Compositions comprising cyclic olefins and thermally conductive filler

Patent metadata

Field	Value
Publication number	US-12338316-B2
Application number	US-202017762498-A
Country	US
Kind code	B2
Filing date	Oct 2, 2020
Priority date	Oct 14, 2019
Publication date	Jun 24, 2025
Grant date	Jun 24, 2025

Abstract

A composition is described comprising a cyclic olefin; a ring opening metathesis polymerization catalyst; and at least 40 wt. % of thermally conductive particles. The thermally conductive particles are selected such that the composition after curing has a thermal conductivity of at least 1W/M*K. In one embodiment, the thermally conductive particle comprises a combination of smaller and larger thermally conductive particles. In another embodiment, the thermally conductive particles comprise boron nitride particles. Also described are (e.g. structural) adhesives, methods of bonding and articles.

First claim

What is claimed is:

1. A battery module comprising a plurality of battery cells connected to a first base plate by a first layer of a curable composition comprising:
a cyclic olefin;
a ring opening metathesis polymerization catalyst; and
at least 40 wt. % of thermally conductive particles;
wherein the composition has a thermal conductivity of at least 1 W/M*K after curing.

2. The battery module of claim 1 wherein the thermally conductive particles are selected from the group consisting of alumina, alumina trihydrate, silicon carbide, boron nitride, aluminum nitride, graphite, zinc oxide, and a combination thereof.

3. The battery module of claim 1 wherein at least 20 vol. % of the thermally conductive particles have a particle size no greater than 10 microns.

4. The battery module of claim 1 wherein at least 10 vol. % of the thermally conductive particles have a particle size of at least 30 microns.

5. The battery module of claim 1 wherein the composition further comprises thermally conductive particles having an intermediate particle size ranging from greater than 10 microns to less than 30 microns.

6. The battery module of claim 1 wherein the cyclic olefin comprises a cyclic moiety with at least two carbon-carbon double bonds.

7. The battery module of claim 1 wherein the cyclic olefin comprises moieties selected from cyclopentadiene and oligomers thereof.

8. The battery module of claim 1 wherein the cyclic olefin further comprises a cyclic mono-olefin.

9. The battery module of claim 8 wherein the cyclic olefin further comprises alkyl norbornene.

10. The battery module of claim 1 wherein the cyclic olefin is present in an amount from 5 to 60 wt. % of the total composition.

11. The battery module of claim 1 further comprising an isocyanate adhesion promotor, a dispersant, a functional elastomer, or a combinations thereof.

12. The battery module of claim 11 wherein the isocyanate adhesion promotor is the reaction product of a polyol and methylene diphenyl diisocyante (MDI), where the polyol has one or more oxygen atoms in the backbone.

13. The battery module of claim 1 wherein the catalyst is a ruthenium or osmium metal carbene catalyst.

14. The battery module of claim 1 wherein the cyclic olefin is polymerized and the composition has one or more of the following physical properties:
i) a glass transition temperature of at least 70° C.;
ii) overlap shear adhesion to aluminum of at least 1, 2, 3, 4, or 5 MPa at 140° C.;
iii) dielectric constant of less than 4;
iv) a tan delta of less than 0.005; and
v) density/volume % filler of less than 5.5.

15. A method of bonding a battery module comprising:
providing a composition comprising:
a cyclic olefin;
a ring opening metathesis polymerization catalyst; and
at least 40 wt. % of thermally conductive particles;
wherein the composition has a thermal conductivity of at least 1 W/M*K after curing;
applying the composition between a plurality of battery cells and a first base plate; and
polymerizing the cyclic olefin.

Assignees

• 3M Innovative Properties Company

Inventors

• Perez Mario A
• Yao Li
• Pyun Eumi
• Lin Binhong
• Kropp Michael A
• Vang Kalc C
• Kryger Matthew J

Classifications

• C08K2201/005

  Additives being defined by their particle size in general · CPC title

• C08K2201/001

  Conductive additives · CPC title

• C08K2003/385

  Binary compounds of nitrogen with boron · CPC title

• C08K3/38

  Boron-containing compounds · CPC title

• C08G2261/418

  Ring opening metathesis polymerisation [ROMP] · CPC title