Catalyst systems and methods for producing olefins using the same

Patent metadata

Field	Value
Publication number	US-12280360-B2
Application number	US-202118257909-A
Country	US
Kind code	B2
Filing date	Dec 15, 2021
Priority date	Dec 18, 2020
Publication date	Apr 22, 2025
Grant date	Apr 22, 2025

Abstract

According to one or more embodiments of the present disclosure, a fluidization promoter useful for dehydrogenation includes from 0.1 wt. % to 10 wt. % gallium, from 5 ppm to 500 ppm platinum, less than 5 wt. % alkali metal or alkaline earth metal, and a support material. A median particle size of the fluidization promoter is from 20 μm to 50 μm. Catalyst systems useful for dehydrogenation and methods for producing olefins using the same are also disclosed.

First claim

The invention claimed is:

1. A fluidization promoter useful for dehydrogenation, the fluidization promoter comprising:
from 0.1 weight percent to 10 weight percent gallium based on the total weight of the fluidization promoter;
from 5 parts per million to 500 parts per million platinum based on the total weight of the fluidization promoter;
less than 5 weight percent of alkali metal or alkaline earth metal based on the total weight of the fluidization promoter; and
a support material,
wherein a median particle size of the fluidization promoter is from 20 microns to 50 microns.

2. A catalyst system useful for dehydrogenation, the catalyst system comprising:
from 70 volume percent to 98 volume percent of a catalyst having a median particle size of from 50 microns to 90 microns, the catalyst comprising platinum, gallium, and a support material; and
from 2 volume percent to 30 volume percent of a fluidization promoter having a median particle size of from 20 microns to 50 microns, the fluidization promoter comprising platinum, gallium, and a support material,
wherein the fluidization promoter comprises less platinum than the catalyst.

3. The catalyst system of claim 2 , wherein the catalyst comprises from 0.1 weight percent to 10 weight percent gallium based on the total weight of the catalyst.

4. The catalyst system of claim 2 , wherein the catalyst comprises from 5 parts per million to 500 parts per million of platinum based on the total weight of the catalyst.

5. The catalyst system of claim 2 , wherein the support material of the catalyst comprises alumina, silica, titanium oxide, or zirconium.

6. The catalyst system of claim 2 , wherein the catalyst further comprises less than or equal to 5 weight percent alkali metal or alkaline earth metal based on the total weight of the catalyst.

7. The catalyst system of claim 2 , wherein the fluidization promoter comprises from 0.1 weight percent to 10 weight percent gallium based on the total weight of the fluidization promoter.

8. The catalyst system of claim 2 , wherein the fluidization promoter comprises from 5 parts per million to 500 parts per million of platinum based on the total weight of the fluidization promoter.

9. The catalyst system of claim 2 , wherein the fluidization promoter comprises platinum in an amount of from 40 percent to 90 percent of the amount of platinum of the catalyst.

10. The catalyst system of claim 2 , wherein the support material of the fluidization promoter comprises alumina, silica, titanium oxide, or zirconium.

11. The catalyst system of claim 2 , wherein the fluidization promoter further comprises less than or equal to 5 weight percent alkali metal or alkaline earth metal based on the total weight of the fluidization promoter.

12. The catalyst system of claim 2 , wherein a Sauter Mean Diameter of the catalyst system is from 30 microns to 90 microns.

13. A method for producing olefins, the method comprising:
contacting a hydrocarbon-containing feed with a catalyst in a reactor portion of a reactor system to form an olefin-containing effluent;
separating at least a portion of the olefin-containing effluent from the catalyst;
passing the catalyst to a catalyst-processing portion of the reactor system and processing the catalyst to produce a processed catalyst;
passing the processed catalyst from the catalyst processing portion to the reactor portion; and
introducing a fluidization promoter to the reactor system such that a quality of fluidization of the catalyst is improved, wherein:
the catalyst has a median particle size of from 50 microns to 90 microns and comprises platinum, gallium, and a support material;
the fluidization promoter has a median particle size of from 20 microns to 50 microns and comprises platinum, gallium, and a support material; and
the fluidization promoter comprises less platinum than the catalyst.

14. The method of claim 13 , wherein the fluidization promoter comprises platinum in an amount of from 40 percent to 90 percent of the amount of platinum of the catalyst.

15. The method of claim 13 , wherein an amount of the fluidization promoter introduced to the reactor system is from 2 volume percent to 30 volume percent of a sum of a volume of the catalyst and a volume of the fluidization promoter.

Assignees

• Dow Global Technologies Llc

Inventors

• Luo Lin
• Yang Yang
• Pretz Matthew T

Classifications

• B01J35/40

  characterised by dimensions, e.g. grain size (in a colloidal state B01J35/23; crystallite size B01J35/77) · CPC title

• C07C2523/62

  with gallium, indium, thallium, germanium, tin or lead · CPC title

• C07C2523/42

  Platinum · CPC title

• C07C2523/08

  of gallium, indium or thallium · CPC title

• C07C5/325

  of the platinum group · CPC title