Process for conversion of natural gas to hydrocarbon products and a plant for carrying out the process

Patent metadata

Field	Value
Publication number	US-9353022-B2
Application number	US-201414556342-A
Country	US
Kind code	B2
Filing date	Dec 1, 2014
Priority date	Dec 2, 2013
Publication date	May 31, 2016
Grant date	May 31, 2016

Abstract

A process for the conversion of natural gas to hydrocarbon products by (a) mixing natural gas with a small amount of hydrogen, (b) purifying the mixture from (a) to obtain purified natural gas, (c) mixing the purified natural gas from (b) with steam to obtain the desired steam-to-carbon (S/C) ratio, (d) mixing the natural gas/steam mixture from (c) with tail gas from the downstream Fischer-Tropsch synthesis and converting the mixture into a synthesis gas, (e) cooling the synthesis gas from (d) and condensing out the process water from it, (f) leading the dry synthesis gas from (e) to a carbon dioxide removal section, and (g) sending the CO2-deprived synthesis gas to the downstream Fischer-Tropsch synthesis unit as a make-up gas. The carbon dioxide removed from the syngas in step (f) is either vented or kept for other use without any part of it being recycled.

First claim

What is claimed is:

1. A process for the conversion of natural gas to hydrocarbon products, said process comprising the steps of:
(a) mixing natural gas with hydrogen,
(b) purifying the mixture from (a) in a feed purification section to obtain purified natural gas,
(c) mixing the purified natural gas from (b) with steam to obtain a desired steam-to-carbon (S/C) ratio,
(d) mixing the natural gas/steam mixture from (c) with all or a part of a tail gas from a downstream Fischer-Tropsch (FT) synthesis unit in a syngas section and converting the mixture into a synthesis gas,
(e) cooling the synthesis gas from (d) and condensing out the process water from the synthesis gas from step (d),
(f) leading the dry synthesis gas from (e) to a carbon dioxide removal section, where the CO 2 is removed from the synthesis gas, and
(g) sending the CO 2 -deprived synthesis gas to the downstream Fischer-Tropsch synthesis unit as a make-up gas,
wherein the carbon dioxide removed from the syngas in step (f) is either vented or stored without any part of the CO 2 gas being recycled, and wherein no naphtha recycle is performed.

2. The process according to claim 1 , wherein the feed purification section comprises one or more desulfurization reactors.

3. The process according to claim 1 , wherein any non-recycled part of the tail gas from the FT synthesis unit is used as a fuel.

4. The process according to claim 1 , wherein the syngas section consists of one or several catalytic reactors and/or reformers selected from the group consisting of an adiabatic pre-reformer, a tubular reformer and/or an autothermal reformer (ATR) consisting of a burner for partial oxidation of the feed stream with oxygen and an adiabatic catalyst bed.

5. The process according to claim 1 , wherein the syngas section includes a heat exchange reformer, either in parallel with an SMR and/or ATR or upsteam and in series with the SMR and/or ATR.

6. The process according to claim 1 , wherein the syngas section comprises a steam methane reformer (SMR), an autothermal reformer (AIR), a catalytic partial oxidation (CPO) reformer or a combination of these reforming technologies.

7. The process according to claim 1 , wherein the syngas section comprises a pre-reformer combined with an autothermal reformer (ATR).

8. The process according to claim 1 , wherein a part of the FT tail gas is added directly to an SMR, ATR or CPO reformer.

9. The process according to claim 1 , wherein a part of the FT tail gas is added to desulfurization reactors or to an adiabatic pre-reformer.

10. The process according to claim 1 , wherein a catalyst in the FT synthesis unit is based on a transition metal selected from the group consisting of cobalt, iron, and ruthenium.

Assignees

• Haldor Topsoe As
• Haldor Topsoe As

Inventors

• Lindell Kristian
• Christensen Thomas Sandahl
• Hultqvist Michael
• Aasberg-Petersen Kim

Classifications

• C01B2203/062

  Hydrocarbon production, e.g. Fischer-Tropsch process · CPC title

• C01B3/38 Primary

  using catalysts · CPC title

• C01B2203/0233

  the reforming step being a steam reforming step · CPC title

• B01J8/08

  with moving particles (with fluidised particles B01J8/18) · CPC title

• C01B2203/0244

  the reforming step being an autothermal reforming step, e.g. secondary reforming processes · CPC title