Reactivating propane dehydrogenation catalyst

Patent metadata

Field	Value
Publication number	US-9834496-B2
Application number	US-201214122201-A
Country	US
Kind code	B2
Filing date	Jul 11, 2012
Priority date	Jul 13, 2011
Publication date	Dec 5, 2017
Grant date	Dec 5, 2017

Abstract

Increase propane dehydrogenation activity of a partially deactivated dehydrogenation catalyst by heating the partially deactivated catalyst to a temperature of at least 660° C., conditioning the heated catalyst in an oxygen-containing atmosphere and, optionally, stripping molecular oxygen from the conditioned catalyst.

First claim

What is claimed is:

1. An improved process for dehydrogenating an alkane, the process comprising placing an alkane in operative contact with a heated alkane dehydrogenation catalyst in a reactor, the catalyst comprising a Group VIII noble metal and a Group IIIA metal, removing from the reactor a partially deactivated catalyst, rejuvenating the partially deactivated catalyst in a regenerator, and transporting the rejuvenated catalyst from the regenerator to the reactor, wherein the improvement comprises a combination of treatment within the regenerator and transport of the rejuvenated catalyst from the regenerator to the reactor, the treatment within the regenerator comprising sequential steps:
a. heating the partially deactivated catalyst to a temperature of at least 660 degrees Celsius using heat generated by combusting both coke contained on the partially deactivated catalyst and a fuel source other than said coke, said heating yielding a heated, further deactivated catalyst which has an alkane dehydrogenation activity that is less than that of the partially deactivated catalyst wherein combusting the fuel source other than said coke occurs concurrent with combusting said coke contained on the partially deactivated catalyst;
b. subjecting the heated, further deactivated catalyst to a conditioning step which comprises maintaining the heated, further deactivated dehydrogenation catalyst at a temperature of at least 660 degrees Celsius while exposing the heated, further deactivated dehydrogenation catalyst to a flow of an oxygen-containing gas for a period of time greater than two minutes to yield an oxygen-containing reactivated dehydrogenation catalyst that has an activity for dehydrogenating alkane that is greater than that of either the partially deactivated catalyst or the further deactivated catalyst; and, optionally,
c. maintaining the oxygen-containing reactivated catalyst at a temperature of at least 660 degrees Celsius while exposing the reactivated catalyst to a flow of stripping gas that is substantially free of molecular oxygen and combustible fuel for a period of time to remove from the oxygen-containing reactivated dehydrogenation catalyst at least a portion of molecular oxygen trapped within or between catalyst particles and physisorbed oxygen that is desorbable at said temperature during that period of time and yield a rejuvenated dehydrogenation catalyst; with transport from the regenerator to the reactor being effected by a combination of gravity and motive force imparted by an inert transport gas.

2. The process of claim 1 , wherein the oxygen-containing gas has an oxygen content within a range of from 5 mole percent to 100 mole percent, each mole percent being based upon total moles of oxygen-containing gas.

3. The process of claim 1 , wherein the period of time in step b is within a range of from at least three minutes to no more than 14 minutes.

4. The process of claim 1 , wherein the temperature for step b lies within a range of from 660 degrees Celsius to 850 degrees Celsius.

5. The process of claim 1 , wherein the partially deactivated catalyst comprises a Group VIII noble metal, and a Group IIIA metal, wherein the Group VIII noble metal is platinum and the Group IIIA metal is gallium.

6. The process of claim 1 , wherein one or more of steps a), b) and c) are physically separated from one another.

7. The process of claim 6 , wherein steps b) and c) are physically separated from one another and an oxygen-containing atmosphere with an oxygen content within a range of from 5 mole percent to 100 mole percent, each mole percent being based upon total moles of oxygen-containing atmosphere, is used to effect catalyst transfer between steps b) and c).

8. The process of claim 1 , wherein the partially deactivated catalyst comprises a promoter metal.

Assignees

• Pretz Matthew
• Luo Lin
• Domke Susan
• Clark Howard W
• Pierce Richard A
• Malek Andrzej M
• Stewart Mark W
• Stears Brien A
• Schweizer Jr Albert E
• Capone Guido
• Coffey Duncan P
• Mbaraka Isa K
• Dow Global Technologies Llc

Inventors

• Pretz Matthew
• Luo Lin
• Domke Susan
• Clark Howard W
• Pierce Richard A
• Malek Andrzej M
• Stewart Mark W
• Stears Brien A
• Schweizer Jr Albert E
• Capone Guido
• Coffey Duncan P
• Mbaraka Isa K

Classifications

• C07C2523/42

  Platinum · CPC title

• C07C11/10

  with five carbon atoms · CPC title

• C07C2523/44

  Palladium · CPC title

• B01J2523/13

  Potassium · CPC title

• B01J2523/41

  Silicon · CPC title