Oil processing systems and methods for manufacturing a refined vegetable oil

Patent metadata

Field	Value
Publication number	US-12305144-B2
Application number	US-202017441081-A
Country	US
Kind code	B2
Filing date	Mar 11, 2020
Priority date	Mar 22, 2019
Publication date	May 20, 2025
Grant date	May 20, 2025

Abstract

A process for manufacturing a refined vegetable oil having a reduced content of 3-monochloropropane-1.2-diol fatty acid (3-MCPD) esters characterized in that it comprises the following steps: treating a deodorized vegetable oil with a base in a continuous pipe reactor, and contacting the base treated oil with an adsorbent and/or an acid. The thus obtained oil is low in 3-MCPD and has a low degree of interesterification and a low dialkylketones (DAK) content. It further relates to the use a continuous pipe reactor for treating a deodorized vegetable oil with a base wherein 3-MCPD ester content is reduced in the oil.

First claim

The invention claimed is:

1. A process for manufacturing a refined vegetable oil, the process comprising:
A) treating a deodorized vegetable oil with a base in a continuous pipe reactor to obtain a base treated oil, wherein the deodorized vegetable oil comprises 2.5 ppm or more of 3-monochloropropane-1,2-diol fatty acid (3-MCPD) ester, and wherein the continuous pipe reactor is arranged to provide a retention time having a standard deviation of 40% or less of a mean residence time within the continuous pipe reactor, and
B) contacting the base treated oil with an adsorbent, an acid, or a combination thereof, wherein the refined vegetable oil comprises below 2.5 ppm of the 3-MCPD ester.

2. The process according to claim 1 wherein the deodorized vegetable oil in step A) has a 3-MCPD ester content of 4 ppm or more.

3. The process according to claim 1 , wherein the treating of the deodorized vegetable oil is performed at a temperature from 160 to 220° C.

4. The process according to claim 1 , wherein the base is added in a concentration of from 0.06 to 2.35 mmol/kg oil.

5. The process according to claim 1 , wherein the base is a hydroxide and is added in a concentration of 1 to 40 ppm molar equivalents of hydroxide ions.

6. The process according to claim 1 further comprising a fractionation step and/or a further refining step carried out after the contacting of the base treated oil.

7. The process according to claim 6 wherein the further refining step is carried out in a deodorizer or an oil refining equipment consisting of a stripping column with packing and not more than one oil collection tray.

8. The process according to claim 7 wherein the further refining step is carried out at a temperature below 220° C.

9. The process according to claim 1 , wherein the deodorized vegetable oil comprises a vegetable oil having undergone deodorization, wherein the vegetable oil comprises one or more of soybean oil, corn oil, cottonseed oil, palm oil, palm kernel oil, peanut oil, rapeseed oil, safflower oil, sesame seed oil, rice bran oil, coconut oil, canola oil, or blends thereof.

10. The process according to claim 1 , wherein the deodorized vegetable oil comprises deodorized palm oil, deodorized palm oil stearin, deodorized palm oil super stearin, deodorized palm oil olein, deodorized palm oil mid-fraction, or blends thereof.

11. The process according to claim 1 , wherein the deodorized vegetable oil is deodorized palm oil.

12. The process according to claim 1 further comprising subjecting a crude vegetable oil to a physical refining step to obtain the deodorized vegetable oil, wherein the physical refining step comprises degumming, bleaching, and deodorizing the crude vegetable oil.

13. The process according to claim 1 further comprising a further refining step after the contacting of the base treated oil, carried out in an oil refining equipment consisting of a stripping column with packing and not more than one oil collection tray at a temperature from 130 to 210° C., wherein the stripping column has an oil loading of from 0.5 to 4.0 kg/m2h surface of packing.

14. The process according to claim 13 , wherein the further refining step comprises use of a stripping agent comprising steam.

15. The process of claim 1 , wherein the refined vegetable oil comprises below 1.8 ppm of the 3-MCPD ester.

16. The process of claim 1 , wherein the treating of the deodorized vegetable oil is performed without injecting steam or gas into the deodorized vegetable oil.

17. The process of claim 1 , wherein the process induces a degree of interesterification of below 10%.

18. The process of claim 1 , wherein the process induces a formation of below 6.0 ppm of dialkylketones (DAK).

19. The process of claim 1 , wherein the continuous pipe reactor has a height to diameter ratio from 3.0 to 20.0.

Assignees

• Cargill Inc

Inventors

• Bruse Falk
• Tarnow Armin Willem-Friedrich Hermann
• Van Rossum Gijsbertus Johannes
• Vilas Eguileta Ignacio

Classifications

• C11B3/10

  by adsorption · CPC title

• C11B3/08

  with oxidising agents · CPC title

• C11B3/04

  with acids · CPC title

• C11B3/06 Primary

  with bases · CPC title

• C11B3/00 Primary

  Refining fats or fatty oils · CPC title