System for producing a fully impregnated thermoplastic prepreg

Patent metadata

Field	Value
Publication number	US-12319016-B2
Application number	US-202217981027-A
Country	US
Kind code	B2
Filing date	Nov 4, 2022
Priority date	Jul 8, 2015
Publication date	Jun 3, 2025
Grant date	Jun 3, 2025

Abstract

A system for manufacturing a thermoplastic prepreg includes a double belt mechanism that is configured to compress a fiber mat, web, or mesh that is passed through the double belt mechanism, a resin applicator that is configured to apply monomers or oligomers to the fiber mat, web, or mesh, and a curing oven that is configured to effect polymerization of the monomers or oligomers and thereby form the thermoplastic polymer as the fiber mat, web, or mesh is moved through the curing oven. The double belt mechanism compresses the fiber mat, web, or mesh and the applied monomers or oligomers as the fiber mat, web, or mesh is passed through the curing oven so that the monomers or oligomers fully saturate the fiber mat, web, or mesh. Upon polymerization of the monomers or oligomers, the fiber mat, web, or mesh is fully impregnated with the thermoplastic polymer.

First claim

What is claimed is:

1. A method of forming a composite product comprising:
providing a thermoplastic prepreg formed by:
dispersing, via a fiber chopper or fiber scattering device, chopped fibers atop a lower belt of a double belt press mechanism to form a nonwoven fiber mat, web, or mesh, the double belt mechanism including an upper belt and the lower belt, the upper belt being positioned atop the lower belt and the lower belt having a longitudinal length that is substantially longer than the upper belt;
moving the nonwoven fiber mat, web, or mesh atop the lower belt;
applying monomers or oligomers to the nonwoven fiber mat, web, or mesh via a resin applicator that is positioned atop the lower belt;
passing the nonwoven fiber mat, web, or mesh and the applied monomers or oligomers between the lower belt and an upper belt of the double belt press mechanism to press the monomers or oligomers through the nonwoven fiber mat, web, or mesh and thereby fully saturate the nonwoven fiber mat, web, or mesh with the monomers or oligomers;
passing the fully saturated nonwoven fiber mat, web, or mesh through a curing oven that is configured to polymerize the monomers or oligomers as the nonwoven fiber mat, web, or mesh is moved through the curing oven, wherein the nonwoven fiber mat, web, or mesh is fully impregnated with a thermoplastic polymer upon polymerization of the monomers or oligomers; and

coupling a unidirectional tape to at least one side of the nonwoven fiber mat, web, or mesh that is fully impregnated with the thermoplastic polymer.

2. The method of claim 1 , wherein coupling the unidirectional tape to the at least one side of the nonwoven fiber mat, web, or mesh that is fully impregnated with the thermoplastic polymer comprises compression molding the unidirectional tape to the at least one side of the nonwoven fiber mat, web, or mesh that is fully impregnated with the thermoplastic polymer.

3. A method of forming a thermoplastic prepreg comprising:
dispersing, via a fiber chopper or fiber scattering device, chopped fibers atop a lower belt of a double belt press mechanism to form a nonwoven fiber mat, web, or mesh;
applying monomers or oligomers to the fiber mat, web, or mesh via a resin applicator that is positioned atop the lower belt;
passing the fiber mat, web, or mesh and the applied monomers or oligomers between the lower belt and an upper belt of the double belt press mechanism to press the monomers or oligomers through the fiber mat, web, or mesh and thereby fully saturate the fiber mat, web, or mesh with the monomers or oligomers;
passing the fully saturated fiber mat, web, or mesh through a curing oven that is configured to polymerize the monomers or oligomers as the fiber mat, web, or mesh is moved through the curing oven and thereby form a thermoplastic polymer that fully impregnates the fiber mat, web, or mesh; and
coupling a unidirectional tape with at least one side of the fiber mat, web, or mesh that is fully impregnated with the thermoplastic polymer.

4. The method of claim 3 , further comprising mixing the monomers or oligomers with at least one of a catalyst or an activator to form a reactive resin mixture, the catalyst and activator facilitating in polymerizing the monomers or oligomers to form the thermoplastic polymer.

5. The method of claim 3 , further comprising applying a moisture-free gas onto the fiber mat, web, or mesh after application of the monomers or oligomers to substantially prevent exposure of the monomers or oligomers to ambient moisture in a surrounding environment.

6. The method of claim 3 , further comprising drying the fiber mat, web, or mesh via a drying mechanism that is positioned atop the lower belt to remove residual moisture from the fiber mat, web, or mesh.

7. The method of claim 3 , further comprising passing the fiber mat, web, or mesh that is fully impregnated with the thermoplastic polymer through a cooling mechanism after polymerization of the monomers or oligomers.

8. The method of claim 3 , further comprising unwinding a fabric, nonwoven mat, or unidirectional tape from a roller and moving the fabric, nonwoven mat, or unidirectional tape atop the lower belt.

9. The method of claim 3 , wherein the fiber mat, web, or mesh includes glass fibers, carbon fibers, basalt fibers, metal fibers, ceramic fiber, natural fibers, synthetic organic fibers, aramid fibers, inorganic fibers, or combinations thereof.

10. The method of claim 3 , further comprising adding a toughening agent to the monomers or oligomers.

11. The method of claim 10 , wherein the toughening agent comprises a rubber material.

12. The method of claim 3 , further comprising cutting the fiber mat, web, or mesh that is fully impregnated with the thermoplastic polymer into sheets.

13. The method of claim 3 , wherein the monomers or oligomers comprises lactams, lactones, cyclic butylene terephthalate (CBT), methyl methacrylate, precursors of thermoplastic polyurethane, or mixtures thereof.

14. The method of claim 13 , wherein the lactams comprise caprolactam, laurolactam, or mixtures thereof.

15. The method of claim 3 , wherein coupling the unidirectional tape with the at least one side of the fiber mat, web, or mesh that is fully impregnated with the thermoplastic polymer comprises:
positioning the fiber mat, web, or mesh that is fully impregnated with the thermoplastic polymer in a mold;
positioning the unidirectional tape on the at least one side of the fiber mat, web, or mesh that is fully impregnated with the thermoplastic polymer within the mold; and
applying heat and pressure to the unidirectional tape and the fiber mat, web, or mesh that is fully impregnated with the thermoplastic polymer to mold the unidirectional tape to the at least one side of the fiber mat, web, or mesh that is fully impregnated with the thermoplastic polymer.

Assignees

• Johns Manville

Inventors

• Zhang Mingfu
• Chaparro-Chavez Edwing
• Asrar Jawed

Classifications

• D06M15/51

  Unsaturated polymerisable polyesters · CPC title

• B29K2033/12

  Polymers of methacrylic acid esters, e.g. PMMA, i.e. polymethylmethacrylate · CPC title

• B29L2009/00

  Layered products · CPC title

• B29L2007/002

  Panels; Plates; Sheets · CPC title

• B29K2105/256

  Sheets, plates, blanks or films · CPC title