Catalyst for reduction of nitrogen oxides

Patent metadata

Field	Value
Publication number	US-10428708-B2
Application number	US-201515327512-A
Country	US
Kind code	B2
Filing date	Aug 4, 2015
Priority date	Aug 5, 2014
Publication date	Oct 1, 2019
Grant date	Oct 1, 2019

Abstract

The present invention relates to a nitrogen oxide storage catalyst composed of at least two catalytically active washcoat layers on a support body, wherein a lower washcoat layer A comprises cerium oxide, an alkaline earth metal compound and/or an alkali metal compound, and platinum and palladium, and an upper washcoat layer B disposed atop the washcoat layer A comprises cerium oxide, platinum and palladium, and no alkali metal or alkaline earth metal compound, and to a method of converting NOx in exhaust gases from motor vehicles which are operated with lean-burn engines.

First claim

The invention claimed is:

1. Nitrogen oxide storage catalyst composed of at least two catalytically active washcoat layers on a support body,
wherein
a lower washcoat layer A contains cerium oxide in a quantity of 110 to 180 kg/m 3 (110 to 180 g/L) in relation to the volume of the support body, an alkaline earth metal compound and/or an alkali metal compound, as well as platinum and palladium;
an upper washcoat layer B disposed atop the washcoat layer A contains cerium oxide, as well as platinum and palladium, and no alkali metal or alkaline earth metal compounds;
the ratio of the cerium oxide in washcoat layer A to the cerium oxide in washcoat layer B is greater than 1:1 up to 5:1, wherein the total quantity of cerium oxide in washcoat layer A and washcoat layer B, calculated in kg/m 3 (g/L) and in relation to the volume of the support body, is 132 to 240 kg/m 3 (132 to 240 g/L);
the ratio Pt:Pd in washcoat layer A and washcoat layer B is equal, and the ratio Pt:Pd amounts to 2:1 to 20:1;
the total quantity of platinum and palladium, calculated respectively in kg/m 3 (g/L) and in relation to the volume of the support body, in washcoat layer A and washcoat layer B is equal; and
the ratio of the concentrations of platinum and palladium in washcoat layer A to platinum and palladium in washcoat layer B, respectively in relation to the total mass of the respective washcoat layer, is 1:1 to 1:5, and
wherein the quantity of cerium oxide in lower washcoat layer A exceeds the quantity of alkaline earth metal oxide or alkali metal oxide in lower washcoat layer A.

2. Nitrogen oxide storage catalyst according to claim 1 , wherein the washcoat layer B contains cerium oxide in a quantity of 22 to 120 kg/m 3 (22 to 120 g/L).

3. Nitrogen oxide storage catalyst according to claim 1 , wherein the washcoat layer A contains cerium oxide in a quantity of 110 to 160 kg/m 3 (110 to 160 g/L).

4. Nitrogen oxide storage catalyst according to claim 1 , wherein the total washcoat loading of the support body is 300 to 600 kg/m 3 (300 to 600 g/L) in relation to the volume of the support body.

5. Nitrogen oxide storage catalyst according to claim 4 , wherein the loading with washcoat layer A is 150 to 500 kg/m 3 (150 to 500 g/L), and the loading with washcoat layer B is 50 to 300 kg/m 3 (50 to 300 g/L), respectively in relation to the volume of the support body.

6. Nitrogen oxide storage catalyst according to claim 4 , wherein the loading with washcoat layer A is 250 to 300 kg/m 3 (250 to 300 g/L), and the loading with washcoat layer B is 50 to 150 kg/m 3 (50 to 150 g/L), respectively in relation to the volume of the support body.

7. Nitrogen oxide storage catalyst according to claim 1 , wherein the ratio of platinum to palladium is 4:1 to 18:1.

8. Nitrogen oxide storage catalyst according to claim 1 , wherein the ratio of platinum to palladium is 6:1 to 16:1.

9. Nitrogen oxide storage catalyst according to claim 1 wherein washcoat layer A and/or washcoat layer B contain rhodium.

10. Nitrogen oxide storage catalyst according to claim 9 , wherein rhodium is provided in quantities of 0.003 to 0.35 kg/m 3 (0.003 to 0.35 g/L) in relation to the volume of the support body.

11. Nitrogen oxide storage catalyst according to claim 1 , wherein the alkaline earth metal compound in washcoat layer A is magnesium oxide, barium oxide, and/or strontium oxide.

12. Nitrogen oxide storage catalyst composed of least two catalytically active washcoat layers on a support body,
wherein
a lower washcoat layer A contains cerium oxide in a quantity of 110 to 180 kg/m 3 (110 to 180 g/L) in relation to the volume of the support body, an alkaline earth metal compound and/or an alkali metal compound, as well as platinum and palladium; an upper washcoat layer B disposed atop the washcoat layer A contains cerium oxide, as well as platinum and palladium, and no alkali metal or alkaline earth metal compounds; the ratio of the cerium oxide in washcoat layer A to the cerium oxide in washcoat layer B is 1:1 to 5:1, wherein the total quantity of cerium oxide in washcoat layer A and washcoat layer B, calculated in kg/m 3 (g/L) and in relation to the volume of the support body, is 132 to 240 kg/m 3 (132 to 240 g/L);
the ratio Pt:Pd in washcoat layer A and washcoat layer B Is equal, and the ratio Pt:Pd amounts to 2:1 to 20:1;
the total quantity of platinum and palladium, calculated respectively in kg/m 3 (g/L) and in relation to the volume of the support body, in washcoat layer A and washcoat layer B is equal; and
the ratio of the concentrations of platinum and palladium in washcoat layer A to platinum and palladium in washcoat layer B, respectively in relation to the total mass of the respective washcoat layer, is 1:1 to 1:5, and wherein the nitrogen oxide storage catalyst comprises
a lower washcoat layer A that contains
cerium oxide in a quantity of 100 to 160 kg/m 3 (100 to 160 g/L),
platinum and palladium in a ratio of 10:1, as well as
magnesium oxide and/or barium oxide: and

an upper washcoat layer B that is disposed atop the washcoat layer A and contains
no alkaline earth metal compound and no alkali metal compound,
platinum and palladium in a ratio of 10:1, as well as
cerium oxide in a quantity of 45 to 65 kg/m 3 (45 to 65 g/L), wherein washcoat layer A is provided in quantities of 250 to 350 kg/m (250 to 350 g/L), and washcoat layer B is provided in quantities of 80 to 130 kg/m (80 to 130 g/L), wherein the specification of quantity kg/m (g/L) respectively relates to the volume of the support body, and wherein the quantity of cerium oxide in lower washcoat layer A exceeds the quantity of alkaline earth metal oxide or alkali metal oxide in lower washcoat layer A.

13. Method of converting NOx in exhaust gases of motor vehicles that are operated with lean-burn engines, wherein the exhaust gas is guided over a nitrogen oxide storage catalyst composed of at least two catalytically active washcoat layers on a support body, wherein
a lower washcoat layer A contains cerium oxide in a quantity of 110 to 180 kg/m 3 (110 to 180 g/L) in relation to the volume of the support body, an alkaline earth metal compound and/or an alkali metal compound, as well as platinum and palladium;
an upper washcoat layer B disposed atop the washcoat layer A contains cerium oxide, as well as platinum and palladium, and no alkali metal or alkaline earth metal compounds;
the ratio of the cerium oxide in washcoat layer A to the cerium oxide in washcoat layer B is equal to or greater than 2.27:1 up to 5:1, wherein the total quantity of cerium oxide in washcoat layer A and washcoat layer B, calculated in kg/m 3 (g/L) and in relation to the volume of the support body, is 132 to 240 kg/m 3 (132 to 240 g/L);
the ratio Pt:Pd in washcoat layer A and washcoat layer B is equal, and the ratio Pt:Pd amounts to 2:1 to 20:1;
the total quantity of platinum and palladium, calculated respectively in kg/m 3 (g/L) and in relation to the volume of the support body, in washcoat layer A and washcoat layer B is equal; and
the ratio of the concentrations of platinum and palladium in washcoat layer A to platinum and palladium in washcoat layer B, respectively in relation to the total mass of the respective washcoat layer is 1:1 to 1:5, and wherein the quantity of cerium oxide in lower washcoat layer A exceeds the quantity of alkaline earth metal oxide or alkali metal oxide in lower washcoat layer A.

14. Nitrogen oxide storage catalyst according to claim 1 , wherein the alkaline earth metal compound in washcoat layer A is selected from the group consisting of magnesium oxide, barium oxide, strontium oxide,

Assignees

• Umicore Ag & Co Kg

Inventors

• Utschig Thomas
• Hoyer Ruediger
• Mueller Elena

Classifications

• B01J37/0244 Primary

  Coatings comprising several layers · CPC title

• B01J23/58

  with alkali- or alkaline earth metals · CPC title

• B01J23/63

  with rare earths or actinides · CPC title

• B01D2255/2063

  Lanthanum · CPC title

• B01D2255/9022

  Two layers · CPC title