Catalyst for reducing nitrogen oxides

Patent metadata

Field	Value
Publication number	US-12246306-B2
Application number	US-202017776180-A
Country	US
Kind code	B2
Filing date	Nov 18, 2020
Priority date	Nov 20, 2019
Publication date	Mar 11, 2025
Grant date	Mar 11, 2025

Abstract

The present invention relates to a catalyst comprising a carrier substrate of length L and at least two washcoat layers A and B whereinwashcoat layer A comprisesalumina;ceria;an alkaline earth compound and/or an alkali compound;platinum, palladium or platinum and palladium;washcoat layer B comprises a zeolite and palladium, wherein the palladium is present as palladium cation in the zeolite structure or is wholly or partially present as palladium metal and/or as palladium oxide in the zeolite structure and/or on the surface of the zeolite structure; andwherein washcoat layer A is arranged below washcoat layer B.

First claim

The invention claimed is:

1. A catalyst comprising a carrier substrate of length L, which is a flow-through substrate, and at least two washcoat layers A and B wherein
washcoat layer A comprises
alumina in an amount of 50 to 80 g/L, based on the volume of the carrier substrate;)
ceria in an amount of 100 to 130 g/L, based on the volume of the carrier substrate;
a composite material of ceria and alumina which comprises alumina in an amount of 5 to 95 wt %, based on the weight of the composite material in an amount of 10 to 80 g/L, based on the volume of the carrier substrate;
magnesium oxide and/or barium oxide in an amount of 15 to 20 g/L, based on the volume of the carrier substrate; and
platinum and palladium in a weight ratio of 1:1 to 12:1;

washcoat layer B comprises a zeolite of the structural type ABW, AEI, AFX, BEA, CHA, ERI, ESV, FAU, FER, KFI, LEV, LTA, MFI, MWW, SOD or STT and palladium, wherein the palladium is present as (i) a palladium cation in the zeolite structure and/or (ii) is present as either or both of a palladium metal or a palladium oxide located in, on, or both in and on the zeolite structure; and
wherein washcoat layer A is arranged directly on the carrier substrate and washcoat layer B is arranged directly on washcoat layer A.

2. The catalyst according to claim 1 , characterized in that washcoat layer A further comprises rhodium.

3. The catalyst according to claim 1 , characterized in that it comprises a third washcoat layer A 1 which comprises rhodium.

4. The catalyst according to claim 1 , characterized in that washcoat layer B further comprises platinum.

5. An exhaust gas system comprising
a) a catalyst according to claim 1 , and
b) an SCR catalyst.

6. A method for cleaning exhaust gases from motor vehicles that are operated with lean-burn engines, characterized in that the exhaust gas is channeled through an exhaust gas system according to claim 5 .

7. The catalyst according to claim 1 , wherein the palladium in washcoat layer B is present as a palladium cation in the zeolite structure.

8. The catalyst according to claim 1 , wherein the palladium in washcoat layer B is present as a palladium metal located in, on, or both in and on the zeolite structure.

9. The catalyst according to claim 1 wherein the palladium in washcoat layer B is present as a palladium oxide located in, on, or both in and on the zeolite structure.

Assignees

• Umicore Ag & Co Kg

Inventors

• Bassou Badr
• Woerz Anke

Classifications

• F01N3/2066

  Selective catalytic reduction [SCR] · CPC title

• B01J37/0246

  Coatings comprising a zeolite · CPC title

• B01J29/068

  Noble metals · CPC title

• B01J23/63 Primary

  with rare earths or actinides · CPC title

• B01J23/58

  with alkali- or alkaline earth metals · CPC title