Processing hard rock lithium minerals or other materials to produce lithium materials and byproducts converted from a sodium sulfate intermediate product
US-2024425381-A1 · Dec 26, 2024 · US
US12325641B2 · US · B2
| Field | Value |
|---|---|
| Publication number | US-12325641-B2 |
| Application number | US-202418816364-A |
| Country | US |
| Kind code | B2 |
| Filing date | Aug 27, 2024 |
| Priority date | Apr 24, 2024 |
| Publication date | Jun 10, 2025 |
| Grant date | Jun 10, 2025 |
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The present disclosure is directed to systems and methods of producing lithium carbonate. The lithium carbonate can be produced by contacting a lithium precursor with a carbon dioxide gas. The lithium carbonate produced from this method can include micron-sized lithium carbonate particles with nano-sized lithium carbonate particles coated on a surface of the micron-sized lithium carbonate particles.
Opening claim text (preview).
The invention claimed is: 1. A method of producing lithium carbonate comprising: contacting a solid lithium precursor comprising lithium hydroxide with a gas comprising at least 5 wt. % carbon dioxide, thereby converting at least a portion of the solid lithium precursor to lithium carbonate. 2. The method of claim 1 , wherein the solid lithium precursor is milled in a jet mill with an atmosphere comprising the gas. 3. The method of claim 1 , wherein the solid lithium precursor further comprises inorganic lithium salts, organic lithium salts, lithium metals, lithium alloys, lithium oxides, lithium hydroxides, or combinations thereof. 4. The method of claim 1 , wherein the lithium hydroxide is lithium hydroxide monohydrate. 5. The method of claim 1 , wherein the gas comprises at least 25 wt. % carbon dioxide. 6. The method of claim 5 , wherein the gas comprises at least 50 wt. % carbon dioxide. 7. The method of claim 1 , wherein at least 75% of the solid lithium precursor is converted into lithium carbonate. 8. The method of claim 1 , wherein the lithium carbonate comprises micron-sized lithium carbonate particles and nano-sized lithium carbonate particles coated on the micron-sized lithium carbonate particles. 9. The method of claim 8 , wherein the micron-sized lithium carbonate particles have a particle size distribution with a D50 of 1-10 microns. 10. The method of claim 8 , wherein at least a portion of the micron-sized lithium carbonate particles are hollow. 11. The method of claim 1 , wherein the lithium carbonate has a Brunauer-Emmett-Teller (BET) specific surface area of about 2-12 m 2 /g. 12. The method of claim 1 , further comprising drying the lithium carbonate with or without presence of carbon dioxide gas in a fluidized bed. 13. A powder comprising: micron-sized lithium carbonate particles; and nano-sized lithium carbonate particles coated on a surface of the micron-sized lithium carbonate particles. 14. The powder of claim 13 , wherein at least a portion of the micron-sized lithium carbonate particles are hollow. 15. The powder of claim 13 , wherein the micron-sized lithium carbonate particles have a particle size distribution with a D50 of 1-10 microns. 16. The powder of claim 13 , wherein the lithium carbonate has a Brunauer-Emmett-Teller (BET) specific surface area of about 2-12 m 2 /g.
Powder free flowing behaviour · CPC title
obtained by SEM · CPC title
hollow · CPC title
one phase coated with the other · CPC title
Micrometer sized, i.e. from 1-100 micrometer · CPC title
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