Development of alcoholic sucrose-based superplasticizer for geo-polymeric concrete and its process thereof

Patent metadata

Field	Value
Publication number	US-12304865-B2
Application number	US-202217657249-A
Country	US
Kind code	B2
Filing date	Mar 30, 2022
Priority date	Mar 31, 2021
Publication date	May 20, 2025
Grant date	May 20, 2025

Abstract

A geo-polymeric concrete and a process for preparing the geo-polymeric concrete is disclosed. The geo-polymeric concrete includes class F fly ash in a range from 10-20 wt %, of the design mix river sand in a range from 25-40 wt % of the design mix, a natural aggregate in a range from 15 to 40 wt % of the design mix, silica fume in a range from 1 to 2 wt % of class F fly ash, an alkaline activator solution and a superplasticizer in a range from 0.5 to 3 wt %. The materials used for preparing the superplasticizer are easily available in the market in abundance at a reasonable cost. The superplasticizer is economically viable and improves the workability of the geo-polymeric concrete. The presence of the superplasticizer does not affect the compressive strength of the geo-polymeric concrete.

First claim

What is claimed is:

1. A geo-polymeric concrete comprising:
class F fly ash in a range from 10-20 wt % of a design mix;
river sand in a range from 25-35 wt % of the design mix;
a natural aggregate in a range from 20 to 45 wt % of the design mix;
silica fume in a range from 1 to 2 wt % of class F fly ash;
an alkaline activator solution; and
a superplasticizer in a range from 0.5 to 3 wt % of class F fly ash, wherein the superplasticizer comprises about 17 ml of commercial grade ethyl alcohol and 60 g of sucrose in 100 ml water.

2. The geo-polymeric concrete as claimed in claim 1 , wherein the alkaline activator solution comprises 16 M sodium hydroxide and sodium silicate in water.

3. The geo-polymeric concrete as claimed in claim 1 , wherein the natural aggregate has a size in a range from 6 mm to 20 mm.

4. The geo-polymeric concrete as claimed in claim 1 , wherein the alkaline activator solution has a pH in a range from 13-14.

5. The geo-polymeric concrete as claimed in claim 1 , wherein the geo-polymeric concrete has a compressive strength in a range from 50 to 65 MPa with a workable slump in a range from 0 to 190 mm after 28 days curing.

6. The geo-polymeric concrete as claimed in claim 1 , wherein the geo-polymeric concrete with about 0.8 wt % of superplasticizer has a workability in a range from 0-40 mm slump with a compressive strength in a range from 57 to 60 MPa after 28 days curing.

7. The geo-polymeric concrete as claimed in claim 1 , wherein the geo-polymeric concrete with about 1.6 wt % of superplasticizer has a workability in a range from 0-150 mm slump with a compressive strength in a range from 57 to 60 MPa after 28 days curing.

8. The geo-polymeric concrete as claimed in claim 1 , wherein the geo-polymeric concrete with about 2.4 wt % of superplasticizer has a workability in a range from 0-190 mm slump with a compressive strength in a range from 55 to 59 MPa after 28 days curing.

9. A process for preparing a geo-polymeric concrete, the process comprising:
mixing 10-20 wt % of class F fly ash, 25-35 wt % of river sand, and 20 to 40 wt % of a natural aggregate in a motorized concrete mixer for about 5 to 8 minutes to obtain a pre-mixture;
adding 1 to 2 wt % of silica fume according to the wt % of class F fly ash to the pre-mixture to obtain a dry homogeneous mixture;
mixing sodium silicate (Na 2 SiO 3 ), sodium hydroxide (NaOH), and water to obtain an alkaline activator solution;
adding the alkaline activator solution to the dry homogeneous mixture for about 5 to 8 minutes to obtain a fresh geo-polymeric concrete;
adding 0.5 to 3 wt % of a superplasticizer according to the wt % of class F fly ash to the fresh concrete and mixing for about 4 to 6 minutes, wherein the superplasticizer comprises about 17 ml of commercial grade ethyl alcohol and 60 g of sucrose in 100 ml water;
filling into a 15 cm X 15 cm X 15 cm cube and vibrating for about 3 minutes; and
curing in a hot air oven at 60° C. for 48h rs followed by curing at ambient temperature for 28 days to obtain a geo-polymeric concrete.

10. The process as claimed in claim 9 , wherein preparing the superplasticizer comprises:
dissolving the sucrose in tap water;
stirring to obtain a sucrose solution with complete transparency;
adding the ethyl alcohol to the sucrose solution to obtain a mixture;
stirring the mixture to obtain a transparent solution and leaving for about 30 minutes to get a crystal-clear superplasticizer.

11. The process as claimed in claim 9 , wherein the alkaline activator solution has a pH in a range from 13-14.

12. The process as claimed in claim 9 , further comprising measuring workability using a slump cone method.

13. The process as claimed in claim 9 , further comprising evaluating compressive strength after 3, 7, 14-and 28-days of curing.

Assignees

• Council Scient Ind Res

Inventors

• Mudgal Manish
• Kumar Anil
• Chouhan Ramesh Kumar
• SINGH Archana
• Srivastava Avanish Kumar

Classifications

• C04B24/10

  Carbohydrates or derivatives thereof · CPC title

• C04B2103/32

  Superplasticisers · CPC title

• C04B2103/10

  Accelerators; Activators · CPC title

• C04B22/062

  of the alkali or alkaline-earth metals · CPC title

• C04B24/02

  Alcohols; Phenols; Ethers · CPC title