Electrochemical exhaust gas sensor with photolysis

Patent metadata

Field	Value
Publication number	US-12259357-B2
Application number	US-202217724909-A
Country	US
Kind code	B2
Filing date	Apr 20, 2022
Priority date	Apr 20, 2022
Publication date	Mar 25, 2025
Grant date	Mar 25, 2025

Abstract

An automotive exhaust gas sensor includes a gas chamber, an ultraviolet light source configured to emit ultraviolet light into the gas chamber and to photolyze an exhaust gas sample in the gas chamber, and an electrochemical detector disposed in the gas chamber and configured to detect a specified chemical in the photolyzed exhaust gas sample.

First claim

What is claimed is:

1. A method for detecting a chemical in a gas sample, the method comprising:
collecting the gas sample in a gas chamber of an exhaust gas sensor;
photolyzing a background chemical in the gas sample with ultraviolet light transmitted into the gas chamber; and
collecting data from an electrochemical sensor of the exhaust gas sensor, the data indicating an amount of the chemical in the exhaust gas sample.

2. The method of claim 1 , wherein the chemical is nitrogen oxide and the background chemical is nitrogen dioxide.

3. The method of claim 1 , wherein the background chemical is ozone and the detected chemical is at least one of benzene, toluene, and xylene in the gas sample.

4. The method of claim 1 , wherein the detected chemical is formaldehyde.

5. The method of claim 1 , wherein the data include changes in at least one of electrical current or voltage in the electrochemical sensor, the changes in the at least one of electrical current or voltage indicating an amount of the detected chemical present in the gas sample.

6. The method of claim 5 , further comprising photolyzing the background chemical in the gas sample to reduce noise in the collected data.

7. The method of claim 1 , further comprising pulsing the ultraviolet light to photolyze the background chemical.

8. The method of claim 1 , further comprising transmitting the ultraviolet light through a fiber optic cable connecting a light source to the gas chamber.

9. The method of claim 1 , further comprising collecting the data with an electrolyte sensor element disposed in the gas chamber.

10. The method of claim 9 , wherein the electrolyte sensor element includes an yttria-stabilized zirconia electrolyte.

11. An automotive exhaust gas sensor, comprising:
a gas chamber;
an ultraviolet light source configured to emit ultraviolet light into the gas chamber and to photolyze an exhaust gas sample in the gas chamber; and
an electrochemical sensor disposed in the gas chamber and configured to detect a specified chemical in the photolyzed exhaust gas sample.

12. The sensor of claim 11 , wherein the ultraviolet light source is configured to photolyze nitrogen dioxide in the gas sample into nitrogen oxide and to photolyze ozone in the exhaust gas sample into molecular oxygen.

13. The sensor of claim 11 , further comprising a fiber optic cable having a first end connected to the ultraviolet light source and a second end disposed in the gas chamber, the fiber optic cable configured to transmit the ultraviolet light from the ultraviolet light source to the gas chamber.

14. The sensor of claim 11 , wherein the specified chemical detected by the electrochemical sensor is at least one of nitrogen oxide, nitrogen dioxide, oxygen or ozone.

15. The sensor of claim 11 , wherein the specified chemical detected by the electrochemical sensor is at least one of formaldehyde, benzene, toluene, and xylene.

16. The sensor of claim 11 , wherein the electrochemical sensor includes an yttria-stabilized zirconia electrolyte.

17. The sensor of claim 11 , wherein the electrochemical sensor includes an electrolyte sensor element in the gas chamber.

18. The sensor of claim 17 , wherein the electrochemical sensor is configured to transmit data indicating a change in at least one of current or voltage in the electrolyte sensor element, the change in the at least one of current or voltage indicating an amount of the specified chemical in the exhaust gas sample.

19. The sensor of claim 11 , wherein the ultraviolet light source is configured to emit pulses of the ultraviolet light into the gas chamber.

20. The sensor of claim 11 , wherein the electrochemical sensor is configured to detect oxygen ions released upon photolysis of a background chemical in the exhaust gas sample.

Assignees

• Ford Global Tech Llc

Inventors

• Bilby David
• Wolffenbuttel Reinoud Felix

Classifications

• G01N33/0047

  Organic compounds · CPC title

• G01N33/0037

  NOx · CPC title

• G01N27/4045

  for gases other than oxygen · CPC title

• G01N27/4073 Primary

  Composition or fabrication of the solid electrolyte · CPC title

• G01N33/0013

  by a chemical reaction (a chemical reaction taking place or a gas being eliminated in one or more analysing channels G01N33/0024) · CPC title