Process and a multi-stage reactor assembly for the production of polyolefins

Patent metadata

Field	Value
Publication number	US-12290803-B2
Application number	US-202017616433-A
Country	US
Kind code	B2
Filing date	Apr 6, 2020
Priority date	Jun 4, 2019
Publication date	May 6, 2025
Grant date	May 6, 2025

Abstract

A process for the production of polyolefins comprising: feeding a slurry comprising at least one polymerization catalyst, at least one carrier liquid, first olefin monomer(s) and optionally at least one first comonomer into at least one loop reactor; polymerizing the first olefin monomer(s) and optionally the at least one first comonomer yielding a first polyolefin; withdrawing the first polyolefin from the loop reactor; feeding the first polyolefin to a gas-solids olefin polymerization reactor, wherein the gas-solids olefin polymerization reactor comprises: a top zone; a middle zone, which comprises a top end in direct contact with said top zone and which is located below said top zone, the middle zone having a generally cylindrical shape; and a bottom zone, which is in direct contact with a bottom end of the middle zone and which is located below the middle zone; introducing a fluidization gas stream into the bottom zone of the gas-solids olefin polymerization reactor; polymerizing second olefin monomer(s) and optionally at least one second comonomer in the presence of the polymerization catalyst and the first polyolefin to a second polyolefin in a dense phase formed by particles of said second polyolefin suspended in an upwards flowing stream of the fluidization gas in the middle zone; introducing a jet gas stream through one or more jet gas feeding ports in a jet gas feeding area of the middle zone at the dense phase in the middle zone of the gas-solids olefin polymerization reactor; withdrawing the second polyolefin from the gas-solids olefin polymerization reactor.

First claim

The invention claimed is:

1. A process for the production of polyolefins comprising:
a) feeding a slurry comprising at least one polymerization catalyst, at least one carrier liquid, first olefin monomer(s) and optionally at least one first comonomer into at least one loop reactor;
b) polymerizing the first olefin monomer(s) and optionally the at least one first comonomer yielding a first polyolefin;
c) withdrawing the first polyolefin from the at least one loop reactor;
d) feeding the first polyolefin to at least one gas-solids olefin polymerization reactor, wherein the at least one gas-solids olefin polymerization reactor comprises:
a top zone ( 1 );
a middle zone ( 2 ), which comprises a top end in direct contact with said top zone and which is located below said top zone ( 1 ), the middle zone ( 2 ) having a generally cylindrical shape; and
a bottom zone ( 3 ), which is in direct contact with a bottom end of the middle zone ( 2 ) and which is located below the middle zone ( 2 );

e) introducing a fluidization gas (FG) stream into the bottom zone ( 3 ) of the at least one gas-solids olefin polymerization reactor;
f) polymerizing second olefin monomer(s) and optionally at least one second comonomer in the presence of the at least one polymerization catalyst and the first polyolefin to a second polyolefin in a dense zone ( 4 ) formed by particles of said second polyolefin suspended in an upward flowing stream of fluidization gas in the middle zone ( 2 );
g) introducing a jet gas (JG) stream through one or more jet gas feeding ports ( 5 ) in a jet gas feeding area of the middle zone ( 2 ) at the dense zone ( 4 ) in the middle zone ( 2 ) of the at least one gas-solids olefin polymerization reactor;
h) withdrawing the second polyolefin from the at least one gas-solids olefin polymerization reactor;
wherein the jet gas (JG) stream fed through at least one of the one or more jet gas feeding ports ( 5 ) is provided by a flash pipe (FP) from the at least one loop reactor.

2. The process according to claim 1 , wherein the fluidization gas is removed from the top zone ( 1 ) of the at least one gas-solids olefin polymerization reactor and at least a part of the fluidization gas is introduced into the jet gas (JG) stream and into the fluidization gas (FG) stream.

