Multifunctional material for workability of geopolymeric system and its process thereof

Patent metadata

Field	Value
Publication number	US-10023497-B2
Application number	US-201715616308-A
Country	US
Kind code	B2
Filing date	Jun 7, 2017
Priority date	Jun 7, 2016
Publication date	Jul 17, 2018
Grant date	Jul 17, 2018

Abstract

The present invention relates to a novel multifunctional material for workability of geopolymeric system and its process thereof. The viscous characteristics in geopolymeric system are responsible for observed negligible workability of geopolymeric cement concrete system and which limits its broad application spectrum. The novel multifunctional material of the present invention prepared by digestion of siliceous agricultural waste i.e. Rice husk with aqueous alkaline materials involving simultaneous and synergistic chemical reactions among the various constituents of rice husk, aqueous alkaline compounds and optionally adding Cetyl trimethyl ammonium bromide (CTAB) to obtain in-situ synthesis of desired nano-sized multi functional agents lignin, hemicelluloses, cellulose, sodium silicate necessary for addressing the issue of workability and also improving the engineering properties of geopolymeric system for broad application spectrum.

First claim

We claim:

1. A material for addressing an issue of workability of a geopolymeric system comprising: rice husk in a range of 6.2% to 8.5%, NaOH in a range of 1.7% to 31%, and water in the range of 60 to 92%.

2. The material as claimed in claim 1 , wherein the material possesses properties comprising:
i) pH=14
ii) viscosity in a range of 7 mPa·s to 11 mPa·s.

3. The material as claimed in claim 1 , further comprising cetyltrimethylammonium bromide (CTAB) in a range of 0.62% to 0.85%.

4. A process for preparation of a material for addressing an issue of workability of a geopolymeric system comprising steps of:
a) digesting rice husk in a range of 6.2% to 8.5% and NaOH in a range of 1.7% to 31% in water in a range of 62% to 85% at a temperature in a range of 50° C. to 100° C. for a time period in a range of 3 to 14 hours to obtain a digested mass,
b) filtering the digested mass of step a) to obtain a slurry of the material in a range of 50% to 80% containing lignin, hemicelluloses, cellulose, and sodium silicate, wherein the sodium silicate has a size in a range of 40 to 100 nm.

5. The process as claimed in claim 4 , wherein the range of the temperature is 60° C. to 90° C., and the time period range is 4 to 12 hours.

6. The process as claimed in claim 4 , wherein step a) further comprises digesting cetyltrimethylammonium bromide (CTAB) in a range of 0.62% to 0.85% in the water.

7. A process for preparation of geopolymeric mortar/concrete cubes, the process comprising the steps of:
a) adding a slurry of a material comprising rice husk in a range of 6.2% to 8.5%, NaOH in a range of 1.7% to 31%, and water in the range of 60 to 92% to a geopolymeric mortar/ concrete mix and water, the geopolymeric mortar/concrete mix including fly ash, and the slurry having a concentration of 0.25% to 1.5% with respect to the fly ash in the geopolymeric mortar/concrete mix, and casting mortar/concrete cubes from the geopolymeric mortar/concrete mix, b) curing the mortar/concrete cubes at a temperature in a range of 40 to 60° C. for a time period in a range of 46 to 50 hrs to obtain finished geopolymeric cubes.

8. The process as claimed in claim 7 , wherein the geopolymeric mortar/concrete mix comprises sodium hydroxide, sodium meta silicate and water, and the finished geopolymeric cubes are geopolymeric mortar cubes.

9. The process as claimed in claim 7 , wherein the geopolymeric mortar/concrete mix comprises sodium hydroxide, sodium meta silicate, coarse aggregate and fine aggregates and water, and the finished geopolymeric cubes are geopolymeric concrete cubes.

10. A The process as claimed in claim 7 , wherein the finished geopolymeric cubes possess compressive strength in a range of 25 to 60 MPa.

11. The process as claimed in claim 7 , wherein mortar/concrete cubes are casted in dimensions of 7.06 cm×7.06 cm×7.06 cm and 15 cm×15 cm ×15 cm.

12. A The process as claimed in claim 7 , wherein the time period of the curing is 48 hrs.

13. The process as claimed in claim 9 , wherein the material further comprises cetyltrimethylammonium bromide (CTAB) in a range of 0.62% to 0.85%.

Assignees

• Council Scient Ind Res

Inventors

• Amritphale Sudhir Sitaram
• Chouhan Ramesh Kumar
• Mudgal Manish
• Verma Sarika
• Das Satyabrata

Classifications

• C04B24/001

  Waste organic materials · CPC title

• C04B22/062

  of the alkali or alkaline-earth metals · CPC title

• C04B28/006 Primary

  containing mineral polymers, e.g. geopolymers of the Davidovits type · CPC title

• C04B18/08

  Flue dust {, i.e. fly ash} · CPC title

• C04B22/0006 Primary

  Waste inorganic materials · CPC title