Composites and methods of forming composites having an increased volume of oxidation resistant ceramic particles

Patent metadata

Field	Value
Publication number	US-12304869-B2
Application number	US-202217824817-A
Country	US
Kind code	B2
Filing date	May 25, 2022
Priority date	May 25, 2022
Publication date	May 20, 2025
Grant date	May 20, 2025

Abstract

A fiber reinforced composite component may include interleaved textile layers and ceramic particle layers coated with matrix material. The fiber reinforced composite component may be fabricated by forming a fibrous preform and densifying the fibrous preform. The fibrous preform may be fabricated by performing a silicon melt infiltration after the densification process. A plurality of pores defined by the carbon matrix material are infiltrated with a silicon material and the fibrous preform is heated to a melt temperature until a desired percentage (e.g., at least 50%) of the carbon matrix material is converted into silicon carbide or another oxidation resistant material.

First claim

What is claimed is:

1. A method of fabricating a composite component, comprising:
forming a fibrous preform by:
forming a first ceramic particle layer over a first textile layer by depositing a mixture of silicon carbide powder and phenolic resin powder over the first textile layer;
disposing a second textile layer over the first ceramic particle layer;
forming a second ceramic particle layer over the second textile layer; and
disposing a third textile layer over the second ceramic particle layer;

performing a densification process on the fibrous preform, the densification process including coating a plurality of fibers of the fibrous preform with a carbon matrix material; and
performing a silicon melt infiltration process after the densification process, the silicon melt infiltration process including:
infiltrating a plurality of pores defined by the carbon matrix material with a silicon material, and
heating the fibrous preform to a melt temperature until at least 50% of the carbon matrix material and at least a portion of the silicon material are converted into silicon carbide.

2. The method of claim 1 , wherein the densification process further includes applying a compressive load to the fibrous preform.

3. The method of claim 1 , wherein the plurality of fibers are carbon fibers.

4. The method of claim 1 , wherein forming the second ceramic particle layer comprises depositing a second volume of silicon carbide powder over the second textile layer.

5. The method of claim 4 , wherein forming the fibrous preform further comprises:
locating a first shim around an outer perimeter of the first textile layer;
forming the first ceramic particle layer over the first textile layer by depositing the mixture of silicon carbide powder and phenolic resin powder over the first textile layer up to at least an upper surface of the first shim;
locating a second shim around an outer perimeter of the second textile layer;
removing the first shim prior to densification; and
removing the second shim prior to densification.

6. The method of claim 5 , wherein forming the fibrous preform further comprises:
removing a portion of the first volume of silicon carbide powder extending beyond an upper surface of the first shim; and
removing a portion of the second volume of silicon carbide powder extending beyond an upper surface of the second shim.

7. The method of claim 4 , wherein forming the fibrous preform further comprises:
disposing the first textile layer on a first plate; and
disposing a second plate over the third textile layer;

wherein at least one of the first plate or the second plate includes at least one of a groove or an orifice.

8. A method of forming a fibrous preform for fabricating a composite component, comprising:
forming a first ceramic particle layer over a first textile layer, the first ceramic particle layer comprising a first volume of silicon carbide powder having an average particle size between 35 micrometers and 163 micrometers, and the first textile layer comprising pre-oxidized stretch-broken carbon fibers,
disposing a second textile layer over the first ceramic particle layer;
forming a second ceramic particle layer over the second textile layer;
disposing a third textile layer over the second ceramic particle layer;
coating at least one of the first ceramic particle layer, the first textile layer, the second textile layer, the second ceramic particle layer, or the third textile layer with a carbon matrix material;
infiltrating a plurality of pores defined by the carbon matrix material with a silicon material; and
heating the composite component to a melt temperature until at least 50% of the carbon matrix material and at least a portion of the silicon material are converted into a silicon carbide.

9. The method of claim 8 , wherein the composite component is heated to the melt temperature until at least 75% of the carbon matrix material is converted into the silicon carbide.

10. The method of claim 8 , wherein forming the second ceramic particle layer comprises depositing a second volume of silicon carbide powder over the second textile layer.

11. The method of claim 8 , further comprising:
disposing the first textile layer on a mold surface;
forming the first ceramic particle layer by depositing a mixture of silicon carbide powder and phenolic resin powder over the first textile layer, the phenolic resin powder being less than 2% by weight of the first ceramic particle layer; and
curing the phenolic resin powder.

12. The method of claim 8 , wherein at least one of the second textile layer or the third textile layer comprises stretch-broken carbon fibers.

13. The method of claim 8 , wherein a number of moles of the silicon material selected to be between 75% and 100% of a number of moles of the carbon matrix material.

14. The method of claim 8 , wherein the melt temperature is between 1410° C. (2570° F.) and 1500° C. (2732° F.).

Assignees

• Goodrich Corp

Inventors

• Kirkpatrick Christopher T

Classifications

• C04B2235/616

  Liquid infiltration of green bodies or pre-forms · CPC title

• C04B2235/604

  Pressing at temperatures other than sintering temperatures · CPC title

• C04B2235/5256

  Two-dimensional, e.g. woven structures · CPC title

• C04B2235/5248

  Carbon, e.g. graphite · CPC title

• C04B2235/3873

  Silicon nitrides, e.g. silicon carbonitride, silicon oxynitride · CPC title