3. A multi-stage reactor assembly for the production of polyolefins comprising
a) at least one loop reactor, comprising:
at least one inlet for feeding a slurry comprising at least one polymerization catalyst, at least one carrier liquid, first monomer(s) and optionally at least one first comonomer;
at least one outlet for withdrawing a first polyolefin produced in the at least one loop reactor; and
b) at least one gas-solids olefin polymerization reactor comprising:
a top zone ( 1 );
a middle zone ( 2 ), which comprises a top end in direct contact with said top zone ( 1 ) and which is located below said top zone ( 1 ), the middle zone ( 2 ) having a generally cylindrical shape; and
a bottom zone ( 3 ), which is in direct contact with a bottom end of the middle zone ( 2 ) and which is located below said middle zone ( 2 );
one or more jet gas feeding ports ( 5 ) located in a jet gas feeding area of the middle zone ( 2 );
a first line ( 6 ) for feeding a fluidization gas (FG) stream into the bottom zone ( 3 ) of the at least one gas-solids olefin polymerization reactor,
a second line ( 7 ) for withdrawing a stream comprising fluidization gas from the top zone ( 1 ) of the at least one gas-solids olefin polymerization reactor,
a third line ( 8 ) for introducing a jet gas (JG) stream into the middle zone ( 2 ) of the at least one gas-solids olefin polymerization reactor via the one or more feeding ports ( 5 ), wherein the jet gas (JG) stream fed through at least one of the one or more jet gas feeding ports ( 5 ) is provided by a flash pipe (FP) from the loop reactor;
a feeding port ( 9 ) connected to the at least one outlet of the at least one loop reactor, for feeding catalyst, polyolefin, monomer and optionally comonomer; and
a polymer withdrawal outlet ( 10 ) for withdrawing a second polyolefin produced in the at least one gas-solids olefin polymerization reactor;
one or more flash pipe jet gas feeding ports ( 14 ) located in a jet gas feeding area of the middle zone ( 2 ); and
a sixth line ( 15 ) for introducing a flash pipe (FP) gas stream into the middle zone ( 2 ) of the at least one gas-solids olefin polymerization reactor via the one or more flash pipe jet gas feeding ports ( 14 ).

4. The process of claim 1 , wherein carry-over of particles of polyolefin into a second stream comprising fluidization gas withdrawn from the top zone ( 1 ) of the at least one gas-solids olefin polymerization reactor is reduced.

5. The process of claim 1 , wherein a split between the first polyolefin produced in the at least one loop reactor and the second polyolefin produced in the at least one gas-solids olefin polymerization reactor is adjusted.

6. The process of claim 1 , wherein a bulk density of the dense zone is increased during polymerization.

7. The process of claim 2 , wherein carry-over of particles of polyolefin into a second stream comprising fluidization gas withdrawn from the top zone of the at least one gas-solids olefin polymerization reactor is reduced.

8. The multi-stage reactor assembly of claim 3 , wherein carry-over of particles of polyolefin into the stream withdrawn from the top zone of the at least one gas-solids olefin polymerization reactor is reduced.

9. The process of claim 2 , wherein a split between the first polyolefin produced in the at least one loop reactor and the second polyolefin produced in the at least one gas-solids olefin polymerization reactor is adjusted.

10. The multi-stage reactor assembly of claim 3 , wherein a split between the first polyolefin produced in the at least one loop reactor and the second polyolefin produced in the at least one gas-solids olefin polymerization reactor is adjusted.

11. The process of claim 2 , wherein a bulk density of the dense zone is increased during polymerization.

12. The process of claim 1 , wherein the at least one loop reactor is a loop reactor for polymerizing polypropylene.

Assignees

• Borealis Ag

Inventors

• Krallis Apostolos
• Kanellopoulos Vasileios
• Elovainio Erno
• Nyfors Klaus
• Kettner Joana

Classifications

• C08F10/02

  Ethene · CPC title

• C08F2/001

  Multistage polymerisation processes characterised by a change in reactor conditions without deactivating the intermediate polymer (C08F295/00, C08F297/00 take precedence) · CPC title

• C08F2/01

  characterised by special features of the polymerisation apparatus used · CPC title

• C08F210/06 Primary

  Propene · CPC title

• C07F7/28

  Titanium compounds · CPC title