Method of splitting the return fluidization gas in a gas solids olefin polymerization reactor

Patent metadata

Field	Value
Publication number	US-11400429-B2
Application number	US-201816765103-A
Country	US
Kind code	B2
Filing date	Oct 25, 2018
Priority date	Nov 17, 2017
Publication date	Aug 2, 2022
Grant date	Aug 2, 2022

Abstract

The present invention relates to a process for polymerizing olefin monomer(s) in a gas solids olefin polymerization reactor wherein the fluidization gas is split and returned to the reactor into the bottom zone of the reactor and directly into the dense phase formed by particles of a polymer of the olefin monomer(s) suspended in an upwards flowing stream of the fluidization gas in the middle zone of the reactor.

First claim

The invention claimed is:

1. A process for polymerizing olefin monomer(s) in a gas solids olefin polymerization reactor comprising:
a top zone;
a middle zone, which comprises a top end in direct contact with said top zone and which is located below said top zone, the middle zone having a generally cylindrical shape; and
a bottom zone, which is in direct contact with a bottom end of the middle zone and which is located below the middle zone;
comprising the following steps:

a) introducing a first stream of fluidization gas into the bottom zone;
b) polymerizing olefin monomer(s) in the presence of a polymerization catalyst in a dense phase formed by particles of a polymer of the olefin monomer(s) suspended in an upwards flowing stream of the fluidization gas in the middle zone;
c) withdrawing a second stream comprising the fluidization gas from the top zone;
d) introducing the second stream into a cooler;
e) withdrawing the cooled second stream from the cooler; and
f) splitting the cooled second stream into a cooled third stream and the first stream; and
g) introducing the cooled third stream through one or more feeding ports in a feeding area of the middle zone at the dense phase in the middle zone of the gas solids olefin polymerization reactor
wherein the feeding area of the middle zone is located on the surface of the middle zone between the top end and 50% of the total height of the middle zone, whereas the bottom end corresponds to 0% and the top end corresponds to 100% of the total height of the middle zone, and wherein the cooled third stream comprises from 1 to 30 wt % condensed fluidization gas, and wherein the cooled third stream is introduced through the one or more feeding ports into the dense phase in the middle zone of the gas solids olefin polymerization reactor in an introduction angle of 5° to 75°, whereas the introduction angle is the angle between
the projection of the direction of the cooled third stream after introduction into the reactor on a projection plane, which crosses a tangent plane of the generally cylindrical shape of the middle zone at the location of the one or more feeding ports and along an intersection line between the tangent plane and the generally cylindrical surface of the middle zone, whereas the projection plane is located perpendicular to the tangent plane, and
a perpendicular line, which
crosses the generally cylindrical surface of the middle zone at the location of the one or more feeding ports,
is located parallel to the projection plane, and
is perpendicular to the tangent plane.

2. The process according to claim 1 , wherein the feeding area of the middle zone is located in between the top end of the middle zone and 70% of the height of the middle zone in relation to the top end of the middle zone.

3. The process according to claim 1 , wherein number of feeding ports for introducing the cooled third stream is in the range of 1 to 15.

4. The process according to claim 1 , wherein the feeding ports are distributed across the feeding area of the middle zone of the gas solids olefin polymerization reactor in axial and/or radial direction with the proviso that the cooled third stream is introduced into the dense phase.

5. The process according to claim 1 , wherein the cooled second stream is split into the cooled third stream and the first stream at a ratio of 5:95 (v/v) to 75:25 (v/v).

6. The process according to claim 1 , wherein the pressure difference between the cooled third stream and the polymerization pressure in the gas solids polymerization reactor, ΔP, is at least 0.1 bar.

7. The process according to claim 1 , wherein the superficial gas velocity of the upwards flowing stream of the fluidization gas in the middle zone is from 0.35 to 1.2 m/s.

8. The process according to claim 7 wherein the superficial gas velocity of the first stream of fluidization gas introduced into the bottom zone is lower than the superficial gas velocity of the upwards flowing stream of the fluidization gas in the middle zone and is in the range of from 0.1 to 1.3 m/s.

9. The process according to any of the preceding claims wherein the bulk density of the dense phase during polymerization is in the range of from 100 to 500 kg/m 3 .

10. A reactor assembly for polymerizing olefin monomer(s) comprising a gas-solids olefin polymerization reactor ( 1 ) comprising:
a top zone ( 4 );
a middle zone ( 3 ), which comprises a top end in direct contact with said top zone ( 4 ) and which is located below said top zone ( 4 ), the middle zone ( 3 ) having a generally cylindrical shape; and
a bottom zone ( 2 ), which is in direct contact with a bottom end of the middle zone ( 3 ) and which is located below said middle zone ( 3 );
a first line ( 7 ) for withdrawing a second stream comprising fluidization gas from the top zone ( 4 ) of the gas-solids olefin
polymerization reactor ( 1 ),

a cooler ( 10 ) for cooling the second stream;
a second line ( 11 ) for withdrawing the cooled second stream from the cooler ( 10 );
a third line ( 6 ) connecting the second line ( 11 ) and the bottom zone ( 2 ) of the gas-solids olefin polymerization reactor ( 1 ) for introducing a first stream of fluidization gas into the bottom zone ( 2 ) of the gas-solids olefin polymerization reactor ( 1 ),
one or more feeding ports ( 13 ) located in a feeding area of the middle zone;
a fourth line ( 12 ) connecting the second line ( 11 ) and the one or more feeding ports ( 13 ) for introducing a cooled third stream into the middle zone ( 3 ) of the gas-solids olefin polymerization reactor ( 1 )

wherein the feeding area of the middle zone is located on the surface of the middle zone between the top end and 50% of the total height of the middle zone, whereas the bottom end corresponds to 0% and the top end corresponds to 100% of the total height of the middle zone; and wherein the cooled third stream comprises from 1 to 30 wt % condensed fluidization gas, and wherein the cooled third stream is introduced through the one or more feeding ports into the dense phase in the middle zone of the gas solids olefin polymerization reactor in an introduction angle of 5° to 75°, whereas the introduction angle is the angle between
the projection of the direction of the cooled third stream after introduction into the reactor on a projection plane, which crosses a tangent plane of the generally cylindrical shape of the middle zone at the location of the one or more feeding ports and along an intersection line between the tangent plane and the generally cylindrical surface of the middle zone, whereas the projection plane is located perpendicular to the tangent plane, and
a perpendicular line, which
crosses the generally cylindrical surface of the middle zone at the location of the one or more feeding ports,
is located parallel to the projection plane, and
is perpendicular to the tangent plane.

11. The reactor assembly according to claim 10 wherein the gas solids olefin polymerization reactor is a fluidized bed reactor comprising a fluidization grid.

12. The reactor assembly according to claim 10 wherein the gas solids olefin polymerization reactor is a fluidized bed reactor comprising a top zone having a generally conical shape, a middle zone in direct contact and below said top zone having a generally cylindrical shape, a bottom zone in direct contact with and below the middle zone and having a generally conical shape which does not contain a fluidization grid.

Assignees

• Borealis Ag

Inventors

• Weickert Günter
• Prinsen Eric-Jan
• Nyfors Klaus
• Elovainio Erno
• Kanellopoulos Vasileios

Classifications

• B01J8/44

  Fluidisation grids · CPC title

• C08F2/01 Primary

  characterised by special features of the polymerisation apparatus used · CPC title

• B01J8/1818 Primary

  Feeding of the fluidising gas (B01J8/44 takes precedence) · CPC title

• C08F10/00 Primary

  Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond · CPC title

• C08F10/02

  Ethene · CPC title