Gas sensor and method for producing alkaline earth ferrite

Patent metadata

Field	Value
Publication number	US-12241852-B2
Application number	US-202017754126-A
Country	US
Kind code	B2
Filing date	Aug 26, 2020
Priority date	Sep 24, 2019
Publication date	Mar 4, 2025
Grant date	Mar 4, 2025

Abstract

The gas sensor is provided with: a base material; a first electrode and a second electrode arranged on the base material; and a gas detection member connected to the first electrode and the second electrode, wherein the gas detection member contains flaky particles of alkaline earth ferrite.

First claim

The invention claimed is:

1. A gas sensor, comprising:
a base material;
a first electrode and a second electrode arranged on the base material; and
a gas detection member connected to the first electrode and the second electrode, wherein
the gas detection member contains flaky particles of alkaline earth ferrite, wherein an electric resistance of the gas detection member is changed by reacting between oxygen adsorbed on a surface of the alkaline earth ferrite as negative charges with a gas.

2. The gas sensor according to claim 1 , wherein the gas detection member contains the flaky particles and void portions which are gaps between the flaky particles.

3. The gas sensor according to claim 1 , wherein each of the flaky particles has a three-dimensional porous structure.

4. The gas sensor according to claim 1 , wherein a ratio of a length of the flaky particle in a plane direction of the base material to a thickness of the flaky particle (length/thickness) is between 1 and 20.

5. The gas sensor according to claim 4 , wherein the alkaline earth ferrite contains at least one dissimilar element selected from the group consisting of La, Sm, Si, Ti, Hf, and Zr.

6. The gas sensor according to claim 5 , wherein a content of the dissimilar element is 10 mol % or less.

7. The gas sensor according to claim 6 , wherein a content of the dissimilar element is between 3 mol % and 7 mol %.

8. The gas sensor according to claim 4 , wherein the alkaline earth ferrite is CaFe 2 O 4 .

9. The gas sensor according to claim 8 , wherein the dissimilar element is Zr.

10. A method for producing a gas sensor, comprising:
providing a base material, a first electrode, a second electrode and a gas detection member;
arranging the first electrode and the second electrode onto the base material; and
connecting the gas detection member to the first electrode and the second electrode, wherein the gas detection member contains a plurality of flaky particles of alkaline earth ferrite, wherein the alkaline earth ferrite is prepar executing the following steps:
a step of preparing a mixed solution of a plurality of kinds of metal ions, which is a starting material;
a step of adding an organic acid to the mixed solution to prepare a precursor solution containing a metal-organic acid complex;
a step of evaporating and drying the precursor solution to obtain a precursor;
a step of performing a first calcination process on the precursor; and
a step of performing a second calcination process after the first calcination process, wherein the first calcination process is a process of calcining at 300° C. or higher and 600° C. or lower for 10minutes or longer and 120 minutes or shorter, and
the second calcination process is a process of calcining at 600° C. or higher and 1400° C. or lower for 1 hour or longer and 24 hours or shorter, wherein an electric resistance of the gas detection member is changed by reacting between oxygen adsorbed on a surface of the alkaline earth ferrite as negative charges with a gas.

Assignees

• National Institute Of Tech
• Koa Corp

Inventors

• Matsushima Shigenori
• Obata Kenji
• Iguchi Kenichi
• Ota Yukiko
• Nagata Hisakazu
• Urano Koichi

Classifications

• C01P2006/40

  Electric properties · CPC title

• C01G49/0036

  containing one alkaline earth metal, magnesium or lead · CPC title

• C01P2002/54

  one element only · CPC title

• G01N27/125 Primary

  Composition of the body, e.g. the composition of its sensitive layer · CPC title

• G01N27/127 Primary

  comprising nanoparticles · CPC title