Natural gas or methane · CPC title

• C01B2203/085

  by electric heating · CPC title

• C01B2203/0233

  the reforming step being a steam reforming step · CPC title

• C10G2/00

  Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon · CPC title