Seed oil refinement

Patent metadata

Field	Value
Publication number	US-9677028-B2
Application number	US-201514822434-A
Country	US
Kind code	B2
Filing date	Aug 10, 2015
Priority date	Aug 10, 2015
Publication date	Jun 13, 2017
Grant date	Jun 13, 2017

Abstract

Methods for refining crude tobacco seed oils and the refined tobacco seed oils produced by such methods are provided herein. In particular, methods for reducing the amount of free fatty acids in the crude oil, for modifying the color of the crude oil, and for reducing any undesirable taste/odor associated with the crude oil are provided. The present invention further relates to the incorporation and use of such refined oil within various products.

First claim

The invention claimed is:

1. A method of refining a crude oil derived from a seed of a plant of the Nicotiana species, comprising:
a) treating the crude oil derived from a seed of a plant of the Nicotiana species with acid to give an acid-treated oil;
b) neutralizing the acid-treated oil with a basic aqueous solution to give a neutralized mixture and separating a precipitate from the neutralized mixture to give a neutralized oil; and
c) bleaching the neutralized oil, deodorizing the neutralized oil, or both bleaching and deodorizing the neutralized oil, wherein the bleaching comprises contacting the neutralized oil with at least two bleaching clays, wherein the at least two bleaching clays have different pH values,

to provide a refined tobacco seed oil comprising less than 5% free fatty acids by weight, wherein the method results in at least 10% less loss than traditional methods of refining crude oils.

2. The method of claim 1 , wherein the acid comprises citric acid.

3. The method of claim 1 , wherein the basic aqueous solution comprises sodium hydroxide.

4. The method of claim 1 , wherein the neutralizing step is conducted with minimal agitation of the acid-treated oil with the basic aqueous solution.

5. The method of claim 1 , wherein the bleaching step comprises contacting the neutralized oil with both the bleaching clay and activated carbon in a weight ratio of between about 2:1 and about 10:1 bleaching clay:activated carbon.

6. The method of claim 1 , wherein the deodorizing comprises heating the neutralized oil at an elevated temperature at a pressure below atmospheric pressure.

7. The method of claim 6 , wherein the elevated temperature is about 150° C. or greater and the pressure is about 5 mm Hg or below.

8. The method of claim 1 , further comprising obtaining the crude oil via extraction from a seed of a plant of the Nicotiana species.

9. The method of claim 8 , wherein the obtaining comprises: solvent extraction of the seed and separation of the crude oil from an extracted seed; application of pressure to the seed to expel the crude oil; or a combination thereof.

10. The method of claim 1 , wherein the refined tobacco seed oil is substantially colorless.

11. The method of claim 1 , wherein the refined tobacco seed oil is substantially odorless.

12. The method of claim 1 , further comprising determining a content of free fatty acid in the crude oil and calculating an amount of basic aqueous solution to use in step (b) based on the content of free fatty acid in the crude oil, the amount of acid added in step (a), and the desired maximum percentage of free fatty acids by weight in the neutralized oil.

13. The method of claim 12 , wherein the amount of basic aqueous solution, in moles of base, is about 95% of moles of free fatty acid plus moles of acid added to about 100% of moles of free fatty acid plus moles of acid added.

14. A method of refining a crude oil derived from a seed of a plant of the Nicotiana species, comprising:
a) treating the crude oil derived from a seed of a plant of the Nicotiana species with acid to give an acid-treated oil;
b) neutralizing the acid-treated oil with an aqueous solution of sodium hydroxide to give a neutralized mixture, separating a precipitate from the neutralized mixture to give a neutralized oil, and washing the neutralized oil with water;
c) bleaching the neutralized oil by contacting the neutralized oil with one or more bleaching agents, the bleaching agents comprising at least two bleaching clays, wherein the at least two bleaching clays have different pH values and separating a bleached oil from the bleaching agent; and
d) deodorizing the bleached oil by heating the bleached oil,

to provide a refined tobacco seed oil comprising less than 5% free fatty acids by weight, wherein the method results in at least 10% less loss than traditional methods of refining crude oils.

Assignees

• Reynolds Tobacco Co R

Inventors

• Ford Kyle
• Mua John-Paul
• Jackson Thaddeus Jude
• Mcgeown Terence

Classifications

• C11B3/06 Primary

  with bases · CPC title

• C11B3/02

  by chemical reaction {(C11B3/003 takes precedence)} · CPC title

• C11B3/10

  by adsorption · CPC title

• C11B3/04

  with acids · CPC title

• C11B3/001

  by a combination of two or more of the means hereafter · CPC title