Electrically conductive firebrick system

Patent metadata

Field	Value
Publication number	US-11877376-B2
Application number	US-202117462244-A
Country	US
Kind code	B2
Filing date	Aug 31, 2021
Priority date	Oct 23, 2020
Publication date	Jan 16, 2024
Grant date	Jan 16, 2024

Abstract

A thermal energy storage system includes a firebrick checkerwork and an electrode. The firebrick checkerwork includes one or more conductive firebrick layers, each including a plurality of electrically conductive doped metal oxide firebricks with one or more airflow vents. The electrode includes one or more electrode firebrick layers, each layer including a plurality of electrode firebricks. The firebrick checkerwork is heated due to application of electrical power to the electrode. Air flowing through the firebrick checkerwork may then be heated for use in heat-related applications (e.g., an industrial application, commercial application, residential application, transportation application, etc.) some of which may relate to electricity production or in other applications which may relate to other purposes that require heat that are unrelated to electricity production.

First claim

We claim:

1. A thermal energy storage system comprising:
a firebrick checkerwork comprising one or more conductive firebrick layers, each conductive firebrick layer comprising a plurality of electrically conductive semiconductor-doped metal oxide firebricks having one or more vents to allow airflow through the firebrick checkerwork; and
a first electrode comprising one or more electrode firebrick layers, each electrode firebrick layer comprising a plurality of electrode firebricks, the first electrode configured to receive electrical power from a source;
wherein the firebrick checkerwork is heated due to application of the received electrical power, and wherein air flowing through the firebrick checkerwork is heated by the firebrick checkerwork.

2. The system of claim 1 , further comprising:
a second electrode comprising one or more electrode firebrick layers, each electrode firebrick layer comprising a plurality of electrode firebricks;
wherein the firebrick checkerwork comprises a plurality of electrically isolated checkerwork portions and the first electrode comprises a plurality of electrically isolated electrode portions; and
wherein the second electrode is configured to electrically couple two or more of the electrically isolated checkerwork portions of the firebrick checkerwork to form an electrical transmission path through the firebrick checkerwork.

3. The system of claim 2 , wherein each of the plurality of electrically isolated electrode portions is configured to receive an isolated electrical phase from the source.

4. The system of claim 2 , wherein the second electrode is configured to provide a neutral point for electrical power provided as 3-phase power and wherein the thermal energy storage system operates in a wye configuration.

5. The system of claim 2 , wherein:
the second electrode comprises a plurality of electrically isolated second electrode portions, and
the plurality of electrically isolated checkerwork portions, the plurality of electrically isolated electrode portions, and the plurality of electrically isolated second electrode portions are configured to provide an electrical path through each electrically isolated checkerwork portion.

6. The system of claim 5 , wherein a number of snaking portions of each electrical path is an even number for the thermal energy storage system to operate in a 3-phase delta configuration, and wherein the number of snaking portions of each electrical path is an odd number for the thermal energy storage system to operate in a 3-phase wye configuration.

7. The system of claim 1 , further comprising one or more insulating layers, the insulating layers comprising one or more insulating firebrick layers, each insulating firebrick layer comprising a plurality of non-conductive firebricks having one or more vents for allowing airflow through the firebrick.

8. The system of claim 7 , wherein the non-conductive firebricks comprise one or more of alumina, magnesia, or silica.

9. The system of claim 1 , wherein the electrically conductive semiconductor-doped metal oxide firebricks comprise one of: chromium oxide doped with nickel, chromium oxide doped with magnesium, nickel oxide doped with lithium, nickel oxide doped with copper, zinc oxide doped with aluminum, stabilized zirconium oxide doped with cerium, and titanium oxide doped with niobium.

10. The system of claim 9 , wherein the electrically conductive semiconductor-doped metal oxide firebricks are doped with a concentration of approximately 10 20 /cm 3 .

11. The system of claim 1 , wherein the electrode firebricks comprise one of:
chromium oxide doped with nickel, chromium oxide doped with magnesium, nickel oxide doped with lithium, nickel oxide doped with copper, zinc oxide doped with aluminum, stabilized zirconium oxide doped with cerium, or titanium oxide doped with niobium.

12. The system of claim 11 , wherein the electrode firebricks are highly doped with a concentration of approximately 10 21 /cm 3 to be highly conductive and provide low heat generation.

13. The system of claim 11 , wherein a dopant mix is approximately 2% to 5%.

14. The system of claim 1 , wherein the firebrick checkerwork is heated to a temperature between 1000° C. and 2000° C.

15. The system of claim 1 , wherein the electrically conductive semiconductor-doped metal oxide firebricks comprise a high temperature metal oxide doped with a metal of a different valency.

16. The system of claim 15 , wherein the electrically conductive semiconductor-doped metal oxide firebricks further comprise an electrically inactive oxide.

17. The system of claim 16 , wherein the electrically inactive oxide comprises one of alumina, magnesia, or silica.

18. An apparatus, comprising:
a first electrode;
a second electrode; and
electrically conductive firebricks,
wherein the electrically conductive firebricks are disposed between the first electrode and the second electrode in a predetermined pattern, each of the electrically conductive firebricks including a semiconductor-doped metal oxide material configured to generate heat based on an electric potential applied between the first electrode and the second electrode.

19. The apparatus of claim 18 , wherein:
the predetermined pattern includes a plurality of overlapping layers of the electrically conductive firebricks, and
the electrically conductive firebricks are spaced to form air flow channels.

20. An apparatus, comprising:
a first electrode;
a second electrode; and
electrically conductive firebricks,
wherein the electrically conductive firebricks are disposed between the first electrode and the second electrode in a predetermined pattern, each of the electrically conductive firebricks including a doped metal oxide material configured to generate heat based on an electric potential applied between the first electrode and the second electrode;
wherein each of the electrically conductive firebricks includes a dopant concentration that corresponds to a temperature of the heat to be generated based on the potential applied between the first electrode and the second electrode.

Assignees

• Massachusetts Inst Technology

Inventors

• Forsberg Charles
• Stack Daniel C

Classifications

• F28D20/0056

  using solid heat storage material (F28D20/0052 takes precedence) · CPC title

• H05B3/141

  Conductive ceramics, e.g. metal oxides, metal carbides, barium titanate, ferrites, zirconia, vitrous compounds · CPC title

• H05B7/06 Primary

  Electrodes · CPC title

• H05B3/14 Primary

  the material being non-metallic · CPC title

• H05B3/12 Primary

  characterised by the composition or nature of the conductive material · CPC title