Electrically conductive firebrick system

Patent metadata

Field	Value
Publication number	US-12328805-B2
Application number	US-202318526880-A
Country	US
Kind code	B2
Filing date	Dec 1, 2023
Priority date	Oct 23, 2020
Publication date	Jun 10, 2025
Grant date	Jun 10, 2025

Abstract

A thermal energy storage system includes a firebrick checkerwork and an electrode. The firebrick checkerwork includes one or more conductive firebrick layers, each including a plurality of electrically conductive doped metal oxide firebricks with one or more airflow vents. The electrode includes one or more electrode firebrick layers, each layer including a plurality of electrode firebricks. The firebrick checkerwork is heated due to application of electrical power to the electrode. Air flowing through the firebrick checkerwork may then be heated for use in heat-related applications (e.g., an industrial application, commercial application, residential application, transportation application, etc.) some of which may relate to electricity production or in other applications which may relate to other purposes that require heat that are unrelated to electricity production.

First claim

What is claimed is:

1. A thermal energy storage system comprising:
a firebrick layout comprising one or more conductive firebrick layers, each conductive firebrick layer comprising a plurality of electrically conductive semiconductor-doped metal oxide firebricks;
one or more channels to allow airflow through the firebrick layout; and
a first electrode comprising one or more electrode firebrick layers, each electrode firebrick layer comprising a plurality of electrode firebricks, the first electrode configured to receive electrical power from a source;
wherein in response to application of electrical power, the firebrick layout is heated and wherein the one or more conductive firebrick layers are configured such that air flowing through the one or more channels through firebrick layout is heated.

2. The system of claim 1 wherein the firebrick layout comprises a checkerwork.

3. The system of claim 1 wherein the firebrick layout comprises one or more vertically stacked firebrick columns.

4. The system of claim 1 wherein the plurality of electrically conductive semiconductor-doped metal oxide firebricks comprises one or more chimney vents.

5. The system of claim 1 , further comprising:
a second electrode comprising one or more second electrode firebrick layers, each second electrode firebrick layer comprising a plurality of second electrode firebricks;
wherein the firebrick layout comprises a plurality of electrically isolated firebrick portions and the first electrode comprises a plurality of electrically isolated electrode portions; and
wherein the second electrode is configured to electrically couple two or more of the electrically isolated firebrick portions of the firebrick layout to form an electrical transmission path through the firebrick layout.

6. The system of claim 5 , wherein each of the plurality of electrically isolated electrode portions is defined by a plurality of non-conductive firebricks.

7. The system of claim 5 , wherein each of the plurality of electrically isolated firebrick portions is defined by a plurality of non-conductive firebricks.

8. The system of claim 7 , wherein the non-conductive firebricks comprise one or more of alumina, magnesia, or silica.

9. The system of claim 5 , wherein the second electrode is configured to provide a neutral point for electrical power provided as 3-phase power and wherein the thermal energy storage system operates in a wye configuration.

10. The system of claim 5 , wherein:
the second electrode comprises a plurality of electrically isolated second electrode portions, and
the plurality of electrically isolated firebrick portions, the plurality of electrically isolated electrode portions, and the plurality of electrically isolated second electrode portions are configured to provide an electrical path through each electrically isolated firebrick portion.

11. The system of claim 10 , wherein a number of snaking portions of each electrical path is an even number for the thermal energy storage system to operate in a 3-phase delta configuration, and wherein the number of snaking portions of each electrical path is an odd number for the thermal energy storage system to operate in a 3-phase wye configuration.

12. The system of claim 1 , further comprising one or more insulating layers, the insulating layers comprising one or more insulating firebrick layers, each insulating firebrick layer comprising a plurality of non-conductive firebricks having one or more vents for allowing airflow through the firebrick.

13. The system of claim 1 , wherein the electrically conductive semiconductor-doped metal oxide firebricks comprise one of: chromium oxide doped with nickel, chromium oxide doped with magnesium, nickel oxide doped with lithium, nickel oxide doped with copper, zinc oxide doped with aluminum, stabilized zirconium oxide doped with cerium, and titanium oxide doped with niobium.

14. The system of claim 1 , wherein the electrode firebricks comprise one of: chromium oxide doped with nickel, chromium oxide doped with magnesium, nickel oxide doped with lithium, nickel oxide doped with copper, zinc oxide doped with aluminum, stabilized zirconium oxide doped with cerium, or titanium oxide doped with niobium.

15. The system of claim 1 , wherein the electrically conductive semiconductor-doped metal oxide firebricks comprise a high temperature metal oxide doped with a metal of a different valency.

16. The system of claim 15 , wherein the electrically conductive semiconductor-doped metal oxide firebricks further comprise an electrically inactive oxide.

17. The system of claim 16 , wherein the electrically inactive oxide comprises one of alumina, magnesia, or silica.

18. A method of storing thermal energy, the method comprising:
providing a firebrick layout having one or more conductive firebrick layers, each conductive firebrick layer comprising a plurality of electrically conductive semiconductor-doped metal oxide firebricks;

forming one or more channels to allow airflow through the firebrick layout;
coupling a first electrode to the one or more conductive firebrick layers, the first electrode comprising one or more electrode firebrick layers, each electrode firebrick layer comprising a plurality of electrode firebricks, the first electrode configured to receive electrical power from a source;
in response to electrical power, heating the one or more conductive firebrick layers; and
heating an air flow through the one or more channels formed in the firebrick layout.

19. An apparatus, comprising:
a first electrode;
a second electrode;
electrically conductive firebricks; and
wherein the electrically conductive firebricks are disposed between the first electrode and the second electrode and electrically connected in a predetermined pattern, each of the electrically conductive firebricks including a semiconductor-doped metal oxide material configured to generate heat based on an electric potential applied between the first electrode and the second electrode.

20. A method, comprising:
providing a first electrode;
providing a second electrode;
disposing a plurality of electrically conductive firebricks between the first electrode and the second electrode; each of the electrically conductive firebricks including a semiconductor-doped metal oxide material configured to generate heat based on an electric potential applied between the first electrode and the second electrode; and
electrically connecting the plurality of conductive firebricks between the first electrode and the second electrode in a predetermined pattern.

Assignees

• Massachusetts Inst Technology

Inventors

• Forsberg Charles
• Stack Daniel C

Classifications

• F24H2250/10

  Electrodes · CPC title

• F24H3/062

  using electric energy supply; the heating medium being the resistive element (F24H3/08, F24H3/10 takes precedence) · CPC title

• H05B7/06 Primary

  Electrodes · CPC title

• H05B3/24

  heating conductor being self-supporting · CPC title

• F28D20/0056

  using solid heat storage material (F28D20/0052 takes precedence) · CPC title