Transparent 3D printed siloxane elastomers

Patent metadata

Field	Value
Publication number	US-12331204-B2
Application number	US-202017075549-A
Country	US
Kind code	B2
Filing date	Oct 20, 2020
Priority date	Oct 20, 2020
Publication date	Jun 17, 2025
Grant date	Jun 17, 2025

Abstract

An ink includes a siloxane polymer having at least 13 mol. % diphenylsiloxane content relative to the total mol. % of the siloxane polymer, and a filler having a refractive index about matching a refractive index of the siloxane polymer where the refractive indices are within about 5% of one another but are ideally as closely matched as possible.

First claim

What is claimed is:

1. An ink, comprising:
a siloxane polymer having at least 13 mol. % diphenylsiloxane content relative to the total mol. % of the siloxane polymer; and
a filler, wherein the siloxane polymer has a defined diphenyl content predetermined to cause a refractive index of the siloxane polymer to be within about 5% of a refractive index of the filler.

2. The ink as recited in claim 1 , wherein the diphenyl content is in a range of at least 13 mol. % to less than 18 mol. %.

3. The ink as recited in claim 1 , wherein the siloxane polymer is a copolymer having dimethylsiloxane content.

4. The ink as recited in claim 1 , wherein the filler includes fumed silica.

5. The ink as recited in claim 1 , wherein the filler is present in the ink at about 5 wt. % to about 50 wt. % relative to the total weight of the ink.

6. The ink as recited in claim 1 , further comprising a branched siloxane resin.

7. The ink as recited in claim 1 , further comprising a crosslinking catalyst.

8. The ink as recited in claim 1 , further comprising a rheology modifying additive.

9. The ink as recited in claim 1 , wherein the ink is characterized as being transparent after curing.

10. The ink as recited in claim 1 , wherein the siloxane polymer has a viscosity in a range of about 100 centistokes to about 50,000 centistokes.

11. A product, comprising:
a transparent three-dimensional (3D) structure having physical characteristics of formation by additive manufacturing,
wherein the structure includes a siloxane polymer having a refractive index and at least 13 mol. % diphenylsiloxane content relative to the total mol. % of the siloxane polymer, and a filler having a refractive index, wherein the siloxane polymer has a defined diphenyl content predetermined to cause the refractive index of the siloxane polymer to be about matching the refractive index of the filler.

12. The product as recited in claim 11 , wherein the diphenyl content is in a range of at least 13 mol. % to less than 18 mol. %.

13. The product as recited in claim 11 , wherein the siloxane polymer is a copolymer having dimethylsiloxane content.

14. The product as recited in claim 11 , wherein the 3D structure is part of a microfluidic system.

15. The product as recited in claim 11 , wherein the 3D structure includes an elastomeric lens.

16. A method, comprising:
extruding an ink for forming a three-dimensional (3D) structure, the ink comprising:
a siloxane polymer having at least 13 mol. % diphenylsiloxane content relative to the total mol. % of the siloxane polymer, and
a filler, wherein the siloxane polymer has a defined diphenyl content specifically tuned to cause a refractive index of the siloxane polymer to be about matching a refractive index of the filler, wherein the refractive indices are within about 5% of one another, the filler being present in the ink at about 5 wt. % to about 50 wt. %; and
curing the 3D structure for forming a transparent product as a result of the refractive indices.

17. The method as recited in claim 16 , wherein the diphenyl content is in a range of at least 13 mol. % to less than 18 mol. %.

18. The method as recited in claim 16 , wherein the siloxane polymer is a copolymer having dimethylsiloxane content.

19. The method as recited in claim 16 , wherein the ink is extruded by a direct ink writing device.

20. The method as recited in claim 16 , wherein the curing is selected from the group of techniques consisting of: thermal curing, ultraviolet curing, peroxide curing, and moisture curing.

Assignees

• L Livermore Nat Security Llc

Inventors

• Lenhardt Jeremy M

Classifications

• B33Y70/10

  Composites of different types of material, e.g. mixtures of ceramics and polymers or mixtures of metals and biomaterials · CPC title

• C08G77/04

  Polysiloxanes · CPC title

• B33Y80/00

  Products made by additive manufacturing · CPC title

• B29K2083/00

  Use of polymers having silicon, with or without sulfur, nitrogen, oxygen, or carbon only, in the main chain, as moulding material · CPC title

• B33Y10/00

  Processes of additive manufacturing · CPC title