Carbon/carbon composites and methods of making carbon/carbon composites having increased fiber volume and ceramic compounds

Patent metadata

Field	Value
Publication number	US-10450236-B2
Application number	US-201715714006-A
Country	US
Kind code	B2
Filing date	Sep 25, 2017
Priority date	Sep 25, 2017
Publication date	Oct 22, 2019
Grant date	Oct 22, 2019

Abstract

A method of making a carbon-carbon composite part may comprise fabricating a fibrous preform comprising a fiber volume ratio of 25% or greater, heat treating the fibrous preform at a first temperature, infiltrating the fibrous preform with a first ceramic suspension, densifying the fibrous preform by chemical vapor infiltration (CVI) to form a densified fibrous preform, and heat treating the densified fibrous preform at a second temperature of 1600° C. or greater.

First claim

What is claimed is:

1. A method of making a carbon-carbon composite part, comprising:
fabricating a carbonized fibrous preform comprising a fiber volume ratio of 25% or greater, wherein the carbonized fibrous preform includes carbon fibers comprised of at least 99% carbon;
performing a first heat treatment on the carbonized fibrous preform at a first temperature;
infiltrating the carbonized fibrous preform with a first ceramic suspension after the first heat treatment, the first ceramic suspension comprising at least one of yttrium oxide and zirconium oxide, titanium dioxide and boron, zirconium dioxide and boron, or yttrium stabilized zirconium dioxide and boron;
performing a second heat treatment on the carbonized fibrous preform at a temperature of 1200° C. or greater after the infiltrating the carbonized fibrous preform with the first ceramic suspension, wherein the second heat treatment forms a ceramic compound comprising at least one of yttrium carbide and zirconium carbide, titanium diboride, zirconium diboride, or yttrium boride;
densifying the carbonized fibrous preform by chemical vapor infiltration (CVI) after the second heat treatment to form a densified fibrous preform; and
performing a third heat treatment on the densified fibrous preform at a temperature of 1600° C. or greater after the densifying the carbonized fibrous preform.

2. The method of claim 1 , wherein forming the carbonized fibrous preform comprises:
disposing a weight over a fibrous preform; and
carbonizing the fibrous preform.

3. The method of claim 1 , further comprising partially densifying the carbonized fibrous preform prior to infiltrating the carbonized fibrous preform with the first ceramic suspension to form a partially densified fibrous preform.

4. The method of claim 3 , further comprising infiltrating the carbonized fibrous preform with a second ceramic suspension prior to partially densifying the carbonized fibrous preform.

5. The method of claim 4 , further comprising performing a fourth heat treatment after infiltrating the carbonized fibrous preform with the second ceramic suspension and prior to the partially densifying the carbonized fibrous preform.

6. The method of claim 1 , wherein the first ceramic suspension comprises at least one of titanium dioxide and boron, zirconium dioxide and boron, or yttrium stabilized zirconium dioxide and boron, and wherein the method further comprises:
preparing the first ceramic suspension using at least one of a boron-oxide source or an oxide source and a boron source;
wherein the oxide source comprises at least one of zirconium dioxide, yttria stabilized zirconium dioxide, or titanium dioxide; and
wherein the boron source comprises at least one of a boron powder, a boron carbide powder, a boron oxide powder, or boric acid.

7. The method of claim 6 , further comprising adding a carbon source to the first ceramic suspension, wherein the carbon source comprises at least one of polyvinyl alcohol, polyacrylamide, hydro ethylcellulose, or an aqueous emulsion of polyester, epoxy, or phenolic.

8. The method of claim 1 , wherein the first temperature is greater than 2200° C.

9. The method of claim 1 , wherein the carbon-carbon composite part comprises a brake disk.

10. A method of making a carbon-carbon composite, comprising:
performing a first heat treatment on a carbonized fibrous preform at a first temperature, wherein the carbonized fibrous preform comprises a fiber volume ratio of 25% or greater, and wherein the carbonized fibrous preform includes carbon fibers comprised of at least 99% carbon;
performing a first densification of the carbonized fibrous preform using chemical vapor infiltration (CVI);
infiltrating the carbonized fibrous preform with a first ceramic suspension after the first densification;
performing a second heat treatment on the carbonized fibrous preform after the infiltrating the carbonized fibrous preform with the first ceramic suspension;
performing a second densification of the carbonized fibrous preform using CVI after the second heat treatment to form a densified fibrous preform; and
performing a third heat treatment on the densified fibrous preform at a second temperature of 1600° C. or greater.

11. The method of claim 10 , further comprising performing a fourth heat treatment on the carbonized fibrous preform at a temperature of 1850° C. or greater after performing the first densification of the carbonized fibrous preform and prior to infiltrating the carbonized fibrous preform with the first ceramic suspension.

12. The method of claim 10 , wherein the first temperature is greater than 2200° C.

13. The method of claim 12 , further comprising:
preparing the first ceramic suspension using at least one of a boron-oxide source or an oxide source and a boron source;
wherein the oxide source comprises at least one of zirconium dioxide, yttria stabilized zirconium dioxide, titanium dioxide, or Y 2 O 3 ;
wherein the boron source comprises at least one of a boron powder, a boron carbide powder, a boron oxide powder, or a boric acid, the boron powder comprising a size less than 2 micrometers; and
wherein the second heat treatment forms borides in the carbon-carbon composite.

14. The method of claim 12 , further comprising preparing the first ceramic suspension using yttrium oxides and zirconium oxides, wherein the second heat treatment forms at least one of zirconium oxycarbide or zirconium carbide and at least one of yttrium oxycarbide or yttrium carbide in the carbon-carbon composite.

15. The method of claim 14 , wherein the fiber volume ratio of the carbonized fibrous preform is between 25% and 40%.

16. The method of claim 10 , wherein the second temperature is between 1850° C. and 2100° C., and the first temperature is between 2350° C. and 2450° C.

17. The method of claim 10 , further comprising:
infiltrating the carbonized fibrous preform with a second ceramic suspension; and
performing a fourth heat treatment on the carbonized fibrous preform after infiltrating the carbonized fibrous preform with the second ceramic suspension and prior to the performing the first densification of the carbonized fibrous preform.

18. A method of making a carbon-carbon composite brake disk, comprising:
heat treating a carbonized fibrous preform at a temperature of 2200° C. or greater, wherein the carbonized fibrous preform comprises a fiber volume ratio of 25% or greater;
infiltrating the carbonized fibrous preform with a ceramic suspension;
heat treating the carbonized fibrous preform at a temperature of 1200° C. or greater to form a ceramic compound after infiltrating the carbonized fibrous preform with the ceramic suspension;
performing a first densification of the carbonized fibrous preform using chemical vapor infiltration (CVI) to form a densified fibrous preform; and
heat treating the densified fibrous preform at a temperature of 1600° C. or greater.

19. The method of claim 18 , further comprising performing a second densification of the carbonized fibrous preform prior to infiltrating the carbonized fibrous preform with the ceramic suspension.

20. The method of claim 19 , further comprising heat treating the carbonized fibrous preform at a temperature of 1850° C. or greater after the second densification and prior to infiltrating the carbonized fibrous preform with the ceramic suspension.

Assignees

• Goodrich Corp

Inventors

• Kirkpatrick Christopher T
• Le Costaouec Jean-Francois
• Linck John

Classifications

• F16D2200/0047

  Ceramic composite, e.g. C/C composite infiltrated with Si or B, or ceramic matrix infiltrated with metal · CPC title

• F16D69/023

  Composite materials containing carbon and carbon fibres or fibres made of carbonizable material · CPC title

• F16D65/126

  the material being of low mechanical strength, e.g. carbon, beryllium; Torque transmitting members therefor · CPC title

• C04B2235/614

  Gas infiltration of green bodies or pre-forms · CPC title

• C04B2235/48

  Organic compounds becoming part of a ceramic after heat treatment, e.g. carbonising phenol resins · CPC title