Light-emitting device, light-emitting apparatus, electronic device, and lighting device

Patent metadata

Field	Value
Publication number	US-12302685-B2
Application number	US-202418645743-A
Country	US
Kind code	B2
Filing date	Apr 25, 2024
Priority date	Jun 14, 2019
Publication date	May 13, 2025
Grant date	May 13, 2025

Abstract

A novel light-emitting device is provided. A light-emitting device with high emission efficiency is provided. A light-emitting device with a long lifetime is provided. A light-emitting device with low driving voltage is provided. The light-emitting device includes an anode, a cathode, and an EL layer between the anode and the cathode. The EL layer includes a hole-injection layer, a light-emitting layer, and an electron-transport layer. The hole-injection layer is positioned between the anode and the light-emitting layer. The electron-transport layer is positioned between the light-emitting layer and the cathode. The hole-injection layer contains a first substance and a second substance. The first substance is an organic compound which has a hole-transport property and a HOMO level higher than or equal to −5.7 eV and lower than or equal to −5.4 eV. The second substance exhibits an electron-accepting property with respect to the first substance. The electron-transport layer contains a material whose resistance decreases with current flowing therethrough.

First claim

What is claimed is:

1. A light-emitting device comprising:
an anode;
a cathode; and
an EL layer between the anode and the cathode,
wherein the EL layer includes a light-emitting layer and an electron-transport layer,
wherein the electron-transport layer is positioned between the light-emitting layer and the cathode,
wherein the electron-transport layer comprises a first material having a first resistance in a state where no current is flowing between the anode and the cathode and a second resistance in a state where a current is flowing between the anode and the cathode,
wherein the first resistance is higher than the second resistance,
wherein the first material comprises an organic compound having an electron-transport property and an organometallic complex of an alkali metal or an alkaline earth metal,
wherein the organic compound having an electron-transport property comprises an anthracene skeleton and a heterocyclic skeleton, and
wherein the organometallic complex of an alkali metal or an alkaline earth metal comprises a ligand containing nitrogen and oxygen.

2. A light-emitting device comprising:
an anode;
a cathode; and
an EL layer between the anode and the cathode,
wherein the EL layer includes a light-emitting layer and an electron-transport layer,
wherein the electron-transport layer is positioned between the light-emitting layer and the cathode,
wherein the electron-transport layer comprises a first material having a first resistance in a state where no current is flowing between the anode and the cathode and a second resistance in a state where a current is flowing between the anode and the cathode,
wherein the first resistance is higher than the second resistance,
wherein the first material comprises an organic compound having an electron-transport property and an organometallic complex of an alkali metal or an alkaline earth metal,
wherein the organic compound having an electron-transport property comprises an anthracene skeleton and a nitrogen-containing five-membered ring skeleton, and
wherein the organometallic complex of an alkali metal or an alkaline earth metal comprises a ligand containing nitrogen and oxygen.

3. A light-emitting device comprising:
an anode;
a cathode; and
an EL layer between the anode and the cathode,
wherein the EL layer includes a light-emitting layer and an electron-transport layer,
wherein the electron-transport layer is positioned between the light-emitting layer and the cathode,
wherein the electron-transport layer comprises a first material having a first resistance in a state where no current is flowing between the anode and the cathode and a second resistance in a state where a current is flowing between the anode and the cathode,
wherein the first resistance is higher than the second resistance,
wherein the first material comprises an organic compound having an electron-transport property and an organometallic complex of an alkali metal or an alkaline earth metal,
wherein the organic compound having an electron-transport property comprises an anthracene skeleton and a nitrogen-containing five-membered ring skeleton including two heteroatoms in a ring, and
wherein the organometallic complex of an alkali metal or an alkaline earth metal comprises a monovalent metal ion and a ligand having an 8-hydroxyquinolinato structure.

4. The light-emitting device according to claim 1 ,
wherein the electron-transport layer comprises a first layer and a second layer,
wherein the first layer is positioned between the light-emitting layer and the second layer,
wherein the second layer is positioned between the first layer and the cathode, and
wherein a concentration of the organometallic complex of an alkali metal or an alkaline earth metal in the first layer is different from that in the second layer.

5. The light-emitting device according to claim 2 ,
wherein the electron-transport layer comprises a first layer and a second layer,
wherein the first layer is positioned between the light-emitting layer and the second layer,
wherein the second layer is positioned between the first layer and the cathode, and
wherein a concentration of the organometallic complex of an alkali metal or an alkaline earth metal in the first layer is different from that in the second layer.

6. The light-emitting device according to claim 3 ,
wherein the electron-transport layer comprises a first layer and a second layer,
wherein the first layer is positioned between the light-emitting layer and the second layer,
wherein the second layer is positioned between the first layer and the cathode, and
wherein a concentration of the organometallic complex of an alkali metal or an alkaline earth metal in the first layer is different from that in the second layer.

7. The light-emitting device according to claim 4 ,
wherein the concentration of the organometallic complex of an alkali metal or an alkaline earth metal in the first layer is higher than that in the second layer.

8. The light-emitting device according to claim 5 ,
wherein the concentration of the organometallic complex of an alkali metal or an alkaline earth metal in the first layer is higher than that in the second layer.

9. The light-emitting device according to claim 6 ,
wherein the concentration of the organometallic complex of an alkali metal or an alkaline earth metal in the first layer is higher than that in the second layer.

10. The light-emitting device according to claim 1 ,
wherein the light-emitting layer contains a host material and a light-emitting substance, and
wherein the light-emitting substance emits blue fluorescence.

11. The light-emitting device according to claim 2 ,
wherein the light-emitting layer contains a host material and a light-emitting substance, and
wherein the light-emitting substance emits blue fluorescence.

12. The light-emitting device according to claim 3 , wherein the light-emitting layer contains a host material and a light-emitting substance, and wherein the light-emitting substance emits blue fluorescence.

13. The light-emitting device according to claim 1 , further comprising: a hole-injection layer between the anode and the light-emitting layer, wherein the hole-injection layer comprises a first substance and a second substance.

14. The light-emitting device according to claim 2 , further comprising: a hole-injection layer between the anode and the light-emitting layer, wherein the hole-injection layer comprises a first substance and a second substance.

15. The light-emitting device according to claim 3 , further comprising: a hole-injection layer between the anode and the light-emitting layer, wherein the hole-injection layer comprises a first substance and a second substance.

16. The light-emitting device according to claim 13 , wherein the first substance and the second substance are selected in such a way that a carrier recombination region in the light-emitting device extends to the electron-transport layer at an initial driving stage.

17. The light-emitting device according to claim 14 , wherein the first substance and the second substance are selected in such a way that a carrier recombination region in the light-emitting device extends to the electron-transport layer at an initial driving stage.

18. The light-emitting device according to claim 15 , wherein the first substance and the second substance are selected in such a way that a carrier recombination region in the light-emitting device extends to the electron-transport layer at an initial driving stage.

Assignees

• Semiconductor Energy Lab

Inventors

• Seo Satoshi
• Seo Hiromi
• Suzuki Kunihiko
• Abe Kanta
• Iwaki Yuji
• Hashimoto Naoaki
• Suzuki Tsunenori

Classifications

• H10K50/17

  Carrier injection layers · CPC title

• H10K2101/40

  Interrelation of parameters between multiple constituent active layers or sublayers, e.g. HOMO values in adjacent layers · CPC title

• H10K85/321

  Metal complexes comprising a group IIIA element, e.g. Tris (8-hydroxyquinoline) gallium [Gaq3] · CPC title

• H10K59/00

  Integrated devices, or assemblies of multiple devices, comprising at least one organic light-emitting element covered by group H10K50/00 · CPC title

• H10K50/171

  Electron injection layers · CPC